Abstract:
PROCESS FOR DYEING AND/OR PRINTING SYNTHETIC POLYAMIDES WITH DYES CONTAINING SULFONIC ACID GROUPS AND DERIVED FROM 3-AMINOPHTHALIMIDES, OR 4-AMINOPHTHALIMIDES, AND 2-AMINO-8-HYDROXYNAPHTHALENE-6-SULFONIC ACID.
Abstract:
DYES CONTAINING SULFONIC ACID GROUPS DERIVED FROM 3AMINOPHTHALIMIDES, OR 4-AMINOPHTHALIMIDES, AND 2-AMINO8-HYDROXYNAPHTHALENE-6-SULFONIC ACID, WHICH ARE ESPECIAL LY SUITABLE FOR DYEING POLYAMIDES.
Abstract:
The new 2-neopentylanthraquinone compound, which is produced by Friedel-Crafts acylation of neopenthylbenzene with phthalic anhydride followed by cyclization of the 2-(4-neopentylbenzoyl) benzoic acid obtained in the presence of strong anhydrous acids, is a catalyst for the manufacture of hydrogen peroxide.
Abstract:
The novel compound 2-neo-pentylanthraquinone, which is prepared by Friedel-Crafts acylation of neopentylbenzene with phthalic anhydride followed by cyclization of the resulting 2-(4-neopentyl-benzoyl)-benzoic acid in the presence of a strong, anhydrous acid, is a catalyst for the preparation of hydrogen peroxide.
Abstract:
1. A process for the acylation of an aromatic by the Friedel-Crafts method, wherein the acylation is carried out in the presence of a metalalkyl or metalalkyl halide of a metal or semimetal of main groups two to five and/or of a metal of subgroups two or four of the Periodic Table.
Abstract:
The invention comprises tetrazaporphin dyes having the general formula in which Pc is a tetrazaporphin nucleus, R is hydrogen or substituted or unsubstituted alkyl radical, X is an aromatic heterocyclic ring containing in the ring an unsubstituted imino group, the heterocyclic ring may be attached by a substituted or unsubstituted aryleneamino, arylene-sulphonylamino,arylene-carbonylamino, arylene-azo, alkylene or arylene radical which may be fused with the heterocycle, m is 0-5, n is 1-4, p is 0-2, the total of m, n and p amounting to between 2 and 8 inclusive The tetrazaporphin is preferably a phthalocyanine which may be metallized, e.g. copper, nickel or cobalt and iron, aluminium, zinc or chromium. The dyes are obtained by reacting a tetrazaporphin sulphonic acid halide, preferably chloride or bromide, which may contain free sulphonic acid radicals, with an aromatic-heterocyclic amine having an unsubstituted imino group in the ring, and hydrolysing unreacted sulphonic acid halide groups, or by reacting a tetrazaporphin sulphonic acid halide which may contain free sulphonic acid groups, in any sequence with an aromatic-heterocyclic amine containing an unsubstituted imino group in its ring, and with ammonia or any primary amine, and hydrolysing unreacted sulphonic acid halide groups. Aromatic-heterocyclic amines of the above type include, pyrrole, pyrazole, imidazole, triazole and tetrazole derivatives, indole and indazole derivatives are also specified.