公开(公告)号：WO2014105105A1

公开(公告)日：2014-07-03

申请号：PCT/US2013/028519

申请日：2013-03-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  KALGUTKAR, Rajdeep S. ,  ELLIS, Mark F. ,  JACOBSEN, John R. ,  KUMAR, Ramesh C. ,  MORRIS, Mary L. ,  LOCKETT, Michael A. ,  BEHNKE, Jesse R.

Inventor： KALGUTKAR, Rajdeep S. ,  ELLIS, Mark F. ,  JACOBSEN, John R. ,  KUMAR, Ramesh C. ,  MORRIS, Mary L. ,  LOCKETT, Michael A. ,  BEHNKE, Jesse R.

IPC: C07F7/18 ,  C08L83/04 ,  C08G77/04

CPC classification number: C08F220/18 ,  C08F220/14 ,  C08F2220/1891 ,  C08G63/695 ,  C08J5/00 ,  C08J2333/08 ,  C08J2333/12 ,  C08J2433/08 ,  C08J2433/12 ,  C08J2433/20 ,  C08J2483/00 ,  C08F2230/085

Abstract: A composition including at least one moisture-curable, semi-crystalline (meth)acrylic oligomer represented by the formula: wherein R 1 is independently a C 16 to C 40 alkyl group; R 2 is independently a C 16 to C 40 alkyl group; each R 3 is independently a methyl, ethyl, or isopropyl group; X is a chain transfer agent as defined further below; Y is independently selected to be a methyl, ethyl, or isopropyl group; a, b and c are each independently selected to be an integer of at least 10, and a + b + c ≤ 1500; n ≥ 1; and p is 0, 1, 2, or 3. The oligomer may be used advantageously as a coating, primer or adhesion promoter in construction articles, for example, adhesives, caulks, grouts, pavement markings, paving materials, ceramic tiles, or roofing granules.

Abstract translation: 一种组合物，其包含至少一种由下式表示的可湿气固化的半结晶（甲基）丙烯酸低聚物：其中R1独立地为C16至C40烷基; R2独立地为C16〜C40烷基; 每个R 3独立地是甲基，乙基或异丙基; X是如下进一步定义的链转移剂; Y独立选择为甲基，乙基或异丙基; a，b和c各自独立选择为至少10的整数，a + b +c≤1500; n≥1; 并且p为0,1,2或3.低聚物可有利地用作施工制品中的涂层，底漆或粘合促进剂，例如粘合剂，填缝剂，浆料，路面标记，铺路材料，陶瓷砖或屋顶 颗粒。

公开(公告)号：WO2010077811A1

公开(公告)日：2010-07-08

申请号：PCT/US2009/067855

申请日：2009-12-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  SETH, Jayshree ,  QIU, Zai-Ming ,  BOULOS, Marie A. ,  SEMONICK, Michael A. ,  KUMAR, Ramesh C.

Inventor： SETH, Jayshree ,  QIU, Zai-Ming ,  BOULOS, Marie A. ,  SEMONICK, Michael A. ,  KUMAR, Ramesh C.

IPC: C08L83/08 ,  C08L27/16

CPC classification number: C09J7/0228 ,  C08L27/12 ,  C08L27/16 ,  C08L83/08 ,  C09J7/401 ,  Y10T428/1457 ,  Y10T428/2839 ,  Y10T428/31663 ,  C08L83/00 ,  C08L2666/14 ,  C08L2666/04

Abstract: Blended release materials including a blend of a fluoro-functional silicone release polymer and a fluoropolymer are described. Exemplary fluoropolymers include fluoroolefin-based polymers and linear fluoropolymers including linear fluoroacryaltes. Articles including such release materials such as release liners, and adhesive articles, including silicone adhesive articles, are also described.

Abstract translation: 描述了包括氟官能硅氧烷释放聚合物和含氟聚合物的共混物的混合释放材料。 示例性的含氟聚合物包括基于氟烯烃的聚合物和包括直链氟代丙烯酸酯的直链含氟聚合物。 还描述了包括诸如防粘衬垫的释放材料和粘合剂制品的制品，包括硅酮粘合剂制品。

公开(公告)号：WO2022043786A1

公开(公告)日：2022-03-03

申请号：PCT/IB2021/056770

申请日：2021-07-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： SEMONICK, Michael A. ,  DAMIEN, Kathryn S. ,  KUMAR, Ramesh C.

IPC: C08F2/48 ,  C08F220/18 ,  C08F290/06 ,  C09J4/00 ,  C09J4/06 ,  C09J7/38 ,  C09J7/40 ,  C09D4/00 ,  C09D4/06

Abstract: A method of making a release coated article is described comprising: providing a release coating composition comprising at least 50 wt.% of a mixture of ethylenically unsaturated monomers based on the total ethylenically unsaturated components; wherein the mixture comprises monomer(s) with a linear alkyl group with at least 18 carbon atoms, and monomer(s) with a branched alkyl group with 7 to 31 carbon atoms, and crosslinking component(s) comprising at least two ethylenically unsaturated groups. The method comprises applying the release coating to a major surface of a substrate and polymerizing the monomer(s) and crosslinking component(s) of the release coating. The monomer(s) with linear alkyl groups and branched alkyl groups are typically present at a weight ratio such that the release coating is a liquid at 25°C. Also described are release coating compositions and articles.

公开(公告)号：WO2020261037A1

公开(公告)日：2020-12-30

申请号：PCT/IB2020/055578

申请日：2020-06-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： WIENER, Clinton G. ,  ALI, Mahfuza B. ,  APPEANING, Maria A. ,  EL HEDOK, Ibrahim A. ,  HENNA, Phillip H. ,  KUMAR, Ramesh C.

IPC: C08F120/34 ,  C08F220/34 ,  C09D133/14

Abstract: Described herein is a latex coating composition comprising particles of polymer and articles therefrom, wherein at least 60 % of interpolymerized monomeric units of the polymer are of formula I, wherein R 3 is H or CH 3 , L is an alkylene group comprising 1-4 carbon atoms, R 1 and R 2 are independently selected from an alkyl group comprising 1 to 3 carbon atoms, n is an integer from 11 to 21, and A is a counter anion.

公开(公告)号：WO2010077487A3

公开(公告)日：2010-07-08

申请号：PCT/US2009/065519

申请日：2009-11-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  SHERMAN, Audrey A. ,  ELLIS, Mark F. ,  KUMAR, Ramesh C. ,  MACKEY, Sonja S. ,  PELOQUIN, Richard L. ,  EMSLANDER, Jeffrey O.

Inventor： SHERMAN, Audrey A. ,  ELLIS, Mark F. ,  KUMAR, Ramesh C. ,  MACKEY, Sonja S. ,  PELOQUIN, Richard L. ,  EMSLANDER, Jeffrey O.

IPC: C08F230/08 ,  C08F210/02 ,  C09J183/04 ,  C09J123/04

Abstract: Methods for preparing silicone-containing polymers by essentially adiabatic polymerization methods are disclosed. The polymerization system includes free radically polymerizable monomers. The monomers include ethylenically unsaturated silicone-containing monomers and/or mercapto-functional silicones as well as additional free radically polymerizable monomers. The silicone-containing polymers are useful as adhesives or release materials.

公开(公告)号：WO2019058231A1

公开(公告)日：2019-03-28

申请号：PCT/IB2018/057025

申请日：2018-09-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： RATHORE, Jitendra S. ,  KUMAR, Ramesh C. ,  JARIWALA, Chetan P.

IPC: C09D183/04 ,  C09D183/06 ,  C09D183/08 ,  C08G77/04 ,  C08G77/14 ,  C08G77/26 ,  C08G77/28 ,  C09J7/20

Abstract: A composition, and article including such composition, wherein the composition includes a silsesquioxane polymer and a free siloxane; wherein the silsesquioxane polymer includes a three- dimensional network of Formula (I): wherein: each R 1 and R 2 is independently a (C1-C4)alkyl; each L 1 and L 2 is independently a single bond, an alkylene, or an alkylene bonded to a group selected from oxy, thio, carbonyl, -NH-, and combinations thereof; each R 3 is independently a linear (C14-C100)alkyl; each R5 is independently a (C1-C30)alkyl, a (C1-C30)fluorinated alkyl, or a (C2- C30)heteroalkyl having at least one oxygen, sulfur, or -NH- group; with the proviso that L 1 , L 2 , and R5 are selected such that each Si atom is directly bonded to an alkylene or an alkyl; m is an integer of at least 2; n is an integer of 0 or above; m + n is an integer of at least 10; each oxygen atom at an asterisk (*) is bonded to another Si atom within the three-dimensional network; and the silsesquioxane polymer is a solid at 25°C.

公开(公告)号：WO2018128965A1

公开(公告)日：2018-07-12

申请号：PCT/US2018/012033

申请日：2018-01-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： PARTHASARATHY, Ranjani V. ,  KUMAR, Ramesh C. ,  SCHOLZ, Matthew T. ,  SWANSON, Steven P. ,  VAIL, Andrew W. ,  RASMUSSEN, Jerald K. ,  GRIESGRABER, George W. ,  HEAPY, Catherine D.

IPC: A01N47/44 ,  A61K8/34 ,  A61L2/18 ,  A61Q19/00

Abstract: Disclosed herein are methods that include contacting a skin surface with a first liquid composition; and then contacting the skin surface with a cationic coated article loaded with a second liquid composition, while at least some portion of the first liquid composition remains on the skin surface, wherein one or both of the first liquid composition or the second liquid composition includes acrylate copolymer particles dispersed therein, the acrylate copolymer particles including the reaction product of a reaction mixture, the reaction mixture including monomers, the monomers including from about 5 wt% to about 50 wt% of at least one high Tg monomer where the wt% of the high Tg monomer is with respect to the total weight of the monomers in the reaction mixture; and from about 20 wt% to about 80 wt% of at least one low Tg monomer where the wt% of the low Tg monomer is with respect to the total weight of the monomers in the reaction mixture, wherein the particles have a number average diameter of at least about 100 nm and wherein at least one and only one of the first or the second composition comprises greater than or equal to 60 wt% of at least one alcohol.

公开(公告)号：WO2017003923A1

公开(公告)日：2017-01-05

申请号：PCT/US2016/039554

申请日：2016-06-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： PARTHASARATHY, Ranjani V. ,  KUMAR, Ramesh C. ,  SCHOLZ, Matthew T. ,  SWANSON, Steven P. ,  SATTERWHITE, Erin A.

IPC: A61K8/34 ,  A61Q17/00 ,  A61K8/81 ,  A61K8/02

CPC classification number: A61K8/0241 ,  A61K8/34 ,  A61K8/8152 ,  A61K2800/412 ,  A61Q17/005

Abstract: Disclosed herein are compositions that include at least about 85 wt% of a hydroalcoholic solution that includes at least about 1 wt% water; and about 30 to about 85 wt% of at least one C1 to C4 alkyl alcohol based on the total weight of the hydroalcoholic solution; and acrylate copolymer particles dispersed in the hydroalcoholic solution, the acrylate copolymers particles being the reaction product of a reaction mixture, the reaction mixture including monomers, the monomers including from about 5 wt% to about 50 wt% of at least one high Tg monomer; and from about 20 w% to about 80 wt% of at least one low Tg monomer where the wt% of the low and high Tg monomers are with respect to the total weight of the monomers in the reaction mixture, wherein the particles have a number average diameter of at least about 100 nm.

Abstract translation: 本文公开了包含至少约85重量％的包含至少约1重量％的水的醇醇溶液的组合物; 和约30至约85重量％的至少一种C1至C4烷基醇，基于该水醇溶液的总重量; 和丙烯酸酯共聚物颗粒分散在水醇溶液中，丙烯酸酯共聚物颗粒是反应混合物的反应产物，反应混合物包括单体，包含约5重量％至约50重量％的至少一种高Tg单体的单体; 和约20重量％至约80重量％的至少一种低Tg单体，其中低Tg和高Tg单体的wt％相对于反应混合物中单体的总重量，其中颗粒具有数量 平均直径为至少约100nm。

公开(公告)号：WO2012054680A1

公开(公告)日：2012-04-26

申请号：PCT/US2011/057006

申请日：2011-10-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  COGGIO, William D. ,  KUMAR, Ramesh C. ,  WHEATLEY, John A. ,  STEINER, Michael L. ,  EDMONDS, William F. ,  LIU, Lan H. ,  HAO, Encai ,  KAMRATH, Robert F. ,  STRADINGER, John J.

Inventor： COGGIO, William D. ,  KUMAR, Ramesh C. ,  WHEATLEY, John A. ,  STEINER, Michael L. ,  EDMONDS, William F. ,  LIU, Lan H. ,  HAO, Encai ,  KAMRATH, Robert F. ,  STRADINGER, John J.

IPC: G02B1/10 ,  G02B1/11

CPC classification number: G02B1/14 ,  G02B1/105 ,  G02B1/11 ,  G02B2207/107 ,  Y10T428/24975 ,  Y10T428/24997

Abstract: An optical article includes an optical element, a low refractive index layer disposed on the optical element having an effective refractive index of 1.3 or less and a polymeric protective layer disposed on the low refractive index layer. The low refractive index layer includes a binder, a plurality of metal oxide particles dispersed in the binder, and a plurality of interconnected voids. The polymeric protective layer does not increase an effective refractive index of the optical article by greater than 10%.

Abstract translation: 光学制品包括光学元件，设置在光学元件上的有效折射率为1.3或更小的低折射率层和设置在低折射率层上的聚合物保护层。 低折射率层包括粘合剂，分散在粘合剂中的多个金属氧化物颗粒和多个互连的空隙。 聚合物保护层不会使光学制品的有效折射率增加大于10％。

公开(公告)号：WO2011090644A3

公开(公告)日：2011-07-28

申请号：PCT/US2010/061274

申请日：2010-12-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  HANSEN, Richard G. ,  HAYS, David S. ,  IYER, Suresh S. ,  FRANK, John W. ,  KUMAR, Ramesh C.

Inventor： HANSEN, Richard G. ,  HAYS, David S. ,  IYER, Suresh S. ,  FRANK, John W. ,  KUMAR, Ramesh C.

IPC: C07F7/18 ,  C07F7/10 ,  C08G77/04 ,  C08L83/04 ,  C09J183/04

Abstract: Siloxane-containing reactive compounds contain moisture-curable alkoxy-silane functional end groups. The siloxane-containing reactive compounds may be prepared from siloxane-containing oxamide compounds or amine compounds. Siloxane-containing polymers may be prepared from the reactive compounds by reaction with water. The siloxane-containing polymers may be release materials or adhesives.