公开(公告)号：US20190077982A1

公开(公告)日：2019-03-14

申请号：US16185516

申请日：2018-11-09

Applicant: BASF SE

Inventor： Nico VELING ,  Lucia JIMENEZ GARCIA ,  Dirk LAWRENZ

IPC: C09D131/04 ,  C08F228/02 ,  D21H21/18 ,  D21H19/56 ,  D21H19/54 ,  C09D5/00 ,  C08L31/04 ,  C08L3/04 ,  C08F218/08

Abstract: The invention relates to an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C1-C10 alkyl acrylate or a C1-C10 methacrylate, an α,β-ethlyenically unsaturated C3-C8 carboxylic acid and at least one out of glycidyl methacrylate, glycidyl acrylate, allyl methacrylate and allyl acrylate, in the presence of a starch derivative. Optionally, an additional monomer is an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated other monomer or both of them. The aqueous polymer dispersion and a powder form thereof are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.

公开(公告)号：US20220033550A1

公开(公告)日：2022-02-03

申请号：US17299657

申请日：2019-11-21

Applicant: BASF SE

Inventor： Dirk LAWRENZ ,  Nico VELING ,  Carmen-Elena CIMPEANU

IPC: C08F212/08 ,  C08F236/06 ,  C09D109/06 ,  C08F2/22 ,  C08K3/013 ,  C08K5/14

Abstract: The present invention relates to a process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization, by polymerizing, in an aqueous medium, (a) 40 to 75 parts by weight of at least one vinylaromatic compound and (b) 24.9 to 59.9 parts by weight of at least one conjugated aliphatic diene (c) 0.1 to 10 parts by weight of at least one monomer comprising acid groups and (d) 0 to 20 parts by weight of at least one other monoethylenically unsaturated monomer, the amounts of the monomers (a) to (d) adding up to 100 parts by weight, in a monomer feed process in the presence of a free-radical initiator, with the proviso that the vinylaromatic compound is metered in under polymerization conditions in a continuous mass flow over a period of at least 120 minutes, the metering of the conjugated aliphatic diene is started at a time at which at least 5% and not more than 30% of the vinylaromatic compound has already been metered in in a continuous mass flow and optionally, the polymerization is initiated in an aqueous polymerization mixture comprising up to 5% of the vinylaromatic compound and comprising no aliphatic diene, and also to the aqueous polymer dispersions produced by the process and to the use of these as a binder, adhesive, sizing agent for fibers, for the production of coatings or for the production of a paper coating slip.

公开(公告)号：US20220033534A1

公开(公告)日：2022-02-03

申请号：US17299680

申请日：2019-11-21

Applicant: BASF SE

Inventor： Nico VELING ,  Carmen-Elena CIMPEANU ,  Dirk LAWRENZ

IPC: C08F2/22 ,  C08F2/38 ,  C08F212/08 ,  C08F220/06 ,  C08F222/02 ,  C08F236/06 ,  C08F236/08 ,  C08K5/14 ,  D21H19/58

Abstract: The present invention relates to a process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization, by polymerizing, in an aqueous medium,
(a) 40 to 75 parts by weight of at least one vinylaromatic compound and (b) 24.9 to 59.9 parts by weight of at least one conjugated aliphatic diene (c) 0.1 to 10 parts by weight of at least one monomer comprising acid groups and (d) 0 to 20 parts by weight of at least one other monoethylenically unsaturated monomer, the amounts of the monomers (a) to (d) adding up to 100 parts by weight, in a monomer feed process in the presence of at least one inorganic peroxide and at least one organic peroxide, with the proviso that the continuous metering of the inorganic peroxide starts at the same time as the continuous metering of the vinylaromatic compound, the metering of the organic peroxide is started at a time at which at least 5% and not more than 20% of the vinylaromatic compound has already been metered in in a continuous mass flow under polymerization conditions and optionally a portion of the inorganic peroxide is initially charged, and also to the aqueous polymer dispersions produced by the process and to the use of these as a binder, adhesive, sizing agent for fibers, for the production of coatings or for the production of a paper coating slip.

公开(公告)号：US20180237547A1

公开(公告)日：2018-08-23

申请号：US15753649

申请日：2016-08-19

Applicant: BASF SE

Inventor： Nico VELING ,  Dirk LAWRENZ ,  Stefan WEBER ,  Peter WACHTLER

IPC: C08F2/20 ,  C08F236/10 ,  C08F220/18 ,  C08L3/02 ,  C08L9/06 ,  C08F8/04

CPC classification number: C08F2/20 ,  C08F8/04 ,  C08F220/18 ,  C08F236/10 ,  C08F251/02 ,  C08F2800/20 ,  C08L3/02 ,  C08L9/06 ,  C09D4/00 ,  C09D103/02 ,  C09D151/02 ,  C09J4/00 ,  C09J103/02 ,  C09J151/02 ,  D21H17/28 ,  D21H19/54 ,  C08F212/08 ,  C08F220/06 ,  C08F222/02 ,  C08F236/06 ,  C08F2220/1825

Abstract: The present invention refers to a process for the preparation of an aqueous polymer dispersion, an aqueous polymer dispersion obtained by the process, a binder, an adhesive, a size suitable for at least one fiber, a covering, or a paper coating slip, comprising the aqueous polymer dispersion as well as the use of the aqueous polymer dispersion for the preparation of a binder, an adhesive, a size suitable for at least one type of fiber, a paint, a covering, or a paper coating slip.

公开(公告)号：US20180142416A1

公开(公告)日：2018-05-24

申请号：US15574755

申请日：2016-05-13

Applicant: BASF SE

Inventor： Hermann SEYFFER ,  Carmen-Elena CIMPEANU ,  Theo SMIT ,  Nico VELING ,  Juergen SCHMIDT-THUEMMES ,  Dirk LAWRENZ ,  Rainer BLUM

IPC: D21H19/20 ,  D21H27/10 ,  D21H27/18 ,  D21H19/58 ,  D21H19/54

CPC classification number: D21H19/20 ,  C08L25/14 ,  C08L33/08 ,  C08L53/02 ,  D21H19/12 ,  D21H19/22 ,  D21H19/54 ,  D21H19/58 ,  D21H21/14 ,  D21H27/10 ,  D21H27/18

Abstract: The invention relates to a use of a coating layer on a paper substrate for blocking oxygen transfer through the coated paper substrate, wherein the coating layer on the paper substrate is obtainable by a process, which comprises the steps of (a) providing a paper substrate with a surface, (b) applying onto the surface of the provided paper substrate an aqueous coating mass, and (c) drying of the paper substrate with the applied aqueous coating mass to obtain the coated paper substrate, wherein the aqueous coating mass contains an aqueous dispersion of a polymer P, which is obtainable by radically initiated emulsion polymerization of at least 25 parts by weight of a C1-C12 alkyl acrylate or a C1-C12 alkyl methacrylate based on the sum total of the parts by weight of all monomers, which is always 100, in the presence of a first degraded starch. It relates further to a coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the polymer P and a further saccharide, which is added after the polymerization of the monomers. It relates also to a process for manufacturing the coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the polymer P and the further saccharide.

公开(公告)号：US20220251248A1

公开(公告)日：2022-08-11

申请号：US17617402

申请日：2020-05-28

Applicant: BASF SE

Inventor： Carmen-Elena CIMPEANU ,  Dirk LAWRENZ

IPC: C08F2/26 ,  C08F2/38 ,  C08F212/08 ,  C08F220/06 ,  C08F236/06 ,  D21H19/58

Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion by radically initiated aqueous emulsion polymerization, which comprises polymerizing (a)
40 to 75 parts by weight of
at least one vinylaromatic compound, (b)
24.9 to 59.9 parts by weight of
at least one conjugated aliphatic diene, (c)
0.1 to 10 parts by weight of
at least one monomer containing acid groups, an (d)
0 to 20 parts by weight of
at least one other monoethylenically unsaturated monomer, where the amounts of the monomers (a) to (d) add up to 100 parts by weight, in an aqueous medium by a monomer feed process, with the proviso that monomers and emulsifier are metered continuously and following a period P1, when 15 to 30% of the total monomer metering time has elapsed and 15 to 30 wt % of the total monomer amount has been metered in, the metering rate of the emulsifier is increased for a period P2 lasting no longer than 30 minutes to 10 to 100 times the average metering rate of the emulsifier in the period P1, and also to the aqueous polymer dispersions prepared by the process and to the use thereof as a binder, adhesive, fiber sizing agent, for producing coatings or for producing a paper coating slip.

公开(公告)号：US20180135250A1

公开(公告)日：2018-05-17

申请号：US15574714

申请日：2016-05-13

Applicant: BASF SE

Inventor： Hermann SEYFFER ,  Carmen-Elena CIMPEANU ,  Theo SMIT ,  Nico VELING ,  Juergen SCHMIDT-THUEMMES ,  Dirk LAWRENZ ,  Rainer BLUM

IPC: D21H19/12 ,  D21J1/08 ,  D21H27/10 ,  D21H19/60 ,  D21H19/62 ,  C08F212/08 ,  C09D109/06

CPC classification number: D21H19/12 ,  B05D1/28 ,  B05D3/0272 ,  C08F212/08 ,  C08F236/10 ,  C08F2400/00 ,  C08F2800/20 ,  C08K2003/265 ,  C09D109/06 ,  C09D125/10 ,  D21H19/20 ,  D21H19/22 ,  D21H19/54 ,  D21H19/60 ,  D21H19/62 ,  D21H27/10 ,  D21H27/18 ,  D21J1/08 ,  C08F220/06 ,  C08L3/02

Abstract: The invention relates to a use of a coating layer on a paper substrate for blocking oxygen transfer through the coated paper substrate, wherein the coating layer on the paper substrate is obtainable by a process, which comprises the steps of (a) providing a paper substrate with a surface, (b) applying onto the surface of the provided paper substrate an aqueous coating mass, and (c) drying of the paper substrate with the applied aqueous coating mass to obtain the coated paper substrate, wherein the aqueous coating mass contains an aqueous dispersion of a copolymer P, which is obtainable by radically initiated emulsion polymerization of at least 40 parts by weight of styrene and 22 to 49 parts by weight of butadiene and optionally other monomers based on the sum total of the parts by weight of all monomers, which is always 100, in the presence of a first degraded starch. It relates further to a coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the copolymer P and a further saccharide, which is added after the polymerization of the monomers. It relates also to a process for manufacturing the coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the copolymer P and the further saccharide.

公开(公告)号：US20180362689A1

公开(公告)日：2018-12-20

申请号：US16060253

申请日：2016-11-15

Applicant: BASF SE

Inventor： Lucia JIMENEZ GARCIA ,  Carmen-Elena CIMPEANU ,  Marcus SEIBERT ,  Hermann SEYFFER ,  Dirk LAWRENZ ,  Juergen BLAUL

IPC: C08F220/18 ,  C08F2/22 ,  C08F220/32 ,  C08F220/58 ,  C08L33/06 ,  C08L97/00

Abstract: A process for preparing an aqueous dispersion of a polymer P (aqueous polymer P dispersion) by free-radically initiated aqueous emulsion polymerization.

公开(公告)号：US20170029651A1

公开(公告)日：2017-02-02

申请号：US15303415

申请日：2015-04-07

Applicant: BASF SE

Inventor： Nico VELING ,  Lucia JIMENEZ GARCIA ,  Dirk LAWRENZ

IPC: C09D131/04 ,  C08L31/04 ,  C09D5/00 ,  B05D3/12 ,  D21H19/56 ,  D21H21/18 ,  D21H19/64 ,  B05D3/02 ,  C08F218/08 ,  C09D7/12

CPC classification number: C09D131/04 ,  B05D3/0263 ,  B05D3/12 ,  B05D2203/22 ,  B05D2502/00 ,  B05D2601/02 ,  C08F218/08 ,  C08K3/26 ,  C08K2003/265 ,  C08L31/04 ,  C08L2201/54 ,  C09D5/00 ,  C09D7/61 ,  D21H17/36 ,  D21H17/37 ,  D21H19/56 ,  D21H19/58 ,  D21H19/60 ,  D21H19/64 ,  D21H21/18 ,  C08F220/02 ,  C08F220/18 ,  C08F220/32 ,  C08F2220/1825 ,  C08F2220/325 ,  C08F220/06 ,  C08F228/02

Abstract: The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C1-C10 alkyl acrylate or a C1-C10 methacrylate, an α,β-ethylenically unsaturated C3-C8 carboxylic acid, glycidyl methacrylate or glycidyl acrylate, optionally an ethylenically unsaturated sulfonic acid and optionally an ethylenically unsaturated other monomer. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.

Abstract translation: 本发明涉及一种制备聚合物P的水性分散体的方法，其包括乙酸乙烯酯的乳液聚合，丙烯酸酯单体，其是丙烯酸C1-C10烷基酯或C1-C10甲基丙烯酸酯，α，β-烯属 不饱和C3-C8羧酸，甲基丙烯酸缩水甘油酯或丙烯酸缩水甘油酯，任选的烯属不饱和磺酸和任选的烯属不饱和的其它单体。 此外，公开了从该方法得到的聚合物水分散体及其粉末形式。 它们对于含有上述形式之一的纸张涂布滑块是有用的。 涂有纸涂层纸的纸或纸板表现出表面强度，其表现为良好的耐干性，耐湿性好或耐偏移性好。 聚合物水分散体或其粉末形式还可用作粘合剂。

公开(公告)号：US20170029650A1

公开(公告)日：2017-02-02

申请号：US15303337

申请日：2015-04-07

Applicant: BASF SE

Inventor： Nico VELING ,  Lucia JIMENEZ GARCIA ,  Dirk LAWRENZ

IPC: C09D131/04 ,  C08L31/04 ,  D21H21/18 ,  D21H19/56 ,  D21H19/54 ,  C08F218/08 ,  C09D5/00

CPC classification number: C09D131/04 ,  C08F218/08 ,  C08F228/02 ,  C08L3/04 ,  C08L31/04 ,  C08L2201/54 ,  C09D5/00 ,  D21H19/54 ,  D21H19/56 ,  D21H21/18 ,  C08F2220/1825 ,  C08F2220/325 ,  C08K3/26

Abstract: The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C1-C10 alkyl acrylate or a C1-C10 methacrylate, an α,β-ethlyenically unsaturated C3-C8 carboxylic acid and at least one out of glycidyl methacrylate, glycidyl acrylate, allyl methacrylate and allyl acrylate, in the presence of a starch derivative. Optionally, an additional monomer is an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated other monomer or both of them. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.

Abstract translation: 本发明涉及一种制备聚合物P的水性分散体的方法，其包括乙酸乙烯酯的乳液聚合，丙烯酸酯单体，其是丙烯酸C1-C10烷基酯或C1-C10甲基丙烯酸酯，α，β-乙烯基 不饱和C 3 -C 8羧酸和甲基丙烯酸缩水甘油酯中的至少一种，丙烯酸缩水甘油酯，甲基丙烯酸烯丙酯和丙烯酸烯丙酯，在淀粉衍生物存在下进行。 任选地，另外的单体是烯键式不饱和磺酸，烯属不饱和的其它单体或它们两者。 此外，公开了从该方法得到的聚合物水分散体及其粉末形式。 它们对于含有上述形式之一的纸张涂布滑块是有用的。 涂有纸涂层纸的纸或纸板表现出表面强度，其表现为良好的耐干性，耐湿性好或耐偏移性好。 聚合物水分散体或其粉末形式还可用作粘合剂。