公开(公告)号：US09895677B2

公开(公告)日：2018-02-20

申请号：US14208014

申请日：2014-03-13

Applicant: Haldor Topsøe A/S

Inventor： Francesco Castellino ,  Joakim Reimer Thøgersen ,  Peter Schoubye

IPC: B01J23/22 ,  B01D53/56 ,  B01D53/62 ,  B01J21/06 ,  B01J35/04 ,  B01D53/86 ,  B01J21/16

CPC classification number: B01J23/22 ,  B01D53/565 ,  B01D53/62 ,  B01D53/864 ,  B01D53/865 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/915 ,  B01J21/063 ,  B01J21/16 ,  B01J35/04

Abstract: Catalyzed filter consisting of a filter body of bio-soluble fibers catalyzed with a catalyst comprising oxides of vanadium and titanium, wherein the total concentration of alkali metals in the filter body is less than 3000 ppm by weight and/or the total concentration of alkali earth metals in the filter body is less than 20% by weight.

公开(公告)号：US09776133B2

公开(公告)日：2017-10-03

申请号：US15037718

申请日：2014-11-28

Applicant: Haldor Topsøe A/S

Inventor： Peter Schoubye ,  Joakim Reimer Thøgersen

IPC: B01D53/48 ,  B01D53/86 ,  C01B17/48 ,  C01B17/50 ,  B01J35/04 ,  B01J35/00 ,  B01J23/652 ,  B01J23/888 ,  B01J21/06 ,  B01J23/30 ,  B01J35/06 ,  B01J35/10

CPC classification number: B01D53/8612 ,  B01D53/8603 ,  B01D53/8606 ,  B01D53/864 ,  B01D53/869 ,  B01D2255/1023 ,  B01D2255/207 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/904 ,  B01D2257/30 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2257/502 ,  B01D2258/0283 ,  B01J21/063 ,  B01J23/30 ,  B01J23/6527 ,  B01J23/888 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/06 ,  B01J35/1033

Abstract: In a broad form the present invention relates to a method for oxidation of a species comprising sulfur in an oxidation state below +4, such as H2S, CS2, COS and S8 vapor, to SO2 said method comprising the step of contacting the gas and an oxidant with a catalytically active material consisting of one or more elements taken from the group consisting of V, W, Ce, Mo, Fe, Ca, Mg, Si, Ti and Al in elemental, oxide, carbide or sulfide form, optionally with the presence of other elements in a concentration below 1 wt %, at a temperature between 180° C. and 290° C., 330° C., 360° C. or 450° C., with the associated benefit of such a temperature being highly energy effective, and the benefit of said elements having a low tendency to form sulfates under the conditions, with the related benefit of an increased stability of the catalytically active material. The other elements present may be catalytically active noble metals or impurities in the listed materials.

公开(公告)号：US20160296889A1

公开(公告)日：2016-10-13

申请号：US15037718

申请日：2014-11-28

Applicant: HALDOR TOPSØE A/S

Inventor： Peter Schoubye ,  Joakim Reimer Thøgersen

IPC: B01D53/86 ,  B01J23/652 ,  B01J35/04 ,  B01J35/00 ,  B01J35/06 ,  B01J23/30 ,  B01J21/06

CPC classification number: B01D53/8612 ,  B01D53/8603 ,  B01D53/8606 ,  B01D53/864 ,  B01D53/869 ,  B01D2255/1023 ,  B01D2255/207 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/904 ,  B01D2257/30 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2257/502 ,  B01D2258/0283 ,  B01J21/063 ,  B01J23/30 ,  B01J23/6527 ,  B01J23/888 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/06 ,  B01J35/1033

Abstract: In a broad form the present invention relates to a method for oxidation of a species comprising sulfur in an oxidation state below +4, such as H2S, CS2, COS and S8 vapor, to SO2 said method comprising the step of contacting the gas and an oxidant with a catalytically active material consisting of one or more elements taken from the group consisting of V, W, Ce, Mo, Fe, Ca, Mg, Si, Ti and Al in elemental, oxide, carbide or sulfide form, optionally with the presence of other elements in a concentration below 1 wt %, at a temperature between 180° C. and 290° C., 330° C., 360° C. or 450° C., with the associated benefit of such a temperature being highly energy effective, and the benefit of said elements having a low tendency to form sulfates under the conditions, with the related benefit of an increased stability of the catalytically active material. The other elements present may be catalytically active noble metals or impurities in the listed materials.

Abstract translation: 在广泛的形式中，本发明涉及一种氧化低于+4的氧化态的硫的物质如H2S，CS2，COS和S8蒸气的方法，所述方法包括使气体和 氧化剂与由元素，氧化物，碳化物或硫化物形式的V，W，Ce，Mo，Fe，Ca，Mg，Si，Ti和Al组成的组中的一种或多种元素组成的催化活性材料， 存在浓度低于1重量％的其它元素，在180℃至290℃，330℃，360℃或450℃之间的温度下，这种温度的相关益处是 高能量有效，并且所述元素在条件下具有较低的形成硫酸盐倾向的益处，并且具有增加的催化活性材料的稳定性的相关益处。 存在的其它元素可以是所列材料中的催化活性的贵金属或杂质。