HERBICIDAL MIXTURES HAVING A SYNERGISTIC EFFECT

    公开(公告)号:CA2334955C

    公开(公告)日:2011-10-11

    申请号:CA2334955

    申请日:1999-06-12

    Applicant: BASF AG

    Abstract: The invention relates to synergistic herbicidal mixtures containing A) at least one 3-heterocyclyl-substituted benzoyl derivative of formula (I) in which the variables have the following meaning: R1, R3 represent hydrogen, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkyl sulfinyl, or alkyl sulfonyl; R2 represents a heterocyclic radical selected from the group: thiazole-2-yl, thiazole-4-yl, thiazole-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl, whereby these can be optionally substituted one time or a multiple number of times by halogen, alkyl, alkoxy, alkyl halide, alkoxy halide, alkylthio; R4 represents hydrogen, halogen or alkyl; R5 represents alkyl; R6 represents hydrogen or alkyl; or one of the environmentally compatible salts thereof; and B) a synergistically effective quantity of at least one herbicidal compound from the group of acetyl CoA carboxylase inhibitors (ACC), acetolactate synthase inhibitors (ALS), amides, auxin herbicides, auxin transport inhibitors, carotinoid biosynthesis inhibitors, enolpyruvyl-shikimat-3-phosphate synthase inhibitors (ESPS), glutamine synthetase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protophorphyrinogen-IX-oxidase inhibitors, photosynthesis inhibitors, synergistic agents, growth substances, cell wall biosynthesis inhibitors and various other herbicides. The invention also relates to agents which contain these mixtures, to methods for producing these agents, and to the use thereof for controlling unwanted plants.

    MEZCLAS HERBICIDAS A BASE DE 3-FENILURACILOS.

    公开(公告)号:ES2281550T3

    公开(公告)日:2007-10-01

    申请号:ES02779329

    申请日:2002-09-10

    Applicant: BASF AG

    Abstract: Una composición con actividad herbicida, que comprende: A) al menos un compuesto de feniluracilo de **fórmula**, en donde las variables R1-R7 se definen como sigue: R1 es metilo o NH2; R2 es haloalquilo C1-C2; R3 es hidrógeno o halógeno; R4 es halógeno o ciano; R5 es hidrógeno, ciano, alquilo C1-C6, alcoxi C1-C6, alcoxi C1-C4-alquilo C1-C4, cicloalquilo C3-C7, alquenilo C3-C6, alquinilo C3-C6 o bencilo que está insustituido o sustituido por halógeno o alquilo; R6, R7 independientemente entre sí son hidrógeno, alquilo C1-C6, alcoxi C1-C6, alquenilo C3-C6, alquinilo C3-C6, cicloalquilo C3-C7, cicloalquenilo C3-C7, fenilo o bencilo, en donde cada uno de los últimos ochos sustituyentes mencionados están insustituidos o pueden estar sustituidos por 1 a 6 átomos de halógeno y/o por uno, dos o tres grupos seleccionados entre: OH, NH2, CN, CONH2, alcoxi C1-C4, haloalcoxi C1-C4, alquil(C1-C4)tio, haloalquil(C1-C4)tio, alquil(C1-C4)sulfonilo, haloalquil(C1-C4)sulfonilo, alquil(C1-C4)amino, di(alquiloC1-C4)amino, formilo, alquil(C1-C4)carbonilo, alcoxi(C1-C4)carbonilo, alquil(C1-C4)aminocarbonilo, di(alquilo C1-C4)aminocarbonilo, cicloalquilo C3-C7, fenilo o bencilo; o R6, R7 junto con el átomo de nitrógeno forman un heterociclo nitrogenado de 3, 4, 5, 6 o 7 miembros, saturado o insaturado, que está insustituido o sustituido por 1 a 6 grupos metilo y que puede contener, como miembros del anillo, 1 o 2 heteroátomos más seleccionados del grupo consistente en nitrógeno, oxígeno y azufre, y/o al menos una de sus sales agrícolamente aceptables; y al menos otro compuesto activo seleccionado entre B) herbicidas de las clases b1) a b15): b1) inhibidores de la biosíntesis de lípidos; b2) inhibidores de acetolactato sintasa (inhibidores de ALS); b3) inhibidores de la fotosíntesis; b4) inhibidores de protoporfirinógeno-IX oxidasa; b5) herbicidas blanqueadores; b6) inhibidores de enolpiruvil siquimato 3-fosfato sintasa (inhibidores de EPSP); b7) inhibidores de glutamina sintetasa; b8) inhibidoresde 7, 8-dihidropteroato sintasa (inhibidores de DHP); b9) inhibidores de mitosas; b10) inhibidores de la síntesis de ácidos grasos de cadena larga (inhibidores de VLCFA); b11) inhibidores de la biosíntesis de celulosa; b12) herbicidas desacopladores; b13) herbicidas de auxinas; b14) inhibidores del transporte de auxinas; b15) otros herbicidas seleccionados del grupo consistente en benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin, methyldymuron, etobenzanid, fosamine, metam, pyributicarb, oxaziclomefone, dazomet, triaziflam y bromuro de metilo; y C) agentes de seguridad seleccionados entre benoxacor, cloquintocet, cyometrinil, dichlormid, dicyclonon, dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, mefenpyr, mephenate, anhídrido naftálico, 2, 2, 5-trimetil-3-(dicloroacetil)-1, 3-oxazolidina, 4-(dicloroacetil)-1-oxa-4-azaspiro[4, 5]decano y oxabetrinil; las sales agrícolamente aceptables de los compuestos activos B y C y los derivados agrícolamente aceptables de los compuestos activos B y C, siempre que los mismos tengan un grupo carboxilo.

    Synergistc herbicidal mixtures based on 3-phenyluracils

    公开(公告)号:NZ531486A

    公开(公告)日:2005-08-26

    申请号:NZ53148602

    申请日:2002-09-10

    Applicant: BASF AG

    Abstract: A herbicidally active composition is described to comprise the component (A), and at least one further active compound selected from (B) and (C). (A) contains at least one phenyluracil compound of formula (I) wherein: R1 is methyl or NH2; R2 isC1-C2-haloalkyl; R3 is hydrogen or halogen; R4 is halogen or cyano; R5 is hydrogen, cyano,C1-C6-alkyl, C1-C6-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C3-C7-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl or benzyl which is unsubstituted or substituted by halogen or alkyl; R6 and R7 are independently hydrogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C6-alkenyl, C3-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkenyl, phenyl or benzyl, where each of the 8 abovementioned substituents is unsubstituted or may be substituted by 1 to 6 halogen atoms and/or by one, two or three groups selected from: OH, NH2, CN, CONH2,C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, C1-C4-alkylamino, di(C1-C4-alkyl) amino, formyl, C1-C4-alkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl) aminocarbonyl, C3-C7-cycloalkyl, phenyl and benzyl; or R6 and R7 together with the nitrogen atom form a 3-, 4-, 5-, 6-or 7-membered saturated or unsaturated nitrogen heterocycle which may be substituted by 1 to 6 methyl groups and which may contain 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen and sulfur as ring members, and/or at least one of its agriculturally acceptable salts. (B) are herbicides selected from lipid biosynthesis inhibitors, acetolactate synthase inhibitors (ALS inhibitors), photosynthesis inhibitors, protoporphyrinogen-IX oxidase inhibitors, bleacher herbicides, enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors), glutamine synthetase inhibitors, 7,8-dihydropteroate synthase inhibitors (DHP inhibitors), mitose inhibitors, inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors), cellulose biosynthesis inhibitors, decoupler herbicides, auxin herbicides, auxin transport inhibitors and other herbicides selected from the group consisting of benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin,methyldymuron, etobenzanid, fosamine, metam, pyributicarb, oxaziclomefone, dazomet, triaziflam and methyl bromide. (C) are safeners selected from benoxacor, cloquintocet, cyometrinil, dichlormid, dicyclonon, dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, mefenpyr, mephenate, naphthalic anhydride,2, 2, 5-trimethyl-3- (dichloroacetyl)- 1,3-oxazolidine, 4- (dichloroacetyl)-l-oxa- 4-azaspiro [4.5] decane and oxabetrinil, the agriculturally acceptable salts of the active compounds B and C and the agriculturally acceptable derivatives of the active compounds B and C, provided they have a carboxyl group. The composition ratios are described to be for component (A) to (B) to range from 10:1 to 1:500; (A) to (C) from 10:1 to 1:10; and (B) to (C) from 50:1 to 1:10. The use of the compositions is to control undesirable vegetation in crops including rice, cotton, potatoes, and forestry, as well as for the desiccation and/or defoliation of plants.

    7.
    发明专利
    未知

    公开(公告)号:DE59611164D1

    公开(公告)日:2005-01-20

    申请号:DE59611164

    申请日:1996-09-12

    Applicant: BASF AG

    Abstract: Herbicidal mixt. comprises: (a) at least one fluoro-substd. sulphonyl urea derivs. of formula (I) or their salts; and (b) at least one herbicide in a synergistic amt. selected from e.g. buthidazole or cyprazole; allidochlor (CDDA), benzoylprop-ethyl, bromobutide, chlorthiamid, dimepiperate, dimethenamid, diphenamid, etobenzanid (benzchlomet), flampropmethyl, fosamin, isoxaben, monalide, naptalame, pronamid (propyzamid) or propanil; bilanafos (bialophos), buminafos, glufosinate ammonium, glyphospate or sulfosate; amitrole, anilofos or mefenacet; 2,4-D, 2,4-DB, clomeprop, dichlorprop, dichlorprop-P, dichlorprop-P (2,4-DP-P), fenoprop (2,4,5-TP, fluoroxypyr, MCPA, MCPB, mecoprop, mecoprop-P, napropamide, napropanilide or triclopyr, or salts of these. Z = N or CH; R1 = 1-6C alkyl opt. substd. by 1-5 OMe, OEt, SO2Me; CN; Cl; F; SMe; or S(O)Me; halo; ER6; COOR8; NO2; S(O)oR9, SO2NR10R11,; or CONR10R11; E = O; S or NR7; R2 = H; 1-4C alkyl or 1-4C alkoxy opt. substd. by halo; 2-4C alkenyl; 2-4C alkynyl; halo; SO2Me; SO2Et; NO2; CN; or 1-4C alkylthio; R3 = F, CF3; CF2Cl; CF2H; OCF3; OCF2Cl; Cl (when R1 - CO2Me and R2 = F); Me (when R1 = CH2CF3 or CF2CF3); or OCF2H or OCF2Br (when R4 =- OCF3 or OCF2Cl); R4 = OMe; OEt; Me or Et opt. substd. by halo; SMe; SEt; NHMe; NHEt; N(1-2C alkyl)2; or halo; R5 = H, OMe; OEt; or 1-4C alkyl; R6 = 1-4C alkyl, 2-4C alkenyl, 2-4C alkynyl or 3-6C cycloalkyl opt. substd by 1-5 halo (except allyl, OCH2F, OCF2Cl or 2-Cl-Et) when E = O or S; or SO2Me, SO2Et, SO2CF3, SO2-allyl or SO2-propargyl when E = O or NR7; R7 = H; Me; or Et; R8 = 1-6C alkyl opt. mono-, di- or trisubstd. by halo, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkoxy, 1-4C alkoxy-1-2C alkoxy, 3-7C cycloalkyl and/or Ph; 5-7C cycloalkyl opt. mono-, di- or trisubstd. by 1-4C alkyl; 3-6C alkenyl; or 3-6C alkynyl; R10 = H; OMe; OEt; or 1-6C alkyl; and R11 = 1-4C alkyl opt. substd by 1-4 halo or 1-4C alkoxy; or 3-6C cycloalkyl; or R10+R11 = 4-6C alkylene with 1 CH2 opt. replaced by O or 1-4C alkylimino; n = 0-3; and o = 1-2.

    8.
    发明专利
    未知

    公开(公告)号:ES2196176T3

    公开(公告)日:2003-12-16

    申请号:ES96932505

    申请日:1996-09-12

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/04000 Sec. 371 Date Mar. 17, 1998 Sec. 102(e) Date Mar. 17, 1998 PCT Filed Sep. 12, 1996 PCT Pub. No. WO97/10710 PCT Pub. Date Mar. 27, 1997Herbicidal compositions containing a) at least one cyclohexenone oxime ether of the formula I and b) at least one of the following 44 compounds: b1) bromobutide, dimepiperate, etobenzanid, propanil, b2) anilofos, mefenacet, b3) 2,4-D, MCPB, naproanilide, b4) bentazone, b5) pyrazolynate/pyrazolate, sulcotrione, b6) esprocarb, molinate, pyributicarb, thiobencarb/benthiocarb, b7) quinclorac, b8) butachlor, butenachlor, pretilachlor, thenylchlor, b9) cycloxydim, sethoxydim, b10) pendimethalin, b11) cyhalofop-butyl, fenoxaprop-ethyl, b12) benzofenap, pyrazoxyfen, b13) dithiopyr, b14) sodium 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]-benzoate and methyl 2-[(4,6-dimethoxypyrimidin-2-yl)-oxy]-6-[1-(methoxyimino)ethyl]benzoate; b15) azimsulfuron, bensulfuron-methyl, cinosulfuron, cyclosulfamuron, ethoxysulfuron, imazosulfuron, pyrazosulfuron-ethyl, b16) dimethametryn, simetryn/simetryne, b17) benfuresate, b18) cafenstrole, b19) cinmethylin, b20) piperophos, are described.

    9.
    发明专利
    未知

    公开(公告)号:AT241271T

    公开(公告)日:2003-06-15

    申请号:AT99929190

    申请日:1999-06-12

    Applicant: BASF AG

    Abstract: A synergistic herbicidal mixture comprising A) at least one compound of the formula I wherein R1, R3 are hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfinyl; R2 is optionally substituted thiazol-2-yl, thiazol-4-yl, thiazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl, 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of at least one herbicidal compound from the group of ACC inhibitors, ALS inhibitors, amides, aixin herbicides, auxin transport inhibitors, carotenoid biosynthesis inhibitors, ESPS inhibitors, glutamine synthetase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protoporphyrinogen IX oxidase inhibitors, photosynthesis inhibitors, synergists, growth substances, cell wall biosynthesis inhibitors and a variety of other herbicides. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.

    10.
    发明专利
    未知

    公开(公告)号:DK0861026T3

    公开(公告)日:2003-04-22

    申请号:DK96932505

    申请日:1996-09-12

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/04000 Sec. 371 Date Mar. 17, 1998 Sec. 102(e) Date Mar. 17, 1998 PCT Filed Sep. 12, 1996 PCT Pub. No. WO97/10710 PCT Pub. Date Mar. 27, 1997Herbicidal compositions containing a) at least one cyclohexenone oxime ether of the formula I and b) at least one of the following 44 compounds: b1) bromobutide, dimepiperate, etobenzanid, propanil, b2) anilofos, mefenacet, b3) 2,4-D, MCPB, naproanilide, b4) bentazone, b5) pyrazolynate/pyrazolate, sulcotrione, b6) esprocarb, molinate, pyributicarb, thiobencarb/benthiocarb, b7) quinclorac, b8) butachlor, butenachlor, pretilachlor, thenylchlor, b9) cycloxydim, sethoxydim, b10) pendimethalin, b11) cyhalofop-butyl, fenoxaprop-ethyl, b12) benzofenap, pyrazoxyfen, b13) dithiopyr, b14) sodium 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]-benzoate and methyl 2-[(4,6-dimethoxypyrimidin-2-yl)-oxy]-6-[1-(methoxyimino)ethyl]benzoate; b15) azimsulfuron, bensulfuron-methyl, cinosulfuron, cyclosulfamuron, ethoxysulfuron, imazosulfuron, pyrazosulfuron-ethyl, b16) dimethametryn, simetryn/simetryne, b17) benfuresate, b18) cafenstrole, b19) cinmethylin, b20) piperophos, are described.

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