公开(公告)号：BG63200B1

公开(公告)日：2001-06-29

申请号：BG10157297

申请日：1997-06-05

Applicant: BASF AG

Inventor： KALCK ULRICH ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS U ,  KOPIETZ MICHAEL

IPC: C07D201/12

Abstract: Caprolactam is produced from mixtures containing polymers or thermoplastic moulded materials with a repeating structural unit -[N(H)-(CH2)5-C(O)-]-, by depolymerization at elevated temperatures in the presence of water. The mixture used includes, in wt. %: from 50 to 99.9 polymer or thermoplastic moulded materials containing a repeating structural unit -[-N(H)-(CH2)5-C(O)-]-, from 0.1 to 50 additives as inorganic fillers, organic and inorganic pigments and dyestuffs, from 0 to 10 organic and/or inorganic additives, from 0 to 40 non-polyamide-containing polymers and from 0 to 20 polyamides, with the exception of polycaprolactam and co-polymers, produced from caprolactam. The depolymerization is effected in the presence of water without any addition of an acid or a base at temperatures ranging from 270 to 350 degrees C and weight ratio between water and polymer or the thermoplastic moulded material from 1:1 to 20:1, for a time less than 3 hours. 1 claim

公开(公告)号：CZ176497A3

公开(公告)日：1998-01-14

申请号：CZ176497

申请日：1995-12-01

Applicant: BASF AG

Inventor： KALCK ULRICH ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS ULRICH ,  KOPIETZ MICHAEL

IPC: C07D201/12

Abstract: Caprolactam is obtained from mixtures which contain polymers or thermoplastic molding materials having the repeating unit -N(H)-(CH2)5-C(O)- (a) by cleavage at elevated temperatures in the presence of a base under reduced pressure or (b) in the presence of water, by using a mixture essentially comprising from 50 to 99.9% by weight of a polymer or of a thermoplastic molding material having the repeating unit -N(H)-(CH2)5-C(O)- from 0.1 to 50% by weight of additives selected from the group consisting of inorganic fillers, organic and inorganic pigments and dyes, from 0 to 10% by weight of organic and/or inorganic additives, from 0 to 40% by weight of non-polyamide-containing polymers and from 0 to 20% by weight of polyamides, with the exception of polycaprolactam and copolyamides prepared from caprolactam, and carrying out the cleavage in the presence of a base under reduced pressure, the water content of the mixture used being not more than 0.01% by weight, or carrying out the cleavage in the presence of water without the addition of acid or base at from 270 DEG to 350 DEG C. and a weight ratio of water to polymer or thermoplastic molding material of from 1:1 to 20:1 and in a reaction time of less than 3 hours.

公开(公告)号：BR9509987A

公开(公告)日：1997-12-30

申请号：BR9509987

申请日：1995-12-01

Applicant: BASF AG

Inventor： KOPIETZ MICHAEL ,  HANDERMAN ALAN ,  JONES SIMON A ,  KALCK ULRICH ,  PRIESTER CLAUS-ULRICH ,  AUER HEINZ ,  RITZ JOSEF ,  FUCHS HUGO ,  PIJL PAUL

IPC: B01J8/10 ,  C07D201/12 ,  C08G69/14 ,  C08J11/16

Abstract: Caprolactam is obtained from caprolactam-containing polymers in the presence of a base under reduced pressure by depolymerizing polymers which contain the repeating unit -[-N(H)-(CH2)5-C(O)-] or mixtures consisting essentially of from 50 to 99.99% by weight of a polymer containing the repeating unit -[-N(H)-(CH2)5-C(O)-]- from 0.01 to 50% by weight of additives selected from the group consisting of inorganic fillers, organic and inorganic pigments and dyes, from 0 to 10% by weight of organic and/or inorganic additives, from 0 to 40% by weight of non-polyamide-containing polymers and from 0 to 20% by weight of polyamides, with the exception of polycaprolactam and copolyamides prepared from caprolactam, in at least two depolymerization reactors connected in series.

公开(公告)号：SK282229B6

公开(公告)日：2001-12-03

申请号：SK66897

申请日：1995-12-01

Applicant: BASF AG

Inventor： KALCK ULRICH ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS ULRICH ,  KOPIETZ MICHAEL

IPC: C07D201/12

Abstract: Caprolactam is obtained from mixtures which contain polymers or thermoplastic molding materials having the repeating unit -N(H)-(CH2)5-C(O)- (a) by cleavage at elevated temperatures in the presence of a base under reduced pressure or (b) in the presence of water, by using a mixture essentially comprising from 50 to 99.9% by weight of a polymer or of a thermoplastic molding material having the repeating unit -N(H)-(CH2)5-C(O)- from 0.1 to 50% by weight of additives selected from the group consisting of inorganic fillers, organic and inorganic pigments and dyes, from 0 to 10% by weight of organic and/or inorganic additives, from 0 to 40% by weight of non-polyamide-containing polymers and from 0 to 20% by weight of polyamides, with the exception of polycaprolactam and copolyamides prepared from caprolactam, and carrying out the cleavage in the presence of a base under reduced pressure, the water content of the mixture used being not more than 0.01% by weight, or carrying out the cleavage in the presence of water without the addition of acid or base at from 270 DEG to 350 DEG C. and a weight ratio of water to polymer or thermoplastic molding material of from 1:1 to 20:1 and in a reaction time of less than 3 hours.

公开(公告)号：MX9704250A

公开(公告)日：1997-09-30

申请号：MX9704250

申请日：1995-12-01

Applicant: BASF AG

Inventor： KALCK ULRICH ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS ULRICH ,  KOPIETZ MICHAEL

IPC: C07D201/12

Abstract: Se obtiene caprolactama a partir de mezclas que contienen polímeros o materiales de moldeo termoplásticos que tienen la unidad respectiva -[-N(H)-(CH2)5-C(O)-]-, (a) mediante despolimerizacion a temperaturas elevadas en presencia de una base bajo presion reducida o (b) en presencia de agua, utilizando una mezcla que comprende esencialmente de 50 a 99.9% en peso de un polímero o de un material de moldeo termoplástico que tiene la unidad repetitiva -[-N(H)-(CH2)5-C(O)-]-, de 0.1 a 50% en peso de aditivos seleccionados a partir del grupo que consiste en rellenos inorgánicos, pigmentos y colorantes orgánicos e inorgánicos, de 0 a 10% en peso de aditivos orgánicos y/o inorgánicos, de 0 a 40% en peso de un polímero que no contienen poliamida y de 0a 20% en peso de poliamidas, con la excepcion de policaprolactama y copoliamidas preparadas a partir de caprolactama, y llevar a cabo la despolimerizacion en presencia de una base bajo presion reducida, el contenido de agua de la mezcla utilizada no siendo más de 0.01% en peso, o llevar a cabo la despolimerizacion en presencia de agua sin la adicion deácido o base a de 270 a 350 degree C y una relacion en peso de agua a polímero o material de moldeo termoplástico de 1:1 a 20:1 y en un tiempo de reaccion de menos de 3 horas.

公开(公告)号：CZ287899B6

公开(公告)日：2001-03-14

申请号：CZ176497

申请日：1995-12-01

Applicant: BASF AG

Inventor： KALCK ULRICH ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS ULRICH ,  KOPIETZ MICHAEL

IPC: C07D201/12

Abstract: Caprolactam is obtained from a mixture that contains polymers or thermoplastic moulding materials having repeating units -¦-N(H)-(CHi2)i5-C(O)-¦-, (a) by depolymerization at elevated temperatures and in the presence of a base and under reduced pressure, or (b) in the presence of water, whereby the mixture contains substantially: 50 to 99.9 percent by weight of polymer or the thermoplastic moulding material having the repeating units, -¦-N(H)-(CHi2)i5-C(O)-¦-; 0.1 do 50 percent by weight of ingredients being selected from a group comprising inorganic filling agents, organic or inorganic pigments and dyestuffs; 0 to 10 percent by weight of organic and/or inorganic additives; 0 to 40 percent by weight of a polymer that is free of polyamide and 0 to 20 percent by weight of polyamides except for polycaprolactam and copolyamides being prepared from caprolactam. The depolymerization process ia carried out in the presence of water without addition of acid or base at a temperature ranging from 270 to 350 degC and weight ratio of water to the polymer or the thermoplastic moulding material ranging from 1:1 to 20:1 and for a reaction period shorter than 3 hours.

公开(公告)号：CZ9701764A3

公开(公告)日：1998-01-14

申请号：CZ176497

申请日：1995-12-01

Applicant: BASF AG

Inventor： KALCK ULRICH ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS ULRICH ,  KOPIETZ MICHAEL

IPC: C07D201/12

CPC classification number: C07D201/12

公开(公告)号：BR9509991A

公开(公告)日：1997-12-30

申请号：BR9509991

申请日：1995-12-01

Applicant: BASF AG

Inventor： KALCK ULRICH ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS-ULRICH ,  KOPIETZ MICHAEL

IPC: C07D201/12

Abstract: Caprolactam is obtained from mixtures which contain polymers or thermoplastic molding materials having the repeating unit -N(H)-(CH2)5-C(O)- (a) by cleavage at elevated temperatures in the presence of a base under reduced pressure or (b) in the presence of water, by using a mixture essentially comprising from 50 to 99.9% by weight of a polymer or of a thermoplastic molding material having the repeating unit -N(H)-(CH2)5-C(O)- from 0.1 to 50% by weight of additives selected from the group consisting of inorganic fillers, organic and inorganic pigments and dyes, from 0 to 10% by weight of organic and/or inorganic additives, from 0 to 40% by weight of non-polyamide-containing polymers and from 0 to 20% by weight of polyamides, with the exception of polycaprolactam and copolyamides prepared from caprolactam, and carrying out the cleavage in the presence of a base under reduced pressure, the water content of the mixture used being not more than 0.01% by weight, or carrying out the cleavage in the presence of water without the addition of acid or base at from 270 DEG to 350 DEG C. and a weight ratio of water to polymer or thermoplastic molding material of from 1:1 to 20:1 and in a reaction time of less than 3 hours.

公开(公告)号：CA2208222A1

公开(公告)日：1996-06-20

申请号：CA2208222

申请日：1995-12-01

Applicant: BASF AG

Inventor： KOPIETZ MICHAEL ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS ULRICH ,  KALCK ULRICH

IPC: C07D201/12 ,  C07D223/10

Abstract: Caprolactam is obtained from mixtures which contain polymers or thermoplastic molding materials having the repeating unit -¢-N(H)-(CH2)5-C(O)-!-, (a) by depolymerization at elevated temperatures in the presence of a base under reduced pressure or (b) in the presence of water, by using a mixture essentially comprising, from 50 to 99.9 % by weight of a polymer or of a thermoplastic molding material having the repeating unit -¢-N(H)-(CH2)5-C(O)-!-; from 0.1 to 50 % by weight of additives selected from the group consisting of inorganic fillers, organic and inorganic pigments and dyes; from 0 to 10 % by weight of organic and/or inorganic aditives; from 0 to 40 % by weight of non-polyamide-containing polymers and from 0 to 20 % by weight of polyamides, with the exception of polycaprolactam and copolyamides prepared from caprolactam, and carrying out the depolymerization in the presence of a base under reduced pressure, the water content of the mixture used being not more than 0.01 % by weight, or carrying out the depolymerization in the presence of water without the addition of acid or base at from 270 to 350 ~C and a weight ratio of water to polymer or thermoplastic molding material of from 1:1 to 20:1 and in a reaction time of less than 3 hours.

公开(公告)号：SK66897A3

公开(公告)日：1998-03-04

申请号：SK66897

申请日：1995-12-01

Applicant: BASF AG

Inventor： KALCK ULRICH ,  JONES SIMON A ,  BASSLER PETER ,  PRIESTER CLAUS U ,  KOPIETZ MICHAEL

IPC: C07D201/12

Abstract: Caprolactam is obtained from mixtures which contain polymers or thermoplastic molding materials having the repeating unit -[-N(H)-(CH2)5-C(O)-]-, by depolymerization at elevated temperatures in the presence of a base under reduced pressure or in the presence of water, by using a mixture essentially comprising, from 50 to 99.9 % by weight of a polymer or of a thermoplastic molding material having the repeating unit -[-N(H)-(CH2)5-C(O)-]-; from 0.1 to 50 % by weight of additives selected from the group consisting of inorganic fillers, organic and inorganic pigments and dyes; from 0 to 10 % by weight of organic and/or inorganic additives; from 0 to 40 % by weight of non-polyamide-containing polymers and from 0 to 20 % by weight of polyamides, with the exception of polycaprolactam and copolyamides prepared from caprolactam, and carrying out the depolymerization in the presence of a base under reduced pressure, the water content of the mixture used being not more than 0.01 % by weight, or carrying out the depolymerization in the presence of water without the addition of acid or base at from 270 to 350 C and pressure from 80 to 150 kPa and a weight ratio of water to polymer or thermoplastic molding material of from 1 : 1 to 20 : 1 and in a reaction time of less than 3 hours.