An emulsion is disclosed which comprises a non-aqueous phase comprising a solid silicone resin and a siloxane carrier vehicle having an average of at least one silicon-bonded functional group per molecule and capable of carrying the solid silicone resin, an aqueous phase comprising water, and a surfactant, wherein the emulsion is substantially free from organic solvents. Various methods relating to the emulsion and end uses thereof are also disclosed. A composition comprising the emulsion and an organic binder, as well as related methods, are further disclosed.