公开(公告)号：WO2004078678A3

公开(公告)日：2004-11-04

申请号：PCT/EP2004002180

申请日：2004-03-04

Applicant: BASF AG ,  STROEFER ECKHARD ,  LANG NEVEN ,  HASSE HANS ,  GRUETZNER THOMAS ,  OTT MICHAEL

Inventor： STROEFER ECKHARD ,  LANG NEVEN ,  HASSE HANS ,  GRUETZNER THOMAS ,  OTT MICHAEL

IPC: C07C45/00 ,  C07C45/82 ,  C07C47/058

CPC classification number: C07C45/002 ,  C07C45/82 ,  C07C47/04

Abstract: A method for the production of highly concentrated formaldehyde solutions containing ≥ 50 wt. % CH2O from an aqueous formaldehyde solution having a lower CH2O content by evaporating part of said solution (partial evaporation), wherein the aqueous formaldehyde solution is heated to an evaporation temperature T wherein water becomes enriched in a gaseous phase in relation to the liquid phase and the formed gas phase is continuously or discontinuously removed. For the evaporation temperature T: T [ °C]

公开(公告)号：NO20062749A

公开(公告)日：2006-07-12

申请号：NO20062749

申请日：2006-06-13

Applicant: BASF AG

Inventor： STAMMER ACHIM ,  HASSE HANS ,  STROEFER ECKHARD ,  GRUETZNER THOMAS ,  LANG NEVEN ,  SIEGERT MARKUS ,  FRIESE THORSTEN ,  OTT MICHAEL ,  BLAGOV SERGEJ

IPC: B01D3/14 ,  B01D3/36 ,  C07D323/06

CPC classification number: C07D323/06 ,  B01D3/146 ,  B01D3/36 ,  Y02P20/127

公开(公告)号：AU2004308627A1

公开(公告)日：2005-07-14

申请号：AU2004308627

申请日：2004-12-21

Applicant: BASF AG

Inventor： OTT MICHAEL ,  GRUTZNER THOMAS ,  FRIESE THORSTEN ,  LANG NEVEN ,  HASSE HANS ,  SIEGERT MARKUS ,  STAMMER ACHIM ,  BLAGOV SERGEJ ,  STROEFER ECKHARD

IPC: C07D323/06 ,  B01D3/14 ,  B01D3/36

Abstract: A process for removing trioxane from a mixture I of formaldehyde, trioxane and water, by a) distilling the mixture I in a first distillation stage at a pressure of from 0.1 to 2 bar to obtain a stream II which comprises formaldehyde and a stream III which comprises predominantly trioxane and additionally water and formaldehyde, b) mixing the stream III with a recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde to obtain a stream IIIa which comprises predominantly trioxane and additionally water and formaldehyde, c) distilling the stream IIIa, if appropriate after removing low boilers from the stream III or IIIa in a further distillation stage, in a second distillation stage at a pressure of from 0.2 to 10 bar, the pressure in the second distillation stage being at least 0.1 bar higher than the pressure in the first distillation stage, to obtain a stream IV of trioxane and a stream V which comprises predominantly trioxane and additionally water and formaldehyde, d) distilling the stream V in a third distillation stage at a pressure of from 0.1 to 4 bar to obtain a stream VI which comprises predominantly water and additionally formaldehyde, and the recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde, e) if appropriate, distilling the stream VI in a fourth distillation stage to obtain a stream VIII which comprises predominantly water, and a stream IX which comprises predominantly formaldehyde.

公开(公告)号：DE10309289A1

公开(公告)日：2004-09-16

申请号：DE10309289

申请日：2003-03-04

Applicant: BASF AG

Inventor： STROEFER ECKHARD ,  LANG NEVEN ,  HASSE HANS ,  GRUETZNER THOMAS ,  OTT MICHAEL

IPC: C07C45/00 ,  C07C45/82 ,  C07C47/058 ,  C02F1/08

Abstract: Process for preparing high-concentration formaldehyde solutions having a CH 2 O content of >=50% by weight from an aqueous formaldehyde solution having a lower CH 2 O content by evaporation of part of this solution (partial evaporation), in which the aqueous formaldehyde solution is heated to an evaporation temperature T at which the gas phase becomes enriched in water relative to the liquid phase and the gas phase formed is taken off continuously or discontinuously, wherein the evaporation temperature T obeys the relationship: T[° C.] max [° C.] where T max (c)=A+Bx(c/100)+Cx(c/100) 2 +Dx(c/100) 3 and A=+68.759, B=+124.77, C=-12.851, D=-10.095, where c is the instantaneous CH 2 O content of the aqueous formaldehyde solution during the evaporation in percent by weight and is from 20 to 99% by weight.

公开(公告)号：MY141052A

公开(公告)日：2010-02-25

申请号：MYPI20040732

申请日：2004-03-03

Applicant: BASF AG

Inventor： STROEFER ECKHARD DR ,  LANG NEVEN DR ,  STEINBRENNER ULRICH DR ,  HASSE HANS PROF DR ,  OTT MICHAEL ,  GRUETZNER THOMAS

IPC: C07C45/78 ,  C07C45/00 ,  C07C45/82 ,  C07C47/058

Abstract: PROCESS FOR PREPARING HIGH-CONCENTRATION GASEOUS FORMALDEHYDE HAVING A MOLAR CH2O:H2O RATIO OF >= O.6 FROM AN AQUEOUS FORMALDEHYDE SOLUTION BY EVAPORATION OF AT LEAST PART OF THE SOLUTION, IN WHICH THE AQUEOUS FORMALDEHYDE SOLUTION IS HEATED TO A VAPORIZATION TEMPERATURE T AND THE GAS PHASE FORMED IS TAKEN OFF, WHEREIN THE EVAPORATION TEMPERATURE T OBEYS THE RELATIONSHIP:

公开(公告)号：NO20062749L

公开(公告)日：2006-07-12

申请号：NO20062749

申请日：2006-06-13

Applicant: BASF AG

Inventor： STAMMER ACHIM ,  HASSE HANS ,  STROEFER ECKHARD ,  GRUETZNER THOMAS ,  LANG NEVEN ,  SIEGERT MARKUS ,  FRIESE THORSTEN ,  OTT MICHAEL ,  BLAGOV SERGEJ

IPC: B01D3/14 ,  B01D3/36 ,  C07D323/06

Abstract: A process for removing trioxane from a mixture I of formaldehyde, trioxane and water, by a) distilling the mixture I in a first distillation stage at a pressure of from 0.1 to 2 bar to obtain a stream II which comprises formaldehyde and a stream III which comprises predominantly trioxane and additionally water and formaldehyde, b) mixing the stream III with a recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde to obtain a stream IIIa which comprises predominantly trioxane and additionally water and formaldehyde, c) distilling the stream IIIa, if appropriate after removing low boilers from the stream III or IIIa in a further distillation stage, in a second distillation stage at a pressure of from 0.2 to 10 bar, the pressure in the second distillation stage being at least 0.1 bar higher than the pressure in the first distillation stage, to obtain a stream IV of trioxane and a stream V which comprises predominantly trioxane and additionally water and formaldehyde, d) distilling the stream V in a third distillation stage at a pressure of from 0.1 to 4 bar to obtain a stream VI which comprises predominantly water and additionally formaldehyde, and the recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde, e) if appropriate, distilling the stream VI in a fourth distillation stage to obtain a stream VIII which comprises predominantly water, and a stream IX which comprises predominantly formaldehyde.

公开(公告)号：CA2548640A1

公开(公告)日：2005-07-14

申请号：CA2548640

申请日：2004-12-21

Applicant: BASF AG

Inventor： GRUETZNER THOMAS ,  STROEFER ECKHARD ,  HASSE HANS ,  BLAGOV SERGEJ ,  STAMMER ACHIM ,  OTT MICHAEL ,  SIEGERT MARKUS ,  FRIESE THORSTEN ,  LANG NEVEN

IPC: B01D3/36 ,  B01D3/14 ,  C07D323/06

Abstract: The invention relates to a method for separating trioxane from a mixture containing formaldehyde, trioxane and water. According to said method: the mixture (1) is distilled in a first distillation stage (7) at a pressure of between 0.1 and 2 bar to obtain a stream (8) containing formaldehyde and a stream (9) containing predominantly trioxane, in addition to water and formaldehyde; the stream (9) is mixed with a recycling stream (19) containin g predominantly trioxane, in addition to water and formaldehyde to form a stre am (10) containing predominantly trioxane, in addition to water and formaldehyd e; the stream (10) is then distilled in a second distillation stage (14) at a pressure of between 0.2 and 10 bar, optionally after the separation of low- boilers from the stream (9) or (10) in an additional distillation stage (11) . The pressure in the second distillation stage (14) is at least 0.1 bar highe r than the pressure in the first distillation stage (7). Said distillation produces a stream (15) consisting of trioxane and a stream (16) containing predominantly trioxane, in addition to water and formaldehyde. The stream (1 6) is then distilled in a third distillation stage (17) at a pressure of betwee n 0.1 and 4 bar, to obtain a stream (18) containing predominantly water, in addition to formaldehyde and the recycling stream (19) containing predominantly trioxane, in addition to water and formaldehyde. The resultant stream (18) is optionally distilled in a fourth distillation stage (20), to obtain a stream (21) containing predominantly water and a stream (22) containing predominantly formaldehyde.

公开(公告)号：BRPI0417859A

公开(公告)日：2007-04-27

申请号：BRPI0417859

申请日：2004-12-21

Applicant: BASF AG

Inventor： LANG NEVEN ,  STROEFER ECKHARD ,  STAMMER ACHIM ,  FRIESE THORSTEN ,  SIEGERT MARKUS ,  OTT MICHAEL ,  HASSE HANS ,  GRUETZNER THOMAS ,  BLAGOV SERGEJ

IPC: B01D3/36 ,  B01D3/14 ,  C07D323/06

Abstract: A process for removing trioxane from a mixture I of formaldehyde, trioxane and water, by a) distilling the mixture I in a first distillation stage at a pressure of from 0.1 to 2 bar to obtain a stream II which comprises formaldehyde and a stream III which comprises predominantly trioxane and additionally water and formaldehyde, b) mixing the stream III with a recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde to obtain a stream IIIa which comprises predominantly trioxane and additionally water and formaldehyde, c) distilling the stream IIIa, if appropriate after removing low boilers from the stream III or IIIa in a further distillation stage, in a second distillation stage at a pressure of from 0.2 to 10 bar, the pressure in the second distillation stage being at least 0.1 bar higher than the pressure in the first distillation stage, to obtain a stream IV of trioxane and a stream V which comprises predominantly trioxane and additionally water and formaldehyde, d) distilling the stream V in a third distillation stage at a pressure of from 0.1 to 4 bar to obtain a stream VI which comprises predominantly water and additionally formaldehyde, and the recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde, e) if appropriate, distilling the stream VI in a fourth distillation stage to obtain a stream VIII which comprises predominantly water, and a stream IX which comprises predominantly formaldehyde.

公开(公告)号：DE10361518A1

公开(公告)日：2005-07-28

申请号：DE10361518

申请日：2003-12-23

Applicant: BASF AG

Inventor： LANG NEVEN ,  STROEFER ECKHARD ,  STAMMER ACHIM ,  FRIESE THORSTEN ,  SIEGERT MARKUS ,  OTT MICHAEL ,  HASSE HANS ,  GRUETZNER THOMAS ,  BLAGOV SERGEJ

IPC: B01D3/14 ,  B01D3/36 ,  C07D323/06

Abstract: A process for removing trioxane from a mixture I of formaldehyde, trioxane and water, by a) distilling the mixture I in a first distillation stage at a pressure of from 0.1 to 2 bar to obtain a stream II which comprises formaldehyde and a stream III which comprises predominantly trioxane and additionally water and formaldehyde, b) mixing the stream III with a recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde to obtain a stream IIIa which comprises predominantly trioxane and additionally water and formaldehyde, c) distilling the stream IIIa, if appropriate after removing low boilers from the stream III or IIIa in a further distillation stage, in a second distillation stage at a pressure of from 0.2 to 10 bar, the pressure in the second distillation stage being at least 0.1 bar higher than the pressure in the first distillation stage, to obtain a stream IV of trioxane and a stream V which comprises predominantly trioxane and additionally water and formaldehyde, d) distilling the stream V in a third distillation stage at a pressure of from 0.1 to 4 bar to obtain a stream VI which comprises predominantly water and additionally formaldehyde, and the recycle stream VII which comprises predominantly trioxane and additionally water and formaldehyde, e) if appropriate, distilling the stream VI in a fourth distillation stage to obtain a stream VIII which comprises predominantly water, and a stream IX which comprises predominantly formaldehyde.

公开(公告)号：DE10309288A1

公开(公告)日：2004-09-16

申请号：DE10309288

申请日：2003-03-04

Applicant: BASF AG

Inventor： STROEFER ECKHARD ,  LANG NEVEN ,  STEINBRENNER ULRICH ,  HASSE HANS ,  OTT MICHAEL ,  GRUETZNER THOMAS

IPC: C07C45/00 ,  C07C45/82 ,  C07C47/058 ,  C02F1/08

Abstract: Process for preparing high-concentration gaseous formaldehyde having a molar CH 2 O:H 2 O ratio of >=0.6 from an aqueous formaldehyde solution by evaporation of at least part of the solution, in which the aqueous formaldehyde solution is heated to a vaporization temperature T and the gas phase formed is taken off, wherein the evaporation temperature T obeys the relationship: T[° C.]>=T' min [° C.] where T' min (c)=A+Bx(c/100)+Cx(c/100) 2 +Dx(c/100) 3 and A=+68.759, B=+124.77, C=-12.851, D=-10.095, where c is the instantaneous CH 2 O content of the aqueous formaldehyde solution during the evaporation in percent by weight and is from 20 to 99% by weight.