Abstract:
The invention relates to a method for producing aqueous active substance compositions of active substances that are hardly soluble in water, especially of active substances for use in the protection of plants and materials. The invention also relates to the active substance compositions obtained according to the inventive method and to their use in the control of harmful organisms in the protection of plants and materials. The inventive method comprises the following steps: a) providing an aqueous suspension of solid active substance particles of at least one active substance having a water solubility of not more than 5 g/l at 25 °C/1013 mbar and comprising at least one surface-active substance for stabilizing the active substance particles, whereby the active substance particles in the suspension have an average particle size, determined by dynamic light scattering, of not more than 1200 nm; b) emulsion polymerization of a first monomer composition M1 in the aqueous suspension of the active substance, whereby the monomer composition M1 comprises at least 95 % by weight, based on its total weight, of at least one neutral, monoethylenically unsaturated monomer M1.1 having a water solubility of not more than 30 g/l at 25 °C/1013 mbar, thereby obtaining an aqueous dispersion of polymer/active substance particles; and c) emulsion polymerization of a second monomer composition M2 in an aqueous dispersion of the polymer/active substance particles obtained in step b), whereby the monomer composition M2 comprises at least 60 % by weight, based on its total weight, of at least one neutral, monoethylenically unsaturated monomer M2.1 having a water solubility of not more than 30 g/l at 25 °C/1013 mbar.
Abstract:
The present invention relates to a microcapsular powder having a latent heat storage material as a capsule core and a capsule wall constructed of from 10% to 100% by weight of one or more C1-C24-alkyl esters of acrylic and/or methacrylic acid (monomers I), from 0% to 80% by weight of a water-insoluble or substantially water-insoluble bi- or polyfunctional monomer (monomers II), and from 0% to 90% by weight of other monomers (monomer III) all based on the total weight of the monomers, having an average particle size in the range of 150-400 μm and having 80% by weight of particles ≧90 μm in diameter, to a process for its production and to its use in bindered building materials, textiles and dumped beds.
Abstract:
La presente invencion se refiere a composiciones acuosas insecticidas en forma de una dispersion acuosa de particulas polimericas finas que contienen un principio activo organico insecticida con una hidrosolubilidad no mayor de 5 g/l a 25 degree C / 1013 milibares, en la que el tamano medio de esas particulas, determinado por dispersion dinamica de la luz, no es mayor de 300 nm, y las particulas polimericas que contienen el principio activo insecticida, que es por lo menos uno, presentan una carga superficial cationica y la dispersion acuosa de las particulas polimericas que contienen el principio activo pueden obtenerse mediante polimerizacion en emulsion acuosa por radicales de una composicion monomerica de monomeros M etilenicamente insaturados, conteniendo los monomeros M etilenicamente insaturados el principio activo insecticida, que es por lo menos uno, en forma disuelta. La invencion se refiere tambien al uso de esas composiciones acuosas insecticidas al efecto de proteger materiales que contienen lignocelulosa, en particular maderas, del ataque de insectos que los danan.
Abstract:
The present invention relates to the production of a polymer powder with improved powder properties, and to its use as impact modifier for rigid polyvinyl chloride (PVC) applications. The impact modifier is composed of emulsion polymer particles which have a core-shell structure, where the shell is composed of a hard polymer and the core is composed of a soft, crosslinked rubber polymer.
Abstract:
The invention relates to the production of a polymer powder with improved pulverulent characteristics and to the use of said powder as an impact- resistance modifier for hard polyvinyl chloride (PVC) applications. The impa ct- resistance modifier consists of emulsion polymer particles with a core-shell structure, said shell being composed of a hard polymer and the core of a sof t, vulcanised rubber polymer.
Abstract:
ES REFERIDA A UN PROCEDIMIENTO DE PREPARACION QUE COMPRENDE: A) PREPARACION DE UNA SUSPENSION ACUOSA DE PARTICULAS SOLIDAS DE PRINCIPIO ACTIVO ESTABILIZADAS CON UNA SUSTANCIA TENSOACTIVA NO IONICA, DICHAS PARTICULAS SOLIDAS PRESENTAN UN TAMANO NO MAS DE 1200 NM; B) POLIMERIZACION DE EMULSIONES DE UNA COMPOSICION MONOMERICA QUE COMPRENDE DE 95 A 99% EN PESO DE M1 SELECCIONADOS ENTRE ESTIRENO, ESTERES DE ACIDO ACRILICO, ETILENO, ENTRE OTROS; EN LA SUSPENSION ACUOSA DE PRINCIPIO ACTIVO OBTENIDO EN LA ETAPA A); Y C) POLIMERIZACION DE EMULSIONES DE UNA SEGUNDA COMPOSICION MONOMERICA QUE COMPRENDE ENTRE 70 A 80% EN PESO DE M2 SELECCIONADOS ENTRE MONOMEROS VINILAROMATICOS, METACRILATO DE METILO O CICLOALCANOLES(C3-C10), EN UNA DISPERSION ACUOSA OBTENIDA EN B). DICHO PROCEDIMIENTO PONE A DISPOSICION PREPARACIONES ACUOSAS DE PRINCIPIO ACTIVO CON UNA HIDROSOLUBILIDAD DE NO MAS 5 G/L A 25 °C/1013 MBAR, TALES COMO INSECTICIDAS, FUNGICIDAS, HERBICIDAS, REGULADORES DE CRECIMIENTO
Abstract:
Perfume polymeric particles, polymeric particles having affinities for certain perfume raw materials, compositions containing them and methods for making the same are provided.
Abstract:
The present invention relates to aqueous insecticidal preparations in the form of an aqueous dispersion of finely divided polymer particles which comprise at least one insecticidal organic active ingredient with a solubility in water of not more than 5 g/l at 25° C. at 1013 mbar and which have a mean particle size, determined by dynamic light scattering, of not more than 300 nm, where the polymer particles which comprise the at least one insecticidal active ingredient of a cationic surface charge and where the aqueous dispersion of the active-ingredient-comprising polymer particles is obtainable by subjecting a monomer composition of ethylenically unsaturated monomers M, in which the ethylenically unsaturated monomers M comprise the at least one insecticidal active ingredient in dissolved form, to radical aqueous emulsion polymerization. The invention also related to the use of such aqueous insecticide compositions for protecting lignocellulosic materials, in particular timber, against attack by harmful insects.