METHOD FOR THE PRODUCTION OF 1.6-HEXANEDIOL
    1.
    发明申请
    METHOD FOR THE PRODUCTION OF 1.6-HEXANEDIOL 审中-公开
    用于生产1,6-己二醇

    公开(公告)号:WO2004054948A8

    公开(公告)日:2005-06-23

    申请号:PCT/EP0313634

    申请日:2003-12-03

    CPC classification number: C07C29/177 C07C31/20

    Abstract: The invention relates to a method for producing 1,6-hexanediol having a purity of > 99.5 wt. % by catalytic dimerisation of acrylic acid esters, catalytic hydrogenation of the thus obtained hexene diacidic diester in order to form 1.6-hexanediol. Said method consists in: a) dimerising C1- C8-acrylic acid esters in the presence of at least one rhodium compound in order to form mixtures predominantly of 2- and 3-hexene diacdic diesters, b) hydrating the obtained dimerisation discharge in the presence of chrome-free catalysts containing mainly copper as a hydrogenation component and c) purifying the thus obtained raw 1.6-hexanediol by fractionating distillation.

    Abstract translation: 本发明涉及一种用于制备具有> 99.5重量%的纯度的1,6-己二醇,由丙烯酸酯,以这种方式获得成1,6-己二醇的二酯己烯的催化氢化方法,其包括催化二聚化:一个 )C1至C8丙烯酸酯在二聚的至少一种铑化合物的存在下,得到主要为2-和3-己烯二酯的混合物,b)中氢化在无铬的存在下将所得二聚化流出物,含有作为氢化主要是铜催化剂,和c)将如此得到的粗1 1,6-己二醇通过分馏进行纯化。

    METHOD FOR ISOLATING A HOMOGENEOUS CATALYST CONTAINING RHODIUM

    公开(公告)号:CA2529247A1

    公开(公告)日:2004-12-29

    申请号:CA2529247

    申请日:2004-06-19

    Applicant: BASF AG

    Abstract: The invention relates to a distillation method for isolating a compound comprising at least two functional groups, selected independently of one another from a group consisting of a nitrile group, carboxylic acid group, carboxylic acid ester group and a carboxamide group from a mixture containin g a compound comprising at least two functional groups, selected independently of one another from a group consisting of a nitrile group, carboxylic acid group, carboxylic acid ester group and a carboxamide group and a rhodium containing compound that is homogeneous in the mixture.

    3.
    发明专利
    未知

    公开(公告)号:DE10249928A1

    公开(公告)日:2004-05-06

    申请号:DE10249928

    申请日:2002-10-26

    Applicant: BASF AG

    Abstract: Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).

    6.
    发明专利
    未知

    公开(公告)号:BRPI0411786A

    公开(公告)日:2006-08-08

    申请号:BRPI0411786

    申请日:2004-06-11

    Applicant: BASF AG

    Abstract: A process for separating a mixture comprising a) a monoolefinically unsaturated compound which is obtainable by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, or a saturated compound obtained by hydrogenating such a compound, b) a compound which is obtainable by adding more than two of the terminal olefins mentioned in a) or a compound obtained by hydrogenating such a compound, and c) a compound which contains a transition metal, is homogeneous with respect to the mixture and is suitable as a catalyst for preparing a monoolefinically unsaturated compound by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, by means of a semipermeable membrane to obtain a permeate and a retentate in such a way that the weight ratio of component b) to component c) in the mixture fed to the semipermeable membrane is smaller than in the retentate.

    8.
    发明专利
    未知

    公开(公告)号:DE10328713A1

    公开(公告)日:2005-01-20

    申请号:DE10328713

    申请日:2003-06-25

    Applicant: BASF AG

    Abstract: A process for separating a mixture comprising a) a monoolefinically unsaturated compound which is obtainable by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, or a saturated compound obtained by hydrogenating such a compound, b) a compound which is obtainable by adding more than two of the terminal olefins mentioned in a) or a compound obtained by hydrogenating such a compound, and c) a compound which contains a transition metal, is homogeneous with respect to the mixture and is suitable as a catalyst for preparing a monoolefinically unsaturated compound by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, by means of a semipermeable membrane to obtain a permeate and a retentate in such a way that the weight ratio of component b) to component c) in the mixture fed to the semipermeable membrane is smaller than in the retentate.

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