PROCESS FOR THE PREPARATION OF CHLORINATED PHENOXYALKANOIC ACIDS

    公开(公告)号:DE3161899D1

    公开(公告)日:1984-02-16

    申请号:DE3161899

    申请日:1981-10-24

    Applicant: BASF AG

    Abstract: A process for the preparation of 2,4-dichloro- or 2-methyl-4-chlorophenoxyacetic acid or alpha -2,4-dichloro- or alpha -2-methyl-4-chlorophenoxypropionic acid by reacting phenoxyacetic or 2-methylphenoxyacetic acid or alpha -phenoxypropionic or alpha -2-methylphenoxypropionic acid with chlorine in water, wherein phenoxyacetic acid or phenoxypropionic acid is precipitated from an aqueous solution thereof, chlorine gas is passed into the resulting suspension of phenoxyacetic or 2-methylphenoxyacetic acid or alpha -phenoxypropionic or alpha -2-methylphenoxypropionic acid in water at from 30 DEG to 70 DEG C. at a rate not exceeding the rate at which it is consumed in the suspension, until from 100 to 110% of the theoretically required amount of chlorine gas has been taken up by the suspension, and the 2,4-dichloro- or 2-methyl-4-chloro-phenoxyacetic acid or alpha -2,4-dichloro- or alpha -2-methyl-4-chloro-phenoxypropionic acid is isolated from the suspension.

    5.
    发明专利
    未知

    公开(公告)号:DE4410360A1

    公开(公告)日:1995-09-28

    申请号:DE4410360

    申请日:1994-03-25

    Applicant: BASF AG

    Abstract: Prepn of arylbenzylamines comprises reacting arylamines with a benzyl chloride in the simultaneous presence of (i) phase transfer catalyst, and (ii) base chosen from inorganic bases or weak organic acid salts.

    7.
    发明专利
    未知

    公开(公告)号:GR75381B

    公开(公告)日:1984-07-13

    申请号:GR810166410

    申请日:1981-11-03

    Applicant: BASF AG

    Abstract: A process for the preparation of 2,4-dichloro- or 2-methyl-4-chlorophenoxyacetic acid or alpha -2,4-dichloro- or alpha -2-methyl-4-chlorophenoxypropionic acid by reacting phenoxyacetic or 2-methylphenoxyacetic acid or alpha -phenoxypropionic or alpha -2-methylphenoxypropionic acid with chlorine in water, wherein phenoxyacetic acid or phenoxypropionic acid is precipitated from an aqueous solution thereof, chlorine gas is passed into the resulting suspension of phenoxyacetic or 2-methylphenoxyacetic acid or alpha -phenoxypropionic or alpha -2-methylphenoxypropionic acid in water at from 30 DEG to 70 DEG C. at a rate not exceeding the rate at which it is consumed in the suspension, until from 100 to 110% of the theoretically required amount of chlorine gas has been taken up by the suspension, and the 2,4-dichloro- or 2-methyl-4-chloro-phenoxyacetic acid or alpha -2,4-dichloro- or alpha -2-methyl-4-chloro-phenoxypropionic acid is isolated from the suspension.

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