Invention Grant
- Patent Title: Optical article comprising a double-layer abrasion and scratch resistant coating and method for production thereof
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Application No.: US15264290Application Date: 2016-09-13
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Publication No.: US10222511B2Publication Date: 2019-03-05
- Inventor: Fabien Berit-Debat , Christian Bovet , Jean-Paul Cano , Amélie Kudla , Yves Leclaire
- Applicant: ESSILOR INTERNATIONAL (COMPAGNIE GENERALE D'OPTIQUE)
- Applicant Address: FR Charenton-le-Pont
- Assignee: Essilor International (Compagnie Generale d'Optique)
- Current Assignee: Essilor International (Compagnie Generale d'Optique)
- Current Assignee Address: FR Charenton-le-Pont
- Agency: Norton Rose Fulbright US LLP
- Priority: FR0655085 20061123
- Main IPC: C09D183/04
- IPC: C09D183/04 ; G02B1/14 ; G02B1/10 ; B05D3/02 ; B05D7/00 ; G02C7/02

Abstract:
The invention relates to an optical article comprising a substrate coated with an abrasion and scratch resistant coating composed of a lower layer and an upper layer that do adhere to each other, the upper layer and the lower layer being layers of cured upper and lower layer compositions, said upper layer composition comprising at least one organosilane, or a hydrolyzate thereof, of formula RnYmSi(X)4-n-m and at least one compound, or a hydrolyzate thereof, of formula M(Z)x, the following ratio being lower than 2.3: Rs = theoretical dry matter weight of compounds I in the upper layer composition theoretical dry matter weight of compounds II in the upper layer composition said lower layer composition comprising at least one organosilane, or a hydrolyzate thereof, of formula R′n′Y′m′Si(X′)4-n′-m′ and, optionally, at least one compound, or a hydrolyzate thereof, of formula M′(Z′)y, the following ratio being higher than 2.3: Ri = theoretical dry matter weight of compounds III in the lower layer composition theoretical dry matter extract of compounds IV in the lower layer composition In the hereabove formulas, M and M′ are metals or metalloids of valences x and y, at least equal to 4, R and R′ groups are monovalent organic groups that are bound to silicon through a carbon atom and that contain at least one epoxy function, X, X′, Z and Z′ groups are hydrolyzable groups, Y and Y′ are monovalent organic groups that are bound to silicon through a carbon atom, n, m, n′ and m′ being integers such that n and n′=1 or 2 with n+m and n′+m′=1 or 2.
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