The invention relates to a photocatalytic oil-water separation material and a preparation method thereof, the method including the following steps: cleaning a base material and a metal-doped material, and drying for later use; preparing a mixed solution of an amine monomer and an acid-alkali buffer reagent, soaking the base material in the mixed solution, and reacting under an oscillation condition, to obtain the base material attached with amine monomer polymer; dissolving a soluble metal additive and an organic ligand reagent into an organic solvent, and performing ultrasonic stirring uniformly, to obtain a metal organic framework material (MOF) reaction solution with photocatalytic performance; and placing the metal-doped material, the base material attached with the amine and the MOF reaction solution into a reaction kettle for performing hydrothermal reaction, cleaning and drying the reacted base material, to obtain the photocatalytic oil-water separation material.