Invention Grant
- Patent Title: Process for producing propylene and aromatics from butenes by metathesis and aromatization
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Application No.: US14171905Application Date: 2014-02-04
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Publication No.: US10106474B2Publication Date: 2018-10-23
- Inventor: Jaap W. van Hal , Scott A. Stevenson , Jim Allman , David L. Sullivan , Travis Conant
- Applicant: SAUDI BASIC INDUSTRIES CORPORATION
- Applicant Address: SA Riyadh
- Assignee: SAUDI BASIC INDUSTRIES CORPORATION
- Current Assignee: SAUDI BASIC INDUSTRIES CORPORATION
- Current Assignee Address: SA Riyadh
- Agency: Cantor Colburn LLP
- Main IPC: C07C2/76
- IPC: C07C2/76 ; C07C6/04 ; C07C5/41

Abstract:
The disclosure is for a process for producing propylene and hexene (along with ethylene, pentenes, product butenes, heptenes and octenes) by metathesis from butenes (iso-, 1- and cis and trans 2-) and pentenes and then aromatizing the hexenes (along with higher olefins, such as heptenes and octenes) to benzene (along with toluene, xylenes, ethylbenzene and styrene). Since the desired products of the metathesis reaction are propylene and hexene, the feed to the metathesis reaction has a molar ratio for 1-butene:2-butene which favors production of propylene and 3-hexene with the concentration of hexenes and higher olefins in the metathesis product being up to 30 mole %. An isomerization reactor may be used to obtain the desired molar ratio of 1-butene:2-butene for the feed composition into the metathesis reactor. After the metathesis reaction, of hexene and higher olefins are separated for aromatization to benzene and other aromatics.
Public/Granted literature
- US20140148629A1 PROCESS FOR PRODUCING PROPYLENE AND AROMATICS FROM BUTENES BY METATHESIS AND AROMATIZATION Public/Granted day:2014-05-29
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