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公开(公告)号：NO20051652A
公开(公告)日：2005-05-25
申请号：NO20051652
申请日：2005-04-04
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , PASTRE JORG , STUEER WOLFRAM , EXNER KAI MICHAEL , GEISSLER ELKE
CPC classification number: C07C51/54 , C07C51/09 , C07C51/56 , Y02P20/582 , C07C53/02 , C07C57/04 , C07C53/124 , C07C53/122 , C07C63/313 , C07C53/12
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公开(公告)号：MXPA05001090A
公开(公告)日：2005-04-28
申请号：MXPA05001090
申请日：2003-07-30
Applicant: BASF AG
Inventor： PASTRE JORG
IPC: A23K1/16 , A01N1/00 , A01N3/00 , A61K31/19 , A61P3/00 , B01D9/02 , C07C51/09 , C07C51/41 , C07C53/06 , C07C53/02
Abstract: Procedimiento para la obtencion de formiatos de acido formico, en donde (a) se hidroliza ester metilico de acido formico parcialmente con agua; (b) se destila de la mezcla de reaccion obtenida en la etapa de procedimiento (a) el ester metilico de acido formico y metanol, formandose una corriente que contiene acido formico y agua; (c) se transforma la corriente que contiene ester metilico de acido formico eventualmente metanol de la etapa de procedimiento (b) por (i) reaccion con un compuesto basico con un valor pka del acido correspondiente de la respectiva etapa de disociacion de 3 3, medido a 25_C en solucion acuosa, en presencia de agua, y (ii) separacion destilativa del metanol en una corriente que contiene formiato y agua; y (d) se reune la corriente que contiene el acido formico y agua de la etapa de procedimiento (b) y la corriente que contiene formiato y agua de la etapa de procedimiento (c), formandose una mezcla que contiene el formiato de acido formico y agua. Un dispositivo para su obtencion y el uso de los mismos.
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公开(公告)号：NO20050534A
公开(公告)日：2005-03-02
申请号：NO20050534
申请日：2005-01-31
Applicant: BASF AG
Inventor： PASTRE JORG , KARL JORN , ADAMI CHRISTOPH , HAUK ALEXANDER , LENZ ROBERT , BOHLING RALF
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公开(公告)号：NO20040560L
公开(公告)日：2004-03-31
申请号：NO20040560
申请日：2004-02-06
Applicant: BASF AG
Inventor： ZEHNER PETER , PASTRE JORG , STUEER WOLFRAM
IPC: C07C27/02 , C07C27/00 , C07C45/41 , C07C45/46 , C07C45/89 , C07C49/90 , C07C51/083 , C07C51/09 , C07C51/56 , C07C53/02 , C07C53/08 , C07C67/00 , C07C67/08 , C07C67/10 , C07C67/297 , C07C69/14 , C07C69/15
Abstract: Joint production of formic acid with a \- 2C carboxylic acid (or derivative) involves transesterifying a formic ester (I) with a \- 2C carboxylic acid (II) to give formic acid (III) and the corresponding carboxylic acid ester (IV), and carbonylating part of (IV) to the corresponding carboxylic acid anhydride (V).
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公开(公告)号：NO331010B1
公开(公告)日：2011-09-05
申请号：NO20051652
申请日：2005-04-04
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , PASTRE JORG , STUEER WOLFRAM , EXNER KAI MICHAEL , GEISSLER ELKE
Abstract: Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).
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Patent Agency Ranking
公开(公告)号：NO20051652L
公开(公告)日：2005-05-25
申请号：NO20051652
申请日：2005-04-04
Applicant: BASF AG
Inventor： MACHHAMMER OTTO , PASTRE JORG , STUEER WOLFRAM , EXNER KAI MICHAEL , GEISSLER ELKE
Abstract: Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).
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公开(公告)号：MXPA05001135A
公开(公告)日：2005-05-16
申请号：MXPA05001135
申请日：2003-07-30
Applicant: BASF AG
Inventor： PASTRE JORG
Abstract: Procedimiento para la obtencion de formiatos de acido formico, en donde (a) se hidroliza ester metilico de acido formico parcialmente con agua; (b) se separa de la mezcla de reaccion procedente de la etapa de procedimiento (a) el ester metilico de acido formico y el metano! por destilacion, formandose una corriente que contiene acido formico y agua; y (c) se reune la corriente que contiene acido formico y agua de la etapa de procedimiento (b) con el correspondiente formiato, formandose una mezcla que contiene el formiato de acido formico y agua, un dispositivo para su obtencion y el uso de los mismos.
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公开(公告)号：NO20050538L
公开(公告)日：2005-02-28
申请号：NO20050538
申请日：2005-01-31
Applicant: BASF AG
Inventor： PASTRE JORG , KARL JORN , ADAMI CHRISTOPH , HAUK ALEXANDER , LENZ ROBERT , BOHLING RALF
IPC: A23K1/16 , A01N1/00 , A01N3/00 , A61K31/19 , A61P3/00 , B01D9/02 , C07C51/09 , C07C51/41 , C07C53/06 , C07C53/02
Abstract: Formic acid-formates are produced by (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give (S1) formic acid and water, (c) conversion of the other product from (b) (mainly MF) into a stream (S2) containing formate and water by reaction with aqueous strong base and distillation of methanol, and (d) combination of (S1) with (S2). A method for the production of formic acid-formates (I) involves: (a) partial hydrolysis of methyl formate (MF) with water; (b) distillation to give a stream (S1) containing formic acid and water; (c) conversion of the MF- and possibly methanol-containing stream from (b) into a formate- and water-containing stream (S2) by (i) reaction with a basic compound of an acid with a pKa value of at least 3 in presence of water followed by (ii) removal of methanol by distillation; and (d) combination of streams (S1) and (S2). An Independent claim is also included for apparatus for the production of (I), comprising: (A) a reactor for the hydrolysis of MF; (B) a distillation column for separating a stream containing MF, formic acid, methanol and water; (C) a column for the hydrolysis of MF with a basic compound with removal of methanol by distillation (with an inlet for the base above the inlet for the product from (B)); and (D) a column connected to the bottom of (B) for removing water from the stream containing formic acid and water.
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公开(公告)号：NO20040560A
公开(公告)日：2004-03-31
申请号：NO20040560
申请日：2004-02-06
Applicant: BASF AG
Inventor： ZEHNER PETER , PASTRE JORG , STUEER WOLFRAM
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公开(公告)号：AU2003253357A1
公开(公告)日：2004-03-29
申请号：AU2003253357
申请日：2003-07-30
Applicant: BASF AG
Inventor： ADAMI CHRISTOPH , KARL JORN , HAUK ALEXANDER , BOHLING RALF , PASTRE JORG , LENZ ROBERT
Abstract: A method for the production of formic acid-formates (I) involves (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give formic acid and water (stream S1) and (c) combination of (S1) with the corresponding formate (F) to give a mixture of (I) and water. An Independent claim is also included for apparatus for the production of (I), comprising a reactor (A) for the hydrolysis of MF, a distillation column (B) for separating a stream containing MF, formic acid, methanol and water into MF, methanol and a stream (S1) containing formic acid and water, and a column (E) for removing water from S1.
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