Continuous heterogeneously catalyzed partial dehydrogenation of hydrocarbon involves dehydrogenation through catalyst bed disposed in reaction chamber and with generation of product gas

    公开(公告)号:DE102006029790A1

    公开(公告)日:2008-01-03

    申请号:DE102006029790

    申请日:2006-06-27

    Applicant: BASF AG

    Abstract: Continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in the gas phase involves at least one catalyst bed disposed in the reaction chamber and with generation of a product gas comprising the at least one dehydrogenated hydrocarbon, unconverted hydrocarbon to be dehydrogenated and molecular hydrogen and/or steam, is dehydrogenated partially in an oxidative or non-oxidative manner to at least one dehydrogenated hydrocarbon, and at least one product gas stream is withdrawn continuously from the reaction chamber. Process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in the gas phase involves a reaction chamber enclosed by a shell which is in contact with the reaction chamber and has at least one first orifice for feeding at least one starting gas stream into the reaction chamber and at least one second orifice for withdrawing at least one product gas stream from the reaction chamber, at least one starting gas stream comprising at least one hydrocarbon to be dehydrogenated is fed continuously in the reaction chamber. The at least one hydrocarbon to be dehydrogenated is conducted through at least one catalyst bed disposed in the reaction chamber and with generation of a product gas comprising the at least one dehydrogenated hydrocarbon, unconverted hydrocarbon to be dehydrogenated and molecular hydrogen and/or steam, is dehydrogenated partially in an oxidative or non-oxidative manner to at least one dehydrogenated hydrocarbon, and at least one product gas stream is withdrawn continuously from the reaction chamber. The shell is manufactured from a composite material which, on its side B in contact with the reaction chamber, consists of steel B comprising (wt.%): chromium (18-30), nickel (9-37), silicon (1-4), aluminum (>=0-4), nitrogen (>=0-0.3), carbon (>=0-0.15), manganese (>=0-4), phosphorus (>=0-0.05), sulfur (>=0-0.05), and at least one rare earth metal (>=0-0.1), and iron and impurities resulting from production. The steel B, on its side A facing away from the reaction chamber, is plated either directly or via an intermediate layer of copper, and/or nickel, onto steel A comprising (wt.%): chromium (15-20), nickel (6-18), silicon (>=0-0.8), aluminum (>=0-0.8), nitrogen (>=0-0.3), carbon (>=0-0.15), molybdenum (>=0-4), manganese (>=0-2), titanium (>=0-0.8), niobium (>=0-1.2), vanadium (>=0-0.9), boron (>=0-0.1), phosphorus (>=0-0.05), sulfur (>=0-0.05), iron and impurities resulting from production, or a composition comprising (wt.%) Cr (19-23), Ni (30-35), Co (>=0-1), Si (>=0-1), Al (0.15-0.7), C (>=0-0.12), Mn (>=0-2), Cu (>=0-0.75), Ti (0.15-0.7), Nb (>=0-0.1), P (>=0-0.05), S (>=0-0.05) and iron and impurities resulting from production. An independent claim is included for a shell encloses an interior and has at least one first orifice for feeding at least one gas stream into the interior and at least one second orifice for withdrawing a gas stream fed to the interior beforehand via the at least one first orifice O1 from the interior. The shell is manufactured from a composite material which, on its side B in contact with the reaction chamber, consists of steel B on its side A facing away from the reaction chamber is plated either directly or via an intermediate layer of copper and/or nickel onto steel A.

    PROCEDIMIENTO PARA LA OBTENCION DE POLIAMIDAS

    公开(公告)号:AR045281A1

    公开(公告)日:2005-10-19

    申请号:ARP040102972

    申请日:2004-08-19

    Applicant: BASF AG

    Abstract: Procedimiento para obtención de poliamidas, sus oligómeros o mezclas de los mismos, en caso dado, con otros productos de reacción, por reacción de una mezcla de reacción, que contiene monómeros conteniendo grupos -CN o grupos -CONH2 y, opcionalmente, otros monómeros y/u oligómeros formadores de poliamida y agua, en un dispositivo, caracterizado porque las superficies del dispositivo que entran en contacto con la mezcla de reacción constan parcial o completamente de un material seleccionado entre el grupo que comprende: a) un acero austenítico, que contiene, cada vez con respecto a a), cromo, en un margen de 15 a 25 % en peso, níquel, en un margen de 3 a 25 % en peso y molibdeno, en un margen de 0 a 10 % en peso, opcionalmente, otros componentes de aleación diferentes, resto ad 100 % en peso de hierro; b) un acero dúplex, que contiene, cada vez con respecto a b), cromo, en un margen de 20 a 30 % en peso, níquel, en un margen de 3 a 10 % en peso y molibdeno, en un margen de 0 a 5 % en peso, opcionalmente, otros componentes de aleación diferentes, resto ad 100 % en peso de hierro; y c) una aleación básica de níquel, que contiene, cada vez con respecto a c), cromo, en un margen de 12 a 25 % en peso, molibdeno, en un margen de 12 a 20 % en peso, opcionalmente, otros componentes de aleación diferentes, resto ad 100 % en peso de níquel, y dispositivos, usados en un procedimiento de este tipo o destinados a ser usados en un procedimiento de este tipo.

    METHOD FOR THE PRODUCTION OF POLYAMIDES

    公开(公告)号:CA2535488A1

    公开(公告)日:2005-03-03

    申请号:CA2535488

    申请日:2004-07-15

    Applicant: BASF AG

    Abstract: Disclosed is a method for producing polyamides and the oligomers or mixtures thereof, optionally with additional reaction products, by reacting a reactio n mixture containing monomers that comprise CN groups or -CONH2 groups, other optional polyamide-forming monomers and/or oligomers, and water in a device. Said method is characterized in that the surfaces of the device, which enter in contact with the reaction mixture, are entirely or partly made of a material that is selected among a group comprising: a) an austenitic steel containing 15 to 25 percent by weight of chromium, 3 to 35 percent by weight of nickel, 0 to 10 percent by weight of molybdenum, and other optional alloy components, the balance being made up of iron and the percentages by weight being in relation to a); b) a duplex steel containing 20 to 30 percent by weight of chromium, 3 to 10 percent by weight of nickel, 0 to 5 percent by weight of molybdenum, and other optional alloy components, the balance being made up of iron and the percentages by weight being in relation to b); and c ) a basic nickel alloy containing 12 to 25 percent by weight of chromium, 12 t o 20 percent by weight of molybdenum, and other optional alloy components, the balance being made up of nickel and the percentages being in relation to c). Also disclosed are devices that are used in or intended for such a method.

    4.
    发明专利
    未知

    公开(公告)号:BRPI0413629A

    公开(公告)日:2006-10-17

    申请号:BRPI0413629

    申请日:2004-07-15

    Applicant: BASF AG

    Abstract: An apparatus for making polyamides oligomers thereof mixtures thereof, the apparatus comprising a material selected from the group consisting of a) an austenitic steel comprising from 15 to 25% by weight of chromium, from 3 to 35% by weight of nickel and from 0 to 10% by weight of molybdenum, and iron, b) a duplex steel comprising from 20 to 30% by weight of chromium, from 3 to 10% by weight of nickel and from 0 to 5% by weight of molybdenum, and iron, and c) a nickel-based alloy comprising from 12 to 25% by weight of chromium and from 12 to 20% by weight of molybdenum, and nickel

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