A sampling probe, system and analysis method is disclosed. The sampling probe includes a tube having at least a first bore, a second bore, a first end, and a tapered second end; a first capillary partially disposed within the first bore, at least a portion of the first capillary extending from the first end of the tube; a second capillary partially disposed within the second bore, the second capillary having a portion with a free tapered end which extends from the first end of the tube; and wherein an end of the first capillary and an end of the second capillary converge at a junction in the tapered second end of the tube.