POLYMER DISPERSION WITH A COLOUR EFFECT
    1.
    发明申请
    POLYMER DISPERSION WITH A COLOUR EFFECT 审中-公开
    随着彩色效果的聚合物分散体

    公开(公告)号:WO2004098793A3

    公开(公告)日:2004-12-16

    申请号:PCT/EP2004004707

    申请日:2004-05-04

    Abstract: The invention relates to a method for improving the colour brilliance and the stability of a colour polymer system which consists of a matrix and discrete polymer particles distributed in the matrix according to a defined space lattice structure, and is obtained by filming an emulsion polymer having a core/shell structure. The inventive method is characterised in that the emulsion polymer can be obtained by polymerisation of monomers in at least one first step (monomers of the core), further polymerisation of monomers in at least one other, second step (transition step), and final polymerisation of monomers in a third step (monomers of the shell). In relation to the percentual composition of the monomer mixture of the three steps, a maximum 30 wt. % of the monomers of the first step correspond to those of the third step and at least 5 wt. % of the monomers of the second step respectively correspond to those of the first and the third step. A maximum 60 wt. % of the monomers of the second step are monomers from either the first or the third step.

    Abstract translation: 一种用于改善颜色的亮度和着色聚合物体系,它由基质和离散的聚合物颗粒,其分布于根据在矩阵定义的空间格子结构,由拍摄用核/壳结构的乳液聚合物得到的的稳定性,其特征在于,过程, 所述乳液聚合物是获得由单体的聚合反应在至少一个第一级(核的单体),在至少一个另外的单体的后续聚合,在第三阶段的单体的第二阶段(过渡阶段)和最后聚合(壳的单体),其中, 基于这三个阶段的单体混合物的组成百分比,最多30重量的第一阶段的单体的%与第3阶段和第二阶段的在每种情况下为至少5重量%与第一和与第三的单体重合 同意级 n,其中重量的第二阶段的单体的%为最大值60个的单体,其存在既不在第一也不在第三阶段的。

    AMPLIFYING MEDIUM FOR SOLID-STATE DYE LASERS
    3.
    发明申请
    AMPLIFYING MEDIUM FOR SOLID-STATE DYE LASERS 审中-公开
    固态染料激光放大介质

    公开(公告)号:WO03044911A3

    公开(公告)日:2003-09-18

    申请号:PCT/EP0213027

    申请日:2002-11-20

    CPC classification number: H01S3/17 C08F291/00 C08F2/22

    Abstract: The invention relates to an amplifying medium for solid-state dye lasers and a solid-state dye laser provided with said amplifying medium. Said amplifying medium comprises an essentially solid active medium, containing at least one sort of particles which can be activated and which can be stimulated to emit laser light of a particular wavelength and optical feedback means which define a resonator for the laser light. The feedback means comprises an essentially solid feedback medium which has a periodic structure. The amplifying medium is characterised in that the feedback medium is a polymeric dispersion film with a crystalline structure which particularly comprises core/shell particles which may be coated.

    Abstract translation: 本发明涉及一种用于固态染料激光器的增益介质(16),和设置有这种增益介质(16)的固态染料激光器。 根据本发明的放大介质(16)包括限定用于激光谐振器的基本上固体活性介质,其包含至少一种类型的可活化的粒子的,其可被激发以发射特定波长范围的激光的光,并且光学Rückopplungsmittel,其中所述反馈装置包括 基本上为固体的反馈介质包括具有周期性结构。 增益介质的特征在于,所述反馈介质是具有晶体结构,特别是filmable /包括芯 - 壳颗粒的聚合物Dispersonsfilm。

    PROCEDIMIENTO PARA LA OBTENCION DE UNA DISPERSION ACUOSA DE POLIMEROS.

    公开(公告)号:ES2285470T3

    公开(公告)日:2007-11-16

    申请号:ES04739590

    申请日:2004-06-04

    Applicant: BASF AG

    Abstract: Procedimiento para la obtención de una dispersión acuosa de polímeros mediante polimerización de, al menos, un monómero B etilénicamente insaturado en medio acuoso en presencia de partículas de, al menos, un polímero A (partículas polímeras A) y de, al menos, un agente dispersante, caracterizado porque se lleva a cabo la polimerización de, al menos, un monómero B, etilénicamente insaturado, en presencia de partículas polímeras A con un diámetro de las partículas, promedio en peso, = 1 nm, habiéndose obtenido el polímero A bien a) mediante una polimerización iniciada con, al menos, un iniciador por medio de radicales o b) mediante una polimerización iniciada con, al menos, un complejo de metal de transición de al menos un monómero A etilénicamente insaturado (monómero A) y la polimerización de, al menos, un monómero B etilénicamente insaturado (monómero B) se inicia i) en el caso a) por medio de, al menos, un complejo de metal de transición y ii) en el caso b) por medio de, al menos, un iniciador por medio de radicales.

    6.
    发明专利
    未知

    公开(公告)号:DE102005023804A1

    公开(公告)日:2006-11-23

    申请号:DE102005023804

    申请日:2005-05-19

    Applicant: BASF AG

    Abstract: Process for improvement of the elasticity of a colored polymer system, which is composed of a matrix and of discrete polymer particles distributed in accordance with a defined spatial lattice structure in the matrix, and which is obtained by filming of an emulsion polymer with core/shell structure, where the emulsion polymer is obtainable via polymerization of monomers in at least one first stage (monomers of the core) and subsequent polymerization of monomers in at least one further, second stage (monomers of the shell), which comprises using monomers whose glass transition temperature is below 0° C. as at least 5% by weight of the monomers of the core.

    9.
    发明专利
    未知

    公开(公告)号:DE10125138A1

    公开(公告)日:2002-12-05

    申请号:DE10125138

    申请日:2001-05-22

    Applicant: BASF AG

    Abstract: A method for the production of carbon monoxide/olefin copolymers in aqueous media in presence of metal complex catalysts, dispersants and optionally organic hydroxy compounds, in which copolymerization is also carried out in presence of water-soluble macromolecular compounds with a hydrophobic cavity and a hydrophilic envelope. A method for the production of copolymers of carbon monoxide and 2-20C olefinically-unsaturated compounds (CO/olefin copolymers) involves copolymerization in aqueous media in presence of: (a) metal complexes of formula (I); (b) a dispersant; (c) optionally an organic hydroxy compound; and (d) a water-soluble, macromolecular host compound with a hydrophobic cavity and a hydrophilic shell G = 5-, 6- or 7-membered carbocyclic ring system (optionally with heteroatom(s)), -(CRb2)r-, -(CRb2)s-Si(Ra)2-(CRb2)t-, -A-O-B- or -A-Z(R )-B-; R = H, 1-20C alkyl, 3-14C cycloalkyl, 6-14C aryl or (1-20C alkyl)-(6-14C aryl) (all optionally substituted with atoms of Group IVA, VA, VIA or VIIA elements), -N(Rb)2, -Si(Rc)3 or a group of formula (II); q = 0-20; A, B = -(CRb2)r'-, -(CRb)2)s-Si(Ra)2-(CRb2)t-, -N(Rb)- or a ring-system component with r', s or t atoms, or combined with Z to form a ring-component with (r'+1), (s+1) or (t+1) atoms; Ra, Rc = optionally substituted 1-20C alkyl, 3-14C cycloalkyl, 6-14C aryl or (1-20C alkyl)-(6-14C aryl); Rb = H, -Si(Rc)3 or groups as listed for Ra/Rc; r = 1, 2, 3 or 4; r' = 1 or 2; s, t = 0, 1 or 2; (s+t) = 1-3; Z, E , E = a non-metallic Group VA element; M = a Group VIIIB, IB or IIB metal; R -R = hydrocarbyl groups as listed above (e.g. for Ra), with the proviso that at least one of these groups contains hydroxy, amino or acid group(s) or an ionic functional group; L , L = formally charged or neutral ligands; X = a formally mono- or multi-valent anion; p, m, n = 0-4; p = m x n Independent claims are included for: (1) a method for the production of CO/olefin copolymers by copolymerization in aqueous media in presence of (a1.1) a Group VIIIB, IB or IBB metal in the form of a salt or complex salt, (a1.2) a chelate ligand of formula (R )(R )E -G-E )(R ) (III) and components (b), (c) and (d) as above; (2) aqueous copolymer systems obtained by these methods.

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