Invention Application
US20170029650A1 AQUEOUS POLYMER DISPERSION FOR PAPER WITH A COPOLYMER OF VINYL ACETATE AND AN ACRYLATE MONOMER PREPARED IN THE PRESENCE OF A STARCH DERIVATIVE 审中-公开
用淀粉衍生物存在下制备的乙酸乙烯酯和丙烯酸酯单体的共聚物的纸张的水性聚合物分散体

  • Patent Title: AQUEOUS POLYMER DISPERSION FOR PAPER WITH A COPOLYMER OF VINYL ACETATE AND AN ACRYLATE MONOMER PREPARED IN THE PRESENCE OF A STARCH DERIVATIVE
  • Patent Title (中): 用淀粉衍生物存在下制备的乙酸乙烯酯和丙烯酸酯单体的共聚物的纸张的水性聚合物分散体
  • Application No.: US15303337
    Application Date: 2015-04-07
  • Publication No.: US20170029650A1
    Publication Date: 2017-02-02
  • Inventor: Nico VELINGLucia JIMENEZ GARCIADirk LAWRENZ
  • Applicant: BASF SE
  • Applicant Address: DE Ludwigshafen
  • Assignee: BASF SE
  • Current Assignee: BASF SE
  • Current Assignee Address: DE Ludwigshafen
  • Priority: EP14164346.0 20140411
  • International Application: PCT/EP2015/057456 WO 20150407
  • Main IPC: C09D131/04
  • IPC: C09D131/04 C08L31/04 D21H21/18 D21H19/56 D21H19/54 C08F218/08 C09D5/00
AQUEOUS POLYMER DISPERSION FOR PAPER WITH A COPOLYMER OF VINYL ACETATE AND AN ACRYLATE MONOMER PREPARED IN THE PRESENCE OF A STARCH DERIVATIVE
Abstract:
The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C1-C10 alkyl acrylate or a C1-C10 methacrylate, an α,β-ethlyenically unsaturated C3-C8 carboxylic acid and at least one out of glycidyl methacrylate, glycidyl acrylate, allyl methacrylate and allyl acrylate, in the presence of a starch derivative. Optionally, an additional monomer is an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated other monomer or both of them. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.
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