公开(公告)号：JPH08252464A

公开(公告)日：1996-10-01

申请号：JP30912195

申请日：1995-11-28

Applicant: BASF AG

Inventor： TENTEN ANDREAS ,  WEIDLICH PETER ,  LINDEN GERD

IPC: B01J23/34 ,  B01J21/16 ,  B01J23/88 ,  B01J23/885 ,  B01J23/887 ,  B01J27/192 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J37/02 ,  C07B61/00 ,  C07C27/00 ,  C07C27/14 ,  C07C45/32 ,  C07C45/33 ,  C07C45/35 ,  C07C45/37 ,  C07C47/22 ,  C07C51/235 ,  C07C51/25 ,  C07C57/055

Abstract: PROBLEM TO BE SOLVED: To enable thickness control of catalyst outer shell comprising active oxide and to give a sufficient specific area, when forming a liquid adhesive from water and organic compound, by specifying a mixing ratio of both material and physical property of organic compound. SOLUTION: A carrier forming body is first moistened with a liquid adhesive. And after depositing by contacting an active oxide material of dried particles to the surface of the moistened carrier forming body, the liquid adhesive is removed from the moistened carrier forming body coated with the active oxide material. Consequently, a catalyst comprising the carrier forming body and the catalyst active oxide material provided on the surface of the carrier forming body is prepared. At this time as the liquid adhesive, a solution comprising 20-90 wt.% water and 10-80 wt.% organic compound 10 having boiling point or sublimation temperature of >100 deg.C, preferably >150 deg.C at atmosphere (1 atm) is used.

公开(公告)号：JP2000153154A

公开(公告)日：2000-06-06

申请号：JP28996599

申请日：1999-09-03

Applicant: BASF AG

Inventor： FRENZEL ANDREA ,  FREIRE ERDBRUEGGER CRISTINA DR ,  SCHWAB EKKEHARD ,  HESSE MICHAEL DR ,  LINDEN GERD ,  WANJEK HERBERT DR ,  ALLMANN HANS-MARTIN

IPC: B01J23/38 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J35/10 ,  B01J37/02 ,  C07B61/00 ,  C07C5/02 ,  C07C5/05 ,  C07C5/09 ,  C07C7/163

Abstract: PROBLEM TO BE SOLVED: To provide an improved method for the selective hydrogenation of unsaturated compds. in hydrocarbon streams, especially, the selective hydrogenation of alkine and/or alkadiene in 2-3C hydrocarbon streams. SOLUTION: At least one kind of a group X metal and at least one kind of a group XI metal are supported on an aluminum oxide carrier and the group X metal (single kind or plural kinds) is conc. on the outer layer near to the surface of each of catalyst particles and the group XI metal (single kind or plural kinds) is substatially uniformly distributed over the total vol. of catalyst particles and the wt. ratio of the group XI metal to the group X metal is below 1.95.

公开(公告)号：SG33603A1

公开(公告)日：1996-10-18

申请号：SG1995001935

申请日：1995-11-27

Applicant: BASF AG

Inventor： TENTEN ANDREAS ,  LINDEN GERD ,  WEIDLICH PETER

IPC: B01J23/34 ,  B01J21/16 ,  B01J23/88 ,  B01J23/885 ,  B01J23/887 ,  B01J27/192 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J37/02 ,  C07B61/00 ,  C07C27/00 ,  C07C27/14 ,  C07C45/32 ,  C07C45/33 ,  C07C45/35 ,  C07C45/37 ,  C07C47/22 ,  C07C51/235 ,  C07C51/25 ,  C07C57/055

Abstract: A catalyst having a catalytically active oxide on the surface of a carrier is mfd. by moistening the carrier with a liq. binder consisting of a soln. of 10-80 wt.% of organic binder dissolved in 20-90 wt.% of H2O, contacting its surface with finely divided oxide particles, and removing the binding agent. The organic binder has a b.pt. or sublimation temp. of > 100 degrees C at atmos. pressure. Also claimed are: (i) a shell catalyst consisting of a hollow cylinder carrier 2-10 mm long with an external dia. 4-10 mm and a 1-4 mm wall thickness coated on its external surface with an oxide of general formula Mo12VaX bX cX dX eX fX 6gOn in which, X is W, Nb, Ta, Cr and/or Ce, X is Cu, Ni, Co, Fe, Mn and/or Zn, X is Sb and/or Bi, X is 1 or more alkali metals, X is 1 or more alkaline earth metals, X is Si, Al, Ti and/or Zr and a = 1-6, b = 0.2-4, c = 0.5-18, d = 0-40, e = 0-2, f = 0-4, g = 0-40 and n is a number determined by the valency and the abundance of the different elements in the general formula. The thickness of oxide is 10-1000 mu m, the specific active surface is 20-30 m /g and a value of cX dX eX fOn in which, X is Ni and/or Co, X is Tl, an alkali metal and/or an alkaline earth metal, X is P, As, B, Sb, Sn, Ce, Pb, Nb and/or W, X is Si, Al, Ti and/or Zr and a = 0.5-5, b = 0.01-3, c = 3-10, d = 0.02-2, e = 0-5, f = 0-10 and n is a number determined by the valency and the abundance of the different elements in the general formula.

公开(公告)号：ES2198952T3

公开(公告)日：2004-02-01

申请号：ES99944416

申请日：1999-08-17

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  BAUER STEFAN ,  LINDEN GERD ,  PETERSEN HERMANN

IPC: B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

Abstract: A coated catalyst for the catalytic gas-phase oxidation of aromatic hydrocarbons comprises, on an inert nonporous support, a catalytically active composition comprising a defined amount of vanadium oxide, titanium dioxide, a cesium compound, a phosphorus compound, and antimony oxide, wherein the catalytically active composition is applied in two or more layers and where relative to the inner layer or inner layers the outer layer has an antimony oxide content which is from 50 to 100% lower and wherein the amount of catalytically active composition of the inner layer or layers is from 10 to 90% by weight of the amount of catalytically active composition, and can be used for preparing carboxylic acids and/or anhydrides, in particular phthalic anhydride; also specified is a production process for such catalysts.

公开(公告)号：CA1335856C

公开(公告)日：1995-06-06

申请号：CA607832

申请日：1989-08-09

Applicant: BASF AG

Inventor： EISENBARTH PHILIPP ,  LINDEN GERD ,  ALTSTAEDT VOLKER ,  ROLAND PETER

IPC: C08F216/12 ,  B32B27/04 ,  C07D213/69 ,  C07D237/16 ,  C08F16/32 ,  C08F20/52 ,  C08F222/40 ,  C08G73/12 ,  H01B1/24

Abstract: Heat-curable bismaleimide resins contain a bismaleimide and a heterocyclic comonomer having terminal alkenyl or alkenyloxy groups. A preferred comonomer is 2,6-bis-(2-propenylphenoxy)-pyridine. The bismaleimide resins are suitable for the production of high performance composites.

公开(公告)号：DE19840373A1

公开(公告)日：2000-03-09

申请号：DE19840373

申请日：1998-09-04

Applicant: BASF AG

Inventor： FRENZEL ANDREA ,  FREIRE ERDBRUEGGER CRISTINA ,  SCHWAB EKKEHARD ,  HESSE MICHAEL ,  LINDEN GERD ,  WANJEK HERBERT ,  ALLMANN HANS-MARTIN

IPC: B01J23/38 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J35/10 ,  B01J37/02 ,  C07B61/00 ,  C07C5/02 ,  C07C5/05 ,  C07C5/09 ,  C07C7/163 ,  C07C5/03

Abstract: Catalyst contains group 10 metal(s) (I) and group 11 metal(s) (II) on an alumina support, with (I) concentrated in the surface and (II) uniformly distributed over the volume of the catalyst granule and a (II)/(I) weight ratio NOTGREATER 1.95. An Independent claim is also included for the production of the catalyst.

公开(公告)号：DE19839001A1

公开(公告)日：2000-03-02

申请号：DE19839001

申请日：1998-08-27

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  BAUER STEFAN ,  LINDEN GERD ,  PETERSEN HERMANN

IPC: B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89 ,  C07B41/10

Abstract: Shell catalyst for catalytic gaseous phase oxidation of aromatic hydrocarbons, which contains in an inert non-porous support a catalytically active material with a given content of vanadium oxide, titanium oxide, a cesium compound, a phosphorus compound and antimony oxide, wherein the catalytically active material is applied in two or more layers and wherein the outer layers have 50 to 100 % less antimony oxide content than the inner layer or layers and wherein the amount of catalytically active material of the inner layer or layers accounts for 10 to 90 % by weight of the overall amount of total catalytically active material. The invention also relates to a method for the production of said catalysts and to a method for the production of carboxylic acids and/or carboxylic acid anhydrides and especially phthalic acid anhydride using said catalysts.

公开(公告)号：ES2119293T3

公开(公告)日：1998-10-01

申请号：ES95118264

申请日：1995-11-21

Applicant: BASF AG

Inventor： TENTEN ANDREAS ,  WEIDLICH PETER ,  LINDEN GERD

IPC: B01J23/34 ,  B01J21/16 ,  B01J23/88 ,  B01J23/885 ,  B01J23/887 ,  B01J27/192 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J37/02 ,  C07B61/00 ,  C07C27/00 ,  C07C27/14 ,  C07C45/32 ,  C07C45/33 ,  C07C45/35 ,  C07C45/37 ,  C07C47/22 ,  C07C51/235 ,  C07C51/25 ,  C07C57/055

Abstract: A catalyst having a catalytically active oxide on the surface of a carrier is mfd. by moistening the carrier with a liq. binder consisting of a soln. of 10-80 wt.% of organic binder dissolved in 20-90 wt.% of H2O, contacting its surface with finely divided oxide particles, and removing the binding agent. The organic binder has a b.pt. or sublimation temp. of > 100 degrees C at atmos. pressure. Also claimed are: (i) a shell catalyst consisting of a hollow cylinder carrier 2-10 mm long with an external dia. 4-10 mm and a 1-4 mm wall thickness coated on its external surface with an oxide of general formula Mo12VaX bX cX dX eX fX 6gOn in which, X is W, Nb, Ta, Cr and/or Ce, X is Cu, Ni, Co, Fe, Mn and/or Zn, X is Sb and/or Bi, X is 1 or more alkali metals, X is 1 or more alkaline earth metals, X is Si, Al, Ti and/or Zr and a = 1-6, b = 0.2-4, c = 0.5-18, d = 0-40, e = 0-2, f = 0-4, g = 0-40 and n is a number determined by the valency and the abundance of the different elements in the general formula. The thickness of oxide is 10-1000 mu m, the specific active surface is 20-30 m /g and a value of cX dX eX fOn in which, X is Ni and/or Co, X is Tl, an alkali metal and/or an alkaline earth metal, X is P, As, B, Sb, Sn, Ce, Pb, Nb and/or W, X is Si, Al, Ti and/or Zr and a = 0.5-5, b = 0.01-3, c = 3-10, d = 0.02-2, e = 0-5, f = 0-10 and n is a number determined by the valency and the abundance of the different elements in the general formula.

公开(公告)号：CZ9503112A3

公开(公告)日：1997-07-16

申请号：CZ311295

申请日：1995-11-24

Applicant: BASF AG

Inventor： TENTEN ANDREAS ,  WEIDLICH PETER ,  LINDEN GERD

IPC: B01J23/34 ,  B01J21/16 ,  B01J23/88 ,  B01J23/885 ,  B01J23/887 ,  B01J27/192 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J37/02 ,  C07B61/00 ,  C07C27/00 ,  C07C27/14 ,  C07C45/32 ,  C07C45/33 ,  C07C45/35 ,  C07C45/37 ,  C07C47/22 ,  C07C51/235 ,  C07C51/25 ,  C07C57/055

CPC classification number: C07C45/37 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/026 ,  B01J37/0215 ,  B01J37/0217 ,  B01J37/0223 ,  B01J2523/00 ,  C07C45/32 ,  C07C45/33 ,  C07C45/35 ,  C07C51/252 ,  Y10S502/523 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

公开(公告)号：DE59905354D1

公开(公告)日：2003-06-05

申请号：DE59905354

申请日：1999-08-17

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  BAUER STEFAN ,  LINDEN GERD ,  PETERSEN HERMANN

IPC: B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

Abstract: A coated catalyst for the catalytic gas-phase oxidation of aromatic hydrocarbons comprises, on an inert nonporous support, a catalytically active composition comprising a defined amount of vanadium oxide, titanium dioxide, a cesium compound, a phosphorus compound, and antimony oxide, wherein the catalytically active composition is applied in two or more layers and where relative to the inner layer or inner layers the outer layer has an antimony oxide content which is from 50 to 100% lower and wherein the amount of catalytically active composition of the inner layer or layers is from 10 to 90% by weight of the amount of catalytically active composition, and can be used for preparing carboxylic acids and/or anhydrides, in particular phthalic anhydride; also specified is a production process for such catalysts.