NCC-BASED SUPRAMOLECULAR MATERIALS FOR THERMOPLASTIC AND THERMOSET POLYMER COMPOSITES

    公开(公告)号:CA2848337C

    公开(公告)日:2018-04-24

    申请号:CA2848337

    申请日:2012-09-12

    Applicant: CELLUFORCE INC

    Abstract: Nanocrystalline cellulose (NCC)-based supramolecular materials, a method for their preparation and their use in thermoplastic and thermoset polymer composites are disclosed. Supramolecular materials of NCC and one or two polymers are synthesized by in situ surface graft copohmerization in a multitude of solvent systems, including water. The nano-scale size supramolecular materials are engineered to have a unique combination of lowr polarity and high hydrophobicity and function as copohmers for demanding pohmeric systems such as, but not limited to, polyolefins and polyesters. Nanocomposite materials of enhanced functionality and mechanical properties are produced by compounding the NCC-based supramolecular materials with polymer matrices. The supramolecular materials are used in composite development for packaging materials, structural composites for automotive and construction, as sandwiched foam composites or, combined with biocompatible polymers, in medical applications.

    POLYURETHANE COMPOSITES COMPRISING NANOCRYSTALLINE CELLULOSE AND METHOD FOR IMPROVING PROPERTIES OF POLYURETHANES THEREOF

    公开(公告)号:CA2913359A1

    公开(公告)日:2014-12-04

    申请号:CA2913359

    申请日:2014-05-22

    Applicant: CELLUFORCE INC

    Abstract: The disclosure relates to polyurethane (PU) composites comprising nanocrystalline cellulose (NCC) and methods for improving tensile strength and elongation. The process to prepare the polyurethane comprises providing a dispersion of NCC in (a)one or more polyols, (b) one or more isocyanates, or (c) one or more polyols and one or more isocyanate, separately or mixed together, mixing with a catalyst and isolating the polyurethane. Preferred embodiments include an NCC content of less than 5%, dried NCC starting material, and the NCC being fully dispersed and not aggregated. The polyurethane may be used in elastomeric fibres, paints, solid polyurethane plastics, thermoplastic and cast elastomers and adhesives and/or binders.

    NCC-BASED SUPRAMOLECULAR MATERIALS FOR THERMOPLASTIC AND THERMOSET POLYMER COMPOSITES

    公开(公告)号:CA2848337A1

    公开(公告)日:2013-03-21

    申请号:CA2848337

    申请日:2012-09-12

    Applicant: CELLUFORCE INC

    Abstract: Nanocrystalline cellulose (NCC)-based supramolecular materials, a method for their preparation and their use in thermoplastic and thermoset polymer composites are disclosed. Supramolecular materials of NCC and one or two polymers are synthesized by in situ surface graft copohmerization in a multitude of solvent systems, including water. The nano-scale size supramolecular materials are engineered to have a unique combination of lowr polarity and high hydrophobicity and function as copohmers for demanding pohmeric systems such as, but not limited to, polyolefins and polyesters. Nanocomposite materials of enhanced functionality and mechanical properties are produced by compounding the NCC-based supramolecular materials with polymer matrices. The supramolecular materials are used in composite development for packaging materials, structural composites for automotive and construction, as sandwiched foam composites or, combined with biocompatible polymers, in medical applications.

    POLYDOPAMINE FUNCTIONALIZED CELLULOSE NANOCRYSTALS (PD-CNCS) AND USES THEREOF

    公开(公告)号:CA2955248A1

    公开(公告)日:2016-01-28

    申请号:CA2955248

    申请日:2015-07-17

    Applicant: CELLUFORCE INC

    Abstract: The present disclosure relates to use of polydopamine (PD) coated cellulose nanocrystals (CNCs) as template for further conjugation of functional oligomers (amines, carboxylic acids etc.) and the immobilization of various types of CNC hybrid nanomaterial nanoparticles to improve their stability in aqueous solution, e.g. the preparation of silver nanoparticle on CNC. Surface functionalization of CNC with polydopamine can be performed by mixing dopamine and CNCs for certain time at designed temperature. The resultant PD-CNCs can be used to stabilize metallic and inorganic nanoparticles, which could be generated in-situ, and further immobilized on the surface of PD coated CNCs. Benefiting from the improved stability, the resultant nanoparticles immobilized PD-CNC system also generally possess higher catalytic activity than the nanoparticles alone.

    NCC AS FUNCTIONAL SCAFFOLD FOR AMINE-CURED EPOXY NANOCOMPOSITE MATERIALS OF TUNABLE PROPERTIES

    公开(公告)号:CA2890653A1

    公开(公告)日:2014-05-15

    申请号:CA2890653

    申请日:2013-11-12

    Applicant: CELLUFORCE INC

    Abstract: The disclosure relates to a novel process for functionalizing NCC, a method for producing amine-cured epoxy-based nanocomposites through the use of said functionalized NCC, and nanocomposites thereof. The process for functionalizating NCC comprises providing a mixture of NCC and one or more monomers. The mixture is suitable for free radical polymerization and the monomer is cross-linkable with epoxy and is aqueous soluble. The polymerization takes place in the presence of a free radical initiator and oxygen is purged from the mixture and the initiator solution. The epoxy-based nanocomposite is produced by mixing the funtionalized NCC with an amine-curable epoxy resin and a hardener, in a solvent, and allowing the mixture to cure.

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