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    6.
    发明专利
    未知

    公开(公告)号：DE50302087D1

    公开(公告)日：2006-02-02

    申请号：DE50302087

    申请日：2003-09-12

    Applicant: BASF AG

    Inventor： WALSDORFF CHRISTIAN ,  FIENE MARTIN ,  ADAMI CHRISTOPH ,  STROEFER ECKHARD ,  HARTH KLAUS

    IPC: B01J23/46 ,  C01B7/00 ,  C01B7/04

    Abstract: Production of chlorine by catalytic gas-phase oxidation of hydrogen chloride (HCl), in which an HCl-containing gas and an oxygen-containing gas are fed into a reaction zone containing a fixed bed of catalyst to give a product gas comprising chlorine, oxygen, HCl and water vapor, comprises removing a recycle stream from the product gas and recycling it to the reaction zone.

    METODO PARA PRODUCIR FORMIATOS DE ACIDO FORMICO.
    7.
    发明专利
    METODO PARA PRODUCIR FORMIATOS DE ACIDO FORMICO. 未知

    公开(公告)号：MXPA05011691A

    公开(公告)日：2006-01-23

    申请号：MXPA05011691

    申请日：2004-05-14

    Applicant: BASF AG

    Inventor： ADAMI CHRISTOPH

    IPC: C07C51/09 ,  C07C51/41 ,  C07C53/02 ,  C07C53/06

    Abstract: La invencion se relaciona a un metodo para producir formiatos del acido que consisten de suministrar una corriente (I) fluida que contiene acido formico y una corriente (II) fluida que contiene formiato metalico y en la mezcla de la corriente (I) fluida y la corriente (II) fluida para obtener formiato de acido formico correspondiente. Tal invencion se caracteriza en que una corriente (III) fluida de la corriente que contiene componentes de formiato metalico, metanolato metalico, metanol y metilester del acido formico (MeFo) en una relacion >0.1% en masa se inserta dentro la corriente (I) fluida o el precursor del mismo, dentro de la corriente (II) fluida o los precursores del mismo o dentro de una mezcla que se forma por las corrientes (I) y (II) fluidas. La corriente (III) fluida se obtiene por un metodo para producir MeFo carbonilando .metanol en un reactor a una presion de hasta 50 MPa absolutos en la presencia de metanolato metalico que se utiliza como un catalizador homogeneo.

    PREPARACION DE FORMIATOS ACIDOS
    8.
    发明专利
    PREPARACION DE FORMIATOS ACIDOS 未知

    公开(公告)号：AR044327A1

    公开(公告)日：2005-09-07

    申请号：ARP040101638

    申请日：2004-05-14

    Applicant: BASF AG

    Inventor： HAUK ALEXANDER ,  KARL JOERN ,  LENZ ROBERT ,  ADAMI CHRISTOPH

    IPC: C07C51/41 ,  C07C53/02 ,  C07C53/06 ,  C07C51/09 ,  A23L3/3508

    Abstract: Un proceso para la preparación de formiatos ácidos mediante la provisión de una corriente líquida (I) que contiene ácido fórmico y una corriente líquida (II) que contiene un formiato de metal y la mezcla de la corriente líquida (I) con al corriente líquida (II), para obtener el correspondiente formiato ácido, que comprende la alimentación a la corriente líquida (I) o uno de sus precursores, a la corriente líquida (II) o uno de sus precursores, o a la mezcla de las corrientes líquidas(I) y (II), de una corriente líquida (III) que contiene los siguientes componentes en contenidos de, en cada caso, > 0,1 % en peso: formiato de metal, metóxido de metal, metanol y MeFo (MeFo), que se produce en un proceso para la preparación de MeFo por carbonilación de metanol en un reactor a una presión absoluta de hasta 50 MPa en presencia de un metóxido de metal como catalizador homogéneo. Uso de formiatos ácidos preparados en el proceso descripto para conservar y/o acidificar material vegetal y/o material animal, para el tratamiento de desechos biológicos, o como aditivo para la nutrición animal y/o como promotor del crecimiento de animales.

    9.
    发明专利
    未知

    公开(公告)号：BR0313245A

    公开(公告)日：2005-06-14

    申请号：BR0313245

    申请日：2003-07-30

    Applicant: BASF AG

    Inventor： ADAMI CHRISTOPH ,  KARL JOERN ,  HAUK ALEXANDER ,  BOEHLING RALF ,  PASTRE JOERG ,  LENZ ROBERT

    IPC: A23K1/16 ,  A01N1/00 ,  A01N3/00 ,  A61K31/19 ,  A61P3/00 ,  B01D9/02 ,  C07C51/09 ,  C07C51/41 ,  C07C53/06 ,  C07C53/02

    Abstract: Formic acid-formates are produced by (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give (S1) formic acid and water, (c) conversion of the other product from (b) (mainly MF) into a stream (S2) containing formate and water by reaction with aqueous strong base and distillation of methanol, and (d) combination of (S1) with (S2). A method for the production of formic acid-formates (I) involves: (a) partial hydrolysis of methyl formate (MF) with water; (b) distillation to give a stream (S1) containing formic acid and water; (c) conversion of the MF- and possibly methanol-containing stream from (b) into a formate- and water-containing stream (S2) by (i) reaction with a basic compound of an acid with a pKa value of at least 3 in presence of water followed by (ii) removal of methanol by distillation; and (d) combination of streams (S1) and (S2). An Independent claim is also included for apparatus for the production of (I), comprising: (A) a reactor for the hydrolysis of MF; (B) a distillation column for separating a stream containing MF, formic acid, methanol and water; (C) a column for the hydrolysis of MF with a basic compound with removal of methanol by distillation (with an inlet for the base above the inlet for the product from (B)); and (D) a column connected to the bottom of (B) for removing water from the stream containing formic acid and water.

    10.
    发明专利
    未知

    公开(公告)号：NO20050538L

    公开(公告)日：2005-02-28

    申请号：NO20050538

    申请日：2005-01-31

    Applicant: BASF AG

    Inventor： PASTRE JORG ,  KARL JORN ,  ADAMI CHRISTOPH ,  HAUK ALEXANDER ,  LENZ ROBERT ,  BOHLING RALF

    IPC: A23K1/16 ,  A01N1/00 ,  A01N3/00 ,  A61K31/19 ,  A61P3/00 ,  B01D9/02 ,  C07C51/09 ,  C07C51/41 ,  C07C53/06 ,  C07C53/02

    Abstract: Formic acid-formates are produced by (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give (S1) formic acid and water, (c) conversion of the other product from (b) (mainly MF) into a stream (S2) containing formate and water by reaction with aqueous strong base and distillation of methanol, and (d) combination of (S1) with (S2). A method for the production of formic acid-formates (I) involves: (a) partial hydrolysis of methyl formate (MF) with water; (b) distillation to give a stream (S1) containing formic acid and water; (c) conversion of the MF- and possibly methanol-containing stream from (b) into a formate- and water-containing stream (S2) by (i) reaction with a basic compound of an acid with a pKa value of at least 3 in presence of water followed by (ii) removal of methanol by distillation; and (d) combination of streams (S1) and (S2). An Independent claim is also included for apparatus for the production of (I), comprising: (A) a reactor for the hydrolysis of MF; (B) a distillation column for separating a stream containing MF, formic acid, methanol and water; (C) a column for the hydrolysis of MF with a basic compound with removal of methanol by distillation (with an inlet for the base above the inlet for the product from (B)); and (D) a column connected to the bottom of (B) for removing water from the stream containing formic acid and water.

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