New dyes of the tetrazaporphin series

    公开(公告)号:GB1049766A

    公开(公告)日:1966-11-30

    申请号:GB3545363

    申请日:1963-09-09

    Applicant: BASF AG

    Abstract: The invention comprises tetrazaporphin dyes having the general formula in which Pc is a tetrazaporphin nucleus, R is hydrogen or substituted or unsubstituted alkyl radical, X is an aromatic heterocyclic ring containing in the ring an unsubstituted imino group, the heterocyclic ring may be attached by a substituted or unsubstituted aryleneamino, arylene-sulphonylamino,arylene-carbonylamino, arylene-azo, alkylene or arylene radical which may be fused with the heterocycle, m is 0-5, n is 1-4, p is 0-2, the total of m, n and p amounting to between 2 and 8 inclusive The tetrazaporphin is preferably a phthalocyanine which may be metallized, e.g. copper, nickel or cobalt and iron, aluminium, zinc or chromium. The dyes are obtained by reacting a tetrazaporphin sulphonic acid halide, preferably chloride or bromide, which may contain free sulphonic acid radicals, with an aromatic-heterocyclic amine having an unsubstituted imino group in the ring, and hydrolysing unreacted sulphonic acid halide groups, or by reacting a tetrazaporphin sulphonic acid halide which may contain free sulphonic acid groups, in any sequence with an aromatic-heterocyclic amine containing an unsubstituted imino group in its ring, and with ammonia or any primary amine, and hydrolysing unreacted sulphonic acid halide groups. Aromatic-heterocyclic amines of the above type include, pyrrole, pyrazole, imidazole, triazole and tetrazole derivatives, indole and indazole derivatives are also specified.

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