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1.
公开(公告)号:US20210292570A1
公开(公告)日:2021-09-23
申请号:US17260326
申请日:2019-08-19
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Matthew H. Frey , Ta-Hua Yu , Moses M. David , Richard J. Pokorny , Jun Ma
Abstract: The present disclosure provides an article including an organic layer having a nanostructured first surface including nanofeatures defining nanorecesses and an opposing second surface; and a ceramic layer disposed on the nanostructured first surface of the organic layer and filling at least a portion of the nanorecesses. The ceramic layer has a nanostructured first surface including nanofeatures and an opposing second surface, and the nanostructured first surface of the ceramic layer is interpenetrated with the nanostructured first surface of the organic layer. The present disclosure also provides a method of making the article. The method includes obtaining an organic layer having a nanostructured first surface including nanofeatures defining nanorecesses and an opposing second surface; and filling at least a portion of the nanorecesses of the nanostructured first surface of the organic layer with a ceramic material to form the article. In addition, the present disclosure provides articles including interpenetrating layers having different elastic storage moduli, such as non-metallic layers, and methods of making the articles. The articles can exhibit high abrasion resistance.
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公开(公告)号:US10752811B2
公开(公告)日:2020-08-25
申请号:US15748219
申请日:2016-08-11
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Richard Y. Liu , Victor Ho , Jun Ma
IPC: C08G63/00 , C09J7/38 , C09J11/06 , C08G83/00 , C08G63/54 , C09J167/06 , C08K5/00 , C09J167/02 , C09J167/07 , G01N25/48
Abstract: A polyester including at least one crosslinkable moiety is described. Each crosslinkable moiety includes at least one crosslinkable pendent group. A ratio of a total number of the at least one crosslinkable pendent groups to a total number of ester groups in the polyester may be in a range of 0.0001 to 0.5.
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公开(公告)号:US11384212B2
公开(公告)日:2022-07-12
申请号:US16619267
申请日:2018-06-07
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Xue Tian , Naiyong Jing , Jun Ma
IPC: C08J7/056 , C08J7/06 , C08J7/043 , C08J7/046 , C09D7/40 , C09D7/62 , C08J7/04 , C09D1/02 , C09D4/00 , C09D5/00 , C09D5/16 , C08K3/36
Abstract: A film including: an organic polymeric substrate having a first major surface and a second major surface; an optional acrylic hardcoat layer disposed on the first major surface of the substrate; a siliceous primer layer disposed on the organic polymeric substrate or on the optional acrylic hardcoat layer, wherein the siliceous primer layer includes silica nanoparticles modified by an organic silane; and a superhydrophilic surface layer disposed on the siliceous primer layer, wherein the superhydrophilic surface layer includes hydrophilic-functional groups.
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4.
公开(公告)号:US20200157302A1
公开(公告)日:2020-05-21
申请号:US16619363
申请日:2018-06-07
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Naiyong Jing , Xue Tian , Jun Ma , Garry W. Lachmansingh
Abstract: A film including: an organic polymeric substrate having a first major surface and a second major surface; an optional acrylic hardcoat layer disposed on the first major surface of the substrate; a siliceous primer layer disposed on the organic polymeric substrate or on the optional acrylic hardcoat layer, wherein the siliceous primer layer includes composite particles including an organic polymer portion and a siliceous portion; and a superhydrophilic surface layer disposed on the siliceous primer layer, wherein the superhydrophilic surface layer includes hydrophilic-functional groups.
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公开(公告)号:US20200002564A1
公开(公告)日:2020-01-02
申请号:US16484518
申请日:2018-02-19
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Naiyong Jing , Jun Ma , Erika Saffer , David M. Mahli , Gezahegn D. Damte
IPC: C09D135/02 , C09D5/00 , C09D133/14 , C08F222/10 , C08F220/34 , B43L1/00
Abstract: Dry erase articles are described comprising a writable surface layer comprising a cured hardcoat composition comprising the reaction product of certain low surface energy compound(s). In one embodiment, the compound(s) comprise a C18-C36 hydrocarbon group and an ethylenically unsaturated group. In another embodiment, a mixture of compounds is utilized, the mixture comprising first compounds comprising a C18-C36 hydrocarbon group and an ethylenically unsaturated group and second compounds comprising a C8-C17 hydrocarbon group and an ethylenically unsaturated group, wherein the first and second compound are present at a weight ratio of 3:2 to 4:1.
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公开(公告)号:US20210340404A1
公开(公告)日:2021-11-04
申请号:US17284521
申请日:2019-10-08
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jun Ma , Naiyong Jing , Moses M. David
IPC: C09D183/14 , C08G77/54 , C09D5/00 , C07F7/08 , C07F9/38
Abstract: Described herein are compositions including a silanol compound that is suitably synthesized, stored, and coated from an aqueous solution. Once coated and cured on a suitable surface, the aqueous silanol compositions result in cleanable and abrasion resistant surfaces, such as dry-erase surfaces that release permanent marker by rubbing with a dry cloth or towel. Also disclosed herein are methods of making the silanol compounds, methods of making cleanable substrates, and cleanable substrates suitably formed using the disclosed methods.
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7.
公开(公告)号:US20230357520A1
公开(公告)日:2023-11-09
申请号:US18026268
申请日:2021-09-23
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Naiyong Jing , Xue Tian , Jun Ma , Jordan C. DuCharme , Gezahegn D. Damte , Xi Chen
CPC classification number: C08J7/06 , C08J7/056 , C08K5/541 , C08G77/18 , C08K3/36 , C09D183/06 , C09D7/61 , C08J2367/02
Abstract: Articles are described comprising a substrate and a hardcoat layer disposed on the substrate. The hardcoat layer comprises the hydrolyzed and condensed reaction product of a composition comprising: i) first hydrophobic silane monomer(s) having the formula R1Si(OR)3 wherein R and R1 is methyl or ethyl; ii) optional second silane monomer(s) having the formula (R2)4-mSi(OR)m or Si(OR)4, wherein R, R1 and R2 are organic groups with the proviso that R1 is not methyl or ethyl and m ranges from 1 to 3. The hardcoat layer N may further comprises 10 to 30 wt. % silica nanoparticles. A surface layer comprising a hydrophilic silane may be disposed on the hardcoat layer. Also described is a method of using an article having a rewritable surface, hardcoat coating compositions, and methods of making hardcoat compositions and articles.
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公开(公告)号:US11535721B2
公开(公告)日:2022-12-27
申请号:US16619363
申请日:2018-06-07
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Naiyong Jing , Xue Tian , Jun Ma , Garry W. Lachmansingh
IPC: C08J7/06 , C08K3/08 , C08K3/36 , C08K9/02 , C08K9/08 , C08J7/04 , C08K5/5415 , C08J7/043 , C08J7/046 , C08J7/056
Abstract: A film including: an organic polymeric substrate having a first major surface and a second major surface; an optional acrylic hardcoat layer disposed on the first major surface of the substrate; a siliceous primer layer disposed on the organic polymeric substrate or on the optional acrylic hardcoat layer, wherein the siliceous primer layer includes composite particles including an organic polymer portion and a siliceous portion; and a superhydrophilic surface layer disposed on the siliceous primer layer, wherein the superhydrophilic surface layer includes hydrophilic-functional groups.
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公开(公告)号:US20210070008A1
公开(公告)日:2021-03-11
申请号:US16960272
申请日:2019-01-08
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jon P. Nietfeld , Adam J. Meuler , Moses M. David , Richard J. Pokorny , Paul B. Armstrong , Jun Ma , Molly J. Smith , Haeen Sykora , Chad M. Amb
Abstract: A vehicle sensor system comprising an exterior surface and a polymeric film on the exterior surface. The polymeric film has a first surface opposite the exterior surface, and the first surface is either hydrophobic or hydrophilic.
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公开(公告)号:US20210371615A1
公开(公告)日:2021-12-02
申请号:US16619267
申请日:2018-06-07
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Xue Tian , Naiyong Jing , Jun Ma
Abstract: A film including: an organic polymeric substrate having a first major surface and a second major surface; an optional acrylic hardcoat layer disposed on the first major surface of the substrate; a siliceous primer layer disposed on the organic polymeric substrate or on the optional acrylic hardcoat layer, wherein the siliceous primer layer includes silica nanoparticles modified by an organic silane; and a superhydrophilic surface layer disposed on the siliceous primer layer, wherein the superhydrophilic surface layer includes hydrophilic-functional groups.
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