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公开(公告)号:WO2004054948A8
公开(公告)日:2005-06-23
申请号:PCT/EP0313634
申请日:2003-12-03
Applicant: BASF AG , FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
Inventor: FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
IPC: C07C29/17 , C07C29/149 , C07C31/20 , C07C67/347 , C07C69/593
CPC classification number: C07C29/177 , C07C31/20
Abstract: The invention relates to a method for producing 1,6-hexanediol having a purity of > 99.5 wt. % by catalytic dimerisation of acrylic acid esters, catalytic hydrogenation of the thus obtained hexene diacidic diester in order to form 1.6-hexanediol. Said method consists in: a) dimerising C1- C8-acrylic acid esters in the presence of at least one rhodium compound in order to form mixtures predominantly of 2- and 3-hexene diacdic diesters, b) hydrating the obtained dimerisation discharge in the presence of chrome-free catalysts containing mainly copper as a hydrogenation component and c) purifying the thus obtained raw 1.6-hexanediol by fractionating distillation.
Abstract translation: 本发明涉及一种用于制备具有> 99.5重量%的纯度的1,6-己二醇,由丙烯酸酯,以这种方式获得成1,6-己二醇的二酯己烯的催化氢化方法,其包括催化二聚化:一个 )C1至C8丙烯酸酯在二聚的至少一种铑化合物的存在下,得到主要为2-和3-己烯二酯的混合物,b)中氢化在无铬的存在下将所得二聚化流出物,含有作为氢化主要是铜催化剂,和c)将如此得到的粗1 1,6-己二醇通过分馏进行纯化。
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公开(公告)号:CA2529247A1
公开(公告)日:2004-12-29
申请号:CA2529247
申请日:2004-06-19
Applicant: BASF AG
Inventor: ROEPER MICHAEL , STUEER WOLFRAM , BASSLER PETER , SCHEIDEL JENS
IPC: C07C51/44 , C07C67/54 , C07C231/24 , C07C253/32
Abstract: The invention relates to a distillation method for isolating a compound comprising at least two functional groups, selected independently of one another from a group consisting of a nitrile group, carboxylic acid group, carboxylic acid ester group and a carboxamide group from a mixture containin g a compound comprising at least two functional groups, selected independently of one another from a group consisting of a nitrile group, carboxylic acid group, carboxylic acid ester group and a carboxamide group and a rhodium containing compound that is homogeneous in the mixture.
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公开(公告)号:DE10249928A1
公开(公告)日:2004-05-06
申请号:DE10249928
申请日:2002-10-26
Applicant: BASF AG
Inventor: PASTRE JOERG , EXNER KAI MICHAEL , STUEER WOLFRAM , GEISLER ELKE , MACHHAMMER OTTO
Abstract: Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).
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公开(公告)号:DE19800934A1
公开(公告)日:1999-07-15
申请号:DE19800934
申请日:1998-01-13
Applicant: BASF AG
Inventor: SCHWAB PETER DR , SCHULZ MICHAEL DR , WOLF JUSTIN DR , STUEER WOLFRAM , WERNER HELMUT PROF DR
Abstract: Ruthenium complexes are prepared by addition of alkyne compounds to ruthenium compounds in the presence of hydrogen, a reducing agent and optionally water. A process for the preparation of ruthenium complexes (I) of formula (1) comprises: (a) reaction of RuX3 with L and L in an inert solvent in the presence of a reducing agent and hydrogen and without isolation of intermediates followed by (b) addition of compounds of formula (2), optionally in the presence of water. RuX2(=CH-CH2R)L L (1) R - C ?= CH (2) where X = an anionic ligand R = H, 1-20C alkyl or 6-20C aryl, optionally substituted L , L = neutral electron donor ligands.
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公开(公告)号:AT334956T
公开(公告)日:2006-08-15
申请号:AT03799469
申请日:2003-12-03
Applicant: BASF AG
Inventor: FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
IPC: C07C29/17 , C07C29/149 , C07C31/20 , C07C67/347 , C07C69/593
Abstract: Production of 1,6-hexanediol of purity at least 99.5 % comprises: (1) catalytically dimerizing a 1-8C acrylic acid ester in presence of rhodium compounds to a mixture mainly of 2- and 3-hexenedioic acid diesters; (2) hydrogenating the ester mixture in chromium-free mainly copper-containing catalysts; and (3) purifying the resulting diol mixture by fractional distillation.
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公开(公告)号:BRPI0411786A
公开(公告)日:2006-08-08
申请号:BRPI0411786
申请日:2004-06-11
Applicant: BASF AG
Inventor: STUEER WOLFRAM , SCHEIDEL JENS , VOSS HARTWIG , BASSLER PETER , PER MICHAEL R
Abstract: A process for separating a mixture comprising a) a monoolefinically unsaturated compound which is obtainable by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, or a saturated compound obtained by hydrogenating such a compound, b) a compound which is obtainable by adding more than two of the terminal olefins mentioned in a) or a compound obtained by hydrogenating such a compound, and c) a compound which contains a transition metal, is homogeneous with respect to the mixture and is suitable as a catalyst for preparing a monoolefinically unsaturated compound by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, by means of a semipermeable membrane to obtain a permeate and a retentate in such a way that the weight ratio of component b) to component c) in the mixture fed to the semipermeable membrane is smaller than in the retentate.
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公开(公告)号:NO20051652A
公开(公告)日:2005-05-25
申请号:NO20051652
申请日:2005-04-04
Applicant: BASF AG
Inventor: MACHHAMMER OTTO , PASTRE JORG , STUEER WOLFRAM , EXNER KAI MICHAEL , GEISSLER ELKE
CPC classification number: C07C51/54 , C07C51/09 , C07C51/56 , Y02P20/582 , C07C53/02 , C07C57/04 , C07C53/124 , C07C53/122 , C07C63/313 , C07C53/12
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公开(公告)号:DE10328713A1
公开(公告)日:2005-01-20
申请号:DE10328713
申请日:2003-06-25
Applicant: BASF AG
Inventor: STUEER WOLFRAM , SCHEIDEL JENS , VOS HARTWIG , BASLER PETER , ROEPER MICHAEL
Abstract: A process for separating a mixture comprising a) a monoolefinically unsaturated compound which is obtainable by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, or a saturated compound obtained by hydrogenating such a compound, b) a compound which is obtainable by adding more than two of the terminal olefins mentioned in a) or a compound obtained by hydrogenating such a compound, and c) a compound which contains a transition metal, is homogeneous with respect to the mixture and is suitable as a catalyst for preparing a monoolefinically unsaturated compound by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, by means of a semipermeable membrane to obtain a permeate and a retentate in such a way that the weight ratio of component b) to component c) in the mixture fed to the semipermeable membrane is smaller than in the retentate.
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公开(公告)号:NO20040560L
公开(公告)日:2004-03-31
申请号:NO20040560
申请日:2004-02-06
Applicant: BASF AG
Inventor: ZEHNER PETER , PASTRE JORG , STUEER WOLFRAM
IPC: C07C27/02 , C07C27/00 , C07C45/41 , C07C45/46 , C07C45/89 , C07C49/90 , C07C51/083 , C07C51/09 , C07C51/56 , C07C53/02 , C07C53/08 , C07C67/00 , C07C67/08 , C07C67/10 , C07C67/297 , C07C69/14 , C07C69/15
Abstract: Joint production of formic acid with a \- 2C carboxylic acid (or derivative) involves transesterifying a formic ester (I) with a \- 2C carboxylic acid (II) to give formic acid (III) and the corresponding carboxylic acid ester (IV), and carbonylating part of (IV) to the corresponding carboxylic acid anhydride (V).
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公开(公告)号:NO328392B1
公开(公告)日:2010-02-08
申请号:NO20040560
申请日:2004-02-06
Applicant: BASF AG
Inventor: ZEHNER PETER , PASTRE JORG , STUEER WOLFRAM
IPC: C07C27/02 , C07C51/09 , C07C27/00 , C07C45/41 , C07C45/46 , C07C45/89 , C07C49/90 , C07C51/083 , C07C51/56 , C07C53/02 , C07C53/08 , C07C67/00 , C07C67/08 , C07C67/10 , C07C67/297 , C07C69/14 , C07C69/15
Abstract: Joint production of formic acid with a \- 2C carboxylic acid (or derivative) involves transesterifying a formic ester (I) with a \- 2C carboxylic acid (II) to give formic acid (III) and the corresponding carboxylic acid ester (IV), and carbonylating part of (IV) to the corresponding carboxylic acid anhydride (V).
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