Catalyst for the oxidation of sulfur compounds
Abstract:
In a broad form the present invention relates to a method for oxidation of a species comprising sulfur in an oxidation state below +4, such as H2S, CS2, COS and S8 vapor, to SO2 said method comprising the step of contacting the gas and an oxidant with a catalytically active material consisting of one or more elements taken from the group consisting of V, W, Ce, Mo, Fe, Ca, Mg, Si, Ti and Al in elemental, oxide, carbide or sulfide form, optionally with the presence of other elements in a concentration below 1 wt %, at a temperature between 180° C. and 290° C., 330° C., 360° C. or 450° C., with the associated benefit of such a temperature being highly energy effective, and the benefit of said elements having a low tendency to form sulfates under the conditions, with the related benefit of an increased stability of the catalytically active material. The other elements present may be catalytically active noble metals or impurities in the listed materials.
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