PROCESS FOR THE ISOLATION OF THE METHYL ESTER OF M-NITROBENZOIC ACID

    公开(公告)号:DE3460001D1

    公开(公告)日:1985-09-19

    申请号:DE3460001

    申请日:1984-03-05

    Applicant: BASF AG

    Abstract: Methyl m-nitrobenzoate is prepared by a process in which an isomer mixture is treated with from 10 to 1000% by weight of water in the presence of from 0.05 to 20% by weight of an emulsifier, the percentages being based on the weight of the isomer mixture, (a) in a first stage at from 55 DEG to 100 DEG C. and a pH from 2 to 8 and then (b) in a second stage at from 10 DEG to 40 DEG C. and a pH of not less than 9. The methyl m-nitrobenzoate obtainable by the process of the invention is a useful starting material for the preparation of dyes and crop protection agents.

    ZPUSOB VYROBY SUBSTITUOVANE 4 CHLOR FENOXYKARBOXYLOVE KYSELINY

    公开(公告)号:CS966881A2

    公开(公告)日:1985-07-16

    申请号:CS966881

    申请日:1981-12-22

    Applicant: BASF AG

    Abstract: A process for the preparation of 2,4-dichloro- or 2-methyl-4-chlorophenoxyacetic acid or alpha -2,4-dichloro- or alpha -2-methyl-4-chlorophenoxypropionic acid by reacting phenoxyacetic or 2-methylphenoxyacetic acid or alpha -phenoxypropionic or alpha -2-methylphenoxypropionic acid with chlorine in water, wherein phenoxyacetic acid or phenoxypropionic acid is precipitated from an aqueous solution thereof, chlorine gas is passed into the resulting suspension of phenoxyacetic or 2-methylphenoxyacetic acid or alpha -phenoxypropionic or alpha -2-methylphenoxypropionic acid in water at from 30 DEG to 70 DEG C. at a rate not exceeding the rate at which it is consumed in the suspension, until from 100 to 110% of the theoretically required amount of chlorine gas has been taken up by the suspension, and the 2,4-dichloro- or 2-methyl-4-chloro-phenoxyacetic acid or alpha -2,4-dichloro- or alpha -2-methyl-4-chloro-phenoxypropionic acid is isolated from the suspension.

    4.
    发明专利
    未知

    公开(公告)号:GR75381B

    公开(公告)日:1984-07-13

    申请号:GR810166410

    申请日:1981-11-03

    Applicant: BASF AG

    Abstract: A process for the preparation of 2,4-dichloro- or 2-methyl-4-chlorophenoxyacetic acid or alpha -2,4-dichloro- or alpha -2-methyl-4-chlorophenoxypropionic acid by reacting phenoxyacetic or 2-methylphenoxyacetic acid or alpha -phenoxypropionic or alpha -2-methylphenoxypropionic acid with chlorine in water, wherein phenoxyacetic acid or phenoxypropionic acid is precipitated from an aqueous solution thereof, chlorine gas is passed into the resulting suspension of phenoxyacetic or 2-methylphenoxyacetic acid or alpha -phenoxypropionic or alpha -2-methylphenoxypropionic acid in water at from 30 DEG to 70 DEG C. at a rate not exceeding the rate at which it is consumed in the suspension, until from 100 to 110% of the theoretically required amount of chlorine gas has been taken up by the suspension, and the 2,4-dichloro- or 2-methyl-4-chloro-phenoxyacetic acid or alpha -2,4-dichloro- or alpha -2-methyl-4-chloro-phenoxypropionic acid is isolated from the suspension.

    8.
    发明专利
    未知

    公开(公告)号:DE3308460A1

    公开(公告)日:1984-09-13

    申请号:DE3308460

    申请日:1983-03-10

    Applicant: BASF AG

    Abstract: Methyl m-nitrobenzoate is prepared by a process in which an isomer mixture is treated with from 10 to 1000% by weight of water in the presence of from 0.05 to 20% by weight of an emulsifier, the percentages being based on the weight of the isomer mixture, (a) in a first stage at from 55 DEG to 100 DEG C. and a pH from 2 to 8 and then (b) in a second stage at from 10 DEG to 40 DEG C. and a pH of not less than 9. The methyl m-nitrobenzoate obtainable by the process of the invention is a useful starting material for the preparation of dyes and crop protection agents.

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