1.
    发明专利
    未知

    公开(公告)号:DE19645313A1

    公开(公告)日:1998-05-07

    申请号:DE19645313

    申请日:1996-11-04

    Applicant: BASF AG

    Abstract: The invention relates to substituted 3-benzylpyrazoles of formula (I), their precursors of formulas (IIa), (IIb), (IIc), their byproducts of formula (III) as well as their salts, wherein R stands for H, C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkyl thio, C1-C4 halogen alkyl thio, C1-C4 alkyl sulfinyl, C1-C4 halogen alkyl sulfinyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for H, CN, NO2, halogen, C1-C4 alkyl, C1-C4 halogen alkyl; X -X stands for chemical bond, optionally substituted methylene-, ethylene-, ethene-1,2-diyl or oxymethylene or thiamethylene chain linked through the heteroatom to the phenyl ring; R -R stands for H, CN, NO2, halogen -O-Y -R , -O-CO-Y -R , -N(Y -R ) (Y -R ), -N(Y -R )-SO2-Y -R , -N(SO2-Y -R ) (SO2-Y -R ), -N(Y -R )-CO-Y -R , -N(Y -R ) (O-Y -R ), -S-Y -R , -SO-Y -R , -SO2-Y -R , -SO2-O-Y -R , -SO2-N(Y -R ) (Y -R ), -CO-Y -R , -C(=NOR )-Y -R , -C(=NOR )-O-Y -R , -C(=NOR )-CO-O-Y -R , -CO-O-Y -R , -CO-S-Y -R , -CO-N(Y -R ) (Y -R ), -CO-N(Y -R ) (O-Y -R ); R stands C1-C4 alkyl, C1-C4 halogen alkyl. The invention further relates to the use of (I) as herbicide, for the desiccation/defoliation of plants, and of (I), (IIa), (IIb), (IIc) and (III) for lowering the sugar content in blood.

    2.
    发明专利
    未知

    公开(公告)号:DE19638245A1

    公开(公告)日:1998-03-26

    申请号:DE19638245

    申请日:1996-09-19

    Applicant: BASF AG

    Abstract: Substituted carbamoyl triazoles have the formula (I), in which the variables have the following meanings: R is hydrogen, C1-C6 alkyl, C1-C6 alkyl halide, C3-C8 cycloalkyl, C3-C6 alkenyl or C3-C6 alkinyl; R is R , C1-C6 alkoxy or C1-C6 alkoxy halide; or R and R form together an optionally substituted C2-C5 alcandiyl radical, and if they form a C4-C5 alcandiyl radical one CH2 group may be substituted by oxygen or a group NH or N-C1-C6 alkyl; R , R and R are hydrogen, cyano, C1-C6 alkyl, C1-C6 alkyl halide, C3-C6-cycloalkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C6 alkoxy, C1-C6 alkoxy halide, C1-C6 alkylthio, C1-C6 alkyl carbonyl, C1-C6 alkyl halide carbonyl, C1-C6 alkoxycarbonyl, optionally substituted phenyl or benzyl; A is an optionally substituted, saturated or partially unsaturated heterocycle containing one to three heteroatoms selected from the group of oxygen, sulphur and nitrogen, and is five- or six-membered; n equals 0, 1 or 2, provided that A does not stand for 1,3-dioxolan-2-yl or 1,3-dioxan-2-yl. Also disclosed are salts of (I) useful in agriculture, a process for preparing the same and their use as herbicides.

    New 3-pyrimidinyl:benzyl-hydroxylamine derivs.

    公开(公告)号:DE19616719A1

    公开(公告)日:1997-10-30

    申请号:DE19616719

    申请日:1996-04-26

    Applicant: BASF AG

    Abstract: N- or O-(3-(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)benzyl)-hydroxylamine derivs. of formula (I) and salts of (I; R , R and/or R = H) are new. X = -N(R )-O-, with R bonded to O or N; Y = O or S ; R = halo, CN, NO2 or CF3; R = H or halo; R = H, NH2 or Me; R = H, halo, alkyl, haloalkyl, alkylthio, alkylsulphinyl or alkylsulphonyl; R = H, halo or alkyl; R = H, alkyl, haloalkyl, 3-6C cycloalkyl or 2-6C alkenyl; R = (i) H; (ii) alkyl, cycloalkyl, haloalkyl, alkenyl, alkynyl, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl, alkoxycarbonyl, (2-6C)alkenyloxycarbonyl, (2-6C)alkynyloxycarbonyl, alkylthiocarbonyl, alkylsulphonyl or alkylcarbamoyl (all opt. substd. by 1-3 of NO2, CN, cycloalkyl, OH, alkoxy, cycloalkoxy, alkenyloxy, alkynyloxy, alkoxyalkoxy, alkylthio, alkylcarbonyl, alkylcarbonyloxy, alkylsulphinyl, alkylsulphonyl, 1-6C alkylideneaminoxy, alkylcarbamoyl, Ar, OAr, SO2Ar, Het, OHet, COZ R , OCOZ R and NR R ); or (iii) cycloa lkylcarbonyl, benzoyl, phenylsulphonyl or phenylcarbamoyl (all opt. substd. by 1-3 of halo, NO2, CN, alkyl, alkoxy and haloalkyl); R = H ; or alkyl, cycloalkyl, haloalkyl, alkenyl or alkynyl (all opt. substd. by 1-3 of NO2, CN, halo, cycloalkyl, OH, alkoxy, cycloalkoxy, alkenyloxy, alkynyloxy, alkoxyalkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, 1-6C alkylideneaminoxy, Ar, OAr, SO2Ar, Het, OHet, COZ R , OCOZ R and NR R ); Z = a bond, O, S or NR ; Z = a bond, O, S or NR ; Ar = phenyl (opt. substd. by 1-3 of halo, NO2, CN, alkyl, haloalkyl and alkoxy); Het = 3-7 membered satd., partially or completely unsatd. or aromatic heterocycle contg. 1-3 heteroatoms selected from 2 O, 2 S and 3 N (opt. substd. by 1-3 of halo, NO2, CN, alkyl, alkoxy, haloalkyl and alkylcarbonyl); R , R = H, alkyl, haloalkyl, cycloalkyl, alkenyl, alkynyl, alkoxyalkyl or alkoxycarbonylalkyl, or phenyl or phenylalkyl (both opt. ring-substd. by 1-3 of NO2, CN, halo, alkyl, haloalkyl, alkoxy or alkylcarbonyl); or Z + R and/or Z + R may complete an N-bonded heterocycle as defined for Het (except that the optional substituents do not include alkylcarbonyl); R , R = H, OH, alkyl, cycloalkyl or alkoxy; unless specified otherwise, alkyl moieties have 1-6C, alkenyl or alkynyl moieties 3-6C and cycloalkyl moieties 3-8C.

    4.
    发明专利
    未知

    公开(公告)号:DE19532048A1

    公开(公告)日:1997-03-06

    申请号:DE19532048

    申请日:1995-08-31

    Applicant: BASF AG

    Abstract: The invention concerns substituted benzothiazols of general formula (I) and their salts. In the formula: X , X = O or S; R = H, NH2, C1-C6 alkyl or C1-C6 alkyl halide; R = H, halogen, C1-C6 alkyl, C1-C6 alkyl halide, C1-C6 alkythio, C1-C6 alkylsulphinyl or C1-C6 alkylsulphonyl; R = H, halogen or C1-C6 alkyl; R = H or halogen; R = CN, halogen, C1-C6 alkyl, C1-C6 alkyl halide, C1-C6 alkoxy or C1-C6 alkoxy halide; Y = a chemical bond, -O-, -S-, -SO- or -SO2-; R = hydrogen, CN, halogen, C3-C6 cycloalkyl, C1-C6 alkyl halide, C3-C6 alkenyl, C3-C6 alkyl halide, C3-C6 alkinyl or C1-C6 alkyl, wherein the said cycloalkyl, alkyl, alkenyl and alkinyl groups can be substituted by CN, C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkoxycarbonyl, C1-C6 alkylaminocarbonyl, di(C1-C6 alkyl)aminocarbonyl, C1-C6 alkylcarbonyloxy, C1-C6 alkoxy halide, C1-C6 alkylthio halide or C3-C6 cycloalkyl, provided that R can mean cyano only when Y stands for a chemical bond, oxygen or sulphur, and R can mean halogen only when Y stands for a chemical bond. The invention further concerns the use of these substances as herbicides and for the desiccation and abscission of plants.

    New and known substd. alkylthio-pyridine derivs.

    公开(公告)号:DE19531148A1

    公开(公告)日:1997-02-27

    申请号:DE19531148

    申请日:1995-08-24

    Applicant: BASF AG

    Abstract: Control of fungi using substd. alkylthio-pyridine derivs. (I) and their salts and N-oxides is claimed. R -R = H, CN, NO2 or halo; 1-4C alkyl or 1-4C alkoxy (both opt. substd. by halo), 1-4C alkylthio, 1-4C alkoxy-1-4C alkyl, 1-4C alkoxy-CO or Ar; Ar = aryl, aryloxy or heteroaryl (all opt. ring substd. by 1-3 of halo, CN or NO2; 1-4C alkyl or 1-4C alkoxy (both opt. substd. by halo), 1-4C alkylthio, 1-4C alkoxy-1-4C alkyl, 1-4C alkoxy-CO or 1-4C acyl); m = 0-2; Alk = 1,2-ethylene or 1,3-propylene having any H atom opt. replaced by: (a) alkyl, haloalkyl, alkenyl, haloalkenyl or alkynyl (all having up to 8C and opt. substd. by 1-3 of CN, 1-4C alkoxy (opt. substd. by halo), 1-4C alkylthio, 1-4C alkoxycarbonyl, 3-7C cycloalkyl or 5-7C cycloalkenyl); or (b) 3-7C cycloalkyl or 5-7C cycloalkenyl (both opt. substd. by 1 or more halo or opt. substd. by 1-3 of CN, halo, 1-4C alkyl (opt. substd. by halo) or 1-4C alkoxy); X = O, S or NR ; R = H, 1-8C alkyl or 3-7C cycloalkyl; R = (a) aryl, heteroaryl or aryl-1-4C alkyl (all opt. ring substd. by 1-3 of CN, NO2, halo, 1-4C alkyl or 1-4C alkoxy (opt. substd. by halo), 1-4C alkylthio, 1-4C alkoxy-1-4C alkyl, 1-4C alkoxy-CO, 1-4C alkylsulphinyl, 1-4C alkylsulphonyl, 1-4C acyl or Ar); or (b) 3-7C cycloalkyl or 5-7C cycloalkenyl (both opt. substd. by 1 or more halo or opt. substd. by 1-3 of CN, halo, 1-4C alkyl or 1-4C alkoxy (opt. substd. by halo), 1-4C alkoxy-1-4C alkyl, 1-4C alkylthio, 1-4C alkoxy-carbonyl, 3-7C cycloalkyl, 5-7C cycloalkenyl or Ar).

    6.
    发明专利
    未知

    公开(公告)号:DE19530605A1

    公开(公告)日:1997-02-27

    申请号:DE19530605

    申请日:1995-08-21

    Applicant: BASF AG

    Abstract: Trifluoromethylpyridines of formula (Ia) and (Ib) are new. In cpds. (Ia), R2a = CF3, and R2b = halo; in cpds. (Ib), R2a = halo, and R2b = CF3; R1 = NH2 or NHNH2; in (Ib), R1 may also be Cl or Br; R3 = 1-6Calkyl, 1-6Calkenyl or 1-6Calkynyl (all opt. substd. by 1-6 halo), 3-6C cycloalkyl (opt. substd. by 1-3 of 1-3C alkyl), 1-6C alkyl substd. by CN, COOH, 1-6C alkoxycarbonyl, 1-4C alkoxy-2-4C alkoxycarbonyl, CONH2, CONH-1-4C alkyl, CON(1-4C alkyl)2,CONH-2-4C alkenyl, CONH-3-4C alkynyl or CON(1-4C alkyl) (3-4C alkenyl or alkynyl); 2-6C alkyl substd. by 1-4C alkoxy or 3-6C-( alpha -alkylalkylidene)iminoxy, 3-oxetanyl, cyclopropylmethyl, 1-6C alkylamino, di(1-6C alkyl)amino; 1-6C alkylideneimino or alpha -(1-4C alkyl)-2-6C alkylideneimino; and halo = F, Cl, Br or I.

    8.
    发明专利
    未知

    公开(公告)号:DE19523372A1

    公开(公告)日:1997-01-09

    申请号:DE19523372

    申请日:1995-06-29

    Applicant: BASF AG

    Abstract: The invention concerns 1-amino-3-benzyluracils of formula (I) and their salts. In said formula (I), R = halogen; R , R = H, CN, SCN, halogen, C1-C4-alkyl halide, C1-C4-alkoxy halide, C1-C4-alkylthio halide; R = R + C1-C4-alkyl, C1-C4-alkoxy, C1-C6-alkyl-NH-CO-; R = H, CN, NO2, OH, halogen, optionally substituted NH2, optionally substituted C1-C6-alkoxy halide, C1-C6-alkylthio halide, C1-C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C3-C6-alkenyloxy, C3-C6-alkenylthio, C3-C6-alkinyloxy, C3-C6-alkinylthio, C1-C6-alkyl-COO-, C1-C6-alkyl-COS-, C3-C6-alkenyl-COO-, C3-C6-alkenyl-COS-, C3-C6-alkinyl-COO-, C3-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O- or C1-C6-alkyl-SO2-; R = 1) H, OH, SH, halogen, C1-C6-alkoxy halide, C1C6-alkylthio halide, C1-C6-alkylthio-(C1-C6-alkyl)carbonyl, C1-C6-alkyliminooxy-CO-, 2) optionally substituted C1C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C2-C6-alkenyloxy, C2-C6-alkenylthio, C2-C6-alkinyloxy, C2-C6-alkinylthio, C1-C6-alkyl-COO-, C2-C6-alkyl-COS-, C1-C6-alkoxy-COO-, C2-C6-alkenyl-COO-, C2-C6-alkenyl-COS-, C2-C6-alkinyl-COO-, C2-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O-, C1-C6-alkyl-SO2-, 3) -CY-R {Y = -O-, -S-, optionally substituted -NH-}, -C(R )(Z R )(Z R ) {Z , Z = -O-, -S-}, -C(R )=C(R )-CN, -C(R )=C(R )-CO-R , -CH(R )-CH(R )-CO-R , -C(R )=C(R )-CH2-CO-R , -C(R )=C(R )-C(R )=C(R )-CO-R , -C(R )=C(R )-CH2-CH(R )-CO-R , -CO-OR , -CO-SR , -CO-N(R )-OR , -C=C-CO-NH-OR , -C=C-CO-N(R )-OR , -C=C-CS-NH-OR , -C=C-CS-N(R )-OR , -C(R )=C(R )-CO-NH-OR , -C(R )=C(R )-CO-N(R )-OR ,-C(R )=C(R )-CS-NH-OR , -C(R )=C(R )-CS-N(R )-OR , -C(R )=C(R )-C(R )=N-OR , -C(R )=N-OR , -C=C-C(R )=N-OR , -C(Z R )(Z R )-OR , -C(Z R )(Z R )-SR , -C(Z R )(Z R )-N(R )R , optionally substituted amino or -CONH2, azaheterocyclyl, -CO-azaheterocyclyl, or a chain comprising (N + O or N + O + S) heterocyclyl. These compounds can be used as herbicides for desiccating/defoliating plants.

    9.
    发明专利
    未知

    公开(公告)号:DE19508590A1

    公开(公告)日:1996-09-19

    申请号:DE19508590

    申请日:1995-03-13

    Applicant: BASF AG

    Abstract: 3-Aryluracils (I) and their salts (with A = hydrogen) where: A = H, CH3, NH2; R = H, halogen; R = H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkylthio, C1-C6-alkylsulfenyl or C1-C6-alkylsulfonyl; R = H, halogen, C1-C6-alkyl; X = oxygen or -N(R )-, with R = C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkylcarbonyl or C1-C6-alkoxy-C1-C6-alkyl; Y and Y = oxygen or sulfur; Z = oxygen or -N(R )-; R , R and R = H, C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or C1-C6-alkoxy-C1-C6-alkyl; or R and R together are a second chemical bond; R = H, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-haloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkylcarbonyl, C3-C6-alkenyl-carbonyl, C3-C6-alkynylcarbonyl or C1-C6-alkylsulfonyl, where each of the last-mentioned 9 radicals can carry 1-3 substituents: R = H, C1-C6-alkyl, C3-C8-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkoxy-C1-C6-alkyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl, unsubst. or subst. phenyl or phenyl-C1-C6-alkyl; R = H, OH, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-alkoxy, C3-C6-alkenyloxy, C1-C6-alkoxycarbonyl-C1-C6-alkoxy; R = C1-C6alkoxy, C3-C6-alkenyloxy, C1-C6-alkoxycarbonyl-C1-C6alkoxy; R = C1-C6-alkyl, C3-C6-alkenyl, C1-C6-alkoxycarbonyl-C1-C6-alkyl. Use: as herbicides; for the desiccation/defoliation of plants.

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