RESORCINE DERIVATIVES AND THEIR USE AS PESTICIDES
    2.
    发明申请
    RESORCINE DERIVATIVES AND THEIR USE AS PESTICIDES 审中-公开
    RESORCINE衍生物及其作为杀虫剂的用途

    公开(公告)号:WO2007054558A2

    公开(公告)日:2007-05-18

    申请号:PCT/EP2006068329

    申请日:2006-11-10

    CPC classification number: C07D213/64 C07D277/34 C07D307/80

    Abstract: This invention relates to resorcine derivatives of formula (I) wherein R 1 is phenyl or a 5- to 6-membered heteroaromatic ring which may contain 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur, wherein phenyl or the heteroaromatic ring may be fused to a ring selected from phenyl and a 5- to 6-membered saturated, partially unsaturated or aromatic heterocyclic ring which may contain 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur, wherein phenyl or the 5- to 6-membered heteroaromatic ring or the respective fused ring systems may be unsubstituted or substituted by any combination of 1 to 6 optionally substituted groups R 3 , wherein R 3 is halogen, cyano, nitro, hydroxy, mercapto, amino, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, haloalkyl, haloalkenyl, haloalkynyl, halocycloalkyl, halocycloalkenyl, alkoxy, alkenyloxy, alkynyloxy, haloalkoxy, haloalkenyloxy, haloalkynyloxy, alkylthio, alkenylthio, alkynylthio, haloalkylthio, haloalkenylthio, haloalkynylthio, alkylamino, alkenylamino, alkynylamino, dialkylamino, dialkenylamino, dialkynylamino, alkyl-alkenylamino, alkyl-alkynylamino, alkenyl- alkynylamino, trialkylsilyl, or phenyl or a 5-to 7-membered saturated or partially unsaturated heterocyclic ring which may contain 1 to 3 heteroatoms selected from oxygen, sulfur and nitrogen or a 5- to 6-membered heteraromatic ring system which may contain 1 to 4 heteroatoms selected from oxygen, nitrogen and sulfur, which phenyl and which heteroaromatic ring may be bonded via an oxygen or a sulfur atom, or -C(=G)Ra, -C(=G)ORa, -C(=G)NRa2, -C(=G)[N=SRa2], -C(=NORa)Ra, -C(=NORa)NRa2, -C(=NNRa2)Ra , -OC(=G)-OC(=G)ORa, N=SRa2, -NRaC(=G)Ra, -N[C(=G)Ra]2, - NRaC(=G)ORa, -C(=G)NRa-NRa2, -C(=G)NRa-NRa [C(=G)Ra], -NRa-C(=G)NRa2, -NRa-NRaC(=G)Ra, -NRa-N[C(=G)Ra]2, -N[(C=G)Ra]-NRa2, -NRa-NRa[(C=G)GRa], -NRa[(C=G)NRa2, -NRa[C=NRa]Ra, -NRa(C=NRa)NRa2, -O-NRa2, -O-NRa(C=G)Ra, - SO2NRa2, -NRaSO2Ra, -S(=O)Ra, -S(=O)2Ra, -SO2ORa, or -OSO2Ra, wherein G is oxygen or sulfur and Ra is as defined in the description, R 2 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, alkoxy, or haloalkoxy, x is 2, 3, 4, 5, 6, or 7, or the diastereomers, enantiomers, salts or N-oxides thereof, with the proviso that R 1 is not 5-chloro-2,2,-dimethyl-2,3-dihydrobenzo[b]furan-7-yl when R 2 is hydrogen and x is 3 or 4, processes and intermediates for the preparation of compounds I, use of compounds I for combating insects, acarids, or nematodes, and a method for treating, controlling, preventing or protecting animals against infestation or infection by parasites using compounds I.

    Abstract translation: 本发明涉及其中R 1为苯基或可含有1-3个选自氧,氮和硫的杂原子的5至6元杂芳环的式(I)的间苯二酚衍生物,其中苯基 或杂芳环可以与选自苯基和5-至6-元饱和,部分不饱和或芳族杂环的环稠合,所述杂环可以含有1-3个选自氧,氮和硫的杂原子,其中苯基或5- 至6元杂芳环或相应的稠环体系可以是未取代的或被1至6个任选取代的基团R 3 3的任何组合取代,其中R 3是卤素, 氰基,硝基,羟基,巯基,氨基,烷基,烯基,炔基,环烷基,环烯基,卤代烷基,卤代烯基,卤代炔基,卤代环烷基,卤代环烯基,烷氧基,烯氧基,炔氧基,卤代烷氧基,卤代烯氧基,卤代炔氧基,烷硫基,烯硫基,炔硫基,卤代烷硫基, H 烯基氨基,炔基氨基,二烷基氨基,二链烷基氨基,二炔基氨基,烷基 - 链烯基氨基,烷基 - 炔基氨基,烯基 - 炔基氨基,三烷基甲硅烷基或苯基或5至7元饱和或部分不饱和的杂环, 至3个选自氧,硫和氮的杂原子或5至6元杂芳环体系,其可以含有1至4个选自氧,氮和硫的杂原子,该苯基和杂芳环可以通过氧或 硫原子或-C(= G)R a,-C(= G)OR a,-C(= G)NR a 2,-C(= G)[N = SR a 2] (= NORa)NRa2,-C(= NNRa2)Ra,-OC(= G)-OC(= G)ORa,N = SRa2,-NRaC(= G)Ra,-N [C(= G)Ra] 2,-NR a C(= G)OR a,-C(= G)NR a -NR a 2,-C(= G)NR a -NR a [C(= G)R a] -NRaC(= G)Ra,-NRa-N [C(= G)Ra] 2,-N [(C = G)Ra] -NRa2,-NRa-NRa [(C = G) [(C = G)NRa2,-NRa [C = NRa] Ra,-NRa(C = NRa)NRa2,-O-NRa2,-O-NRa(C = G)Ra,-SO2NRa2,-NRaSO2Ra,-S (= O)R a,-S(= O)2 R a,-SO 2 OR a或-O SO 2 R a,其中G是氧或硫,Ra如说明书中所定义,R 2是氢,卤素,氰基,烷基,卤代烷基,烯基,卤代烯基,炔基,卤代炔基,烷氧基或卤代烷氧基, x是2,3,4,5,6或7,或其非对映异构体,对映异构体,盐或N-氧化物,条件是R 1不是5-氯-2,2 ,当R 2是氢并且x是3或4时,制备化合物I的方法和中间体,使用化合物I,其中R 1,R 2,R 3, 用于防治昆虫,螨虫或线虫,以及用化合物I治疗,控制,预防或保护动物免受寄生虫侵袭或感染的方法。

    NOVEL 2-CYANO-3-(HALO)ALKOXY-BENZENESULFONAMIDE COMPOUNDS FOR COMBATING ANIMAL PESTS
    3.
    发明申请
    NOVEL 2-CYANO-3-(HALO)ALKOXY-BENZENESULFONAMIDE COMPOUNDS FOR COMBATING ANIMAL PESTS 审中-公开
    新型2-氰基-3-(卤代)烷氧基苯磺酰胺化合物用于防治动物病虫害

    公开(公告)号:WO2006056433A2

    公开(公告)日:2006-06-01

    申请号:PCT/EP2005012561

    申请日:2005-11-24

    CPC classification number: C07C319/20 A01N41/06 C07C311/29 C07C323/62

    Abstract: The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds (I), where the variables Alk and R1 to R5 are as defined in claim 1, and/or to their agriculturally useful salts. Moreover, the present invention relates to: the use of compounds (I) and/or their salts for combating animal pests; agricultural compositions comprising such an amount of at least one compound of the general formula (I) and/or at least one agriculturally useful salt of (I) and at least one inert liquid and/or solid agronomically acceptable carrier that it has a pesticidal action and, if desired, at least one surfactant; and a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the formula (I) and/or at least one agriculturally acceptable salt thereof; a method for the for the protection of seeds from soil insects and of the resulting plant's roots and shoots from soil and foliar insects comprising contacting the seeds before sowing and/or after pregermination with a 2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the general formula (I).

    Abstract translation: 本发明涉及2-氰基-3-(卤代)烷氧基 - 苯磺酰胺化合物(I),其中变量Alk和R1-R5如权利要求1中所定义,和/或其可农用盐。 此外,本发明涉及:化合物(I)和/或其盐用于对抗动物害虫的用途; 包含这种量的至少一种通式(I)的化合物和/或至少一种(I)的农业上有用的盐和至少一种惰性液体和/或固体农艺上可接受的载体的农业组合物,其具有杀虫作用 和如果需要的话,至少一种表面活性剂; 以及防治动物害虫的方法,其包括使动物害虫,其习性,繁殖场,食物供应,植物,种子,土壤,面积,动物害虫正在生长或可能生长的材料或环境,或材料,植物 (I)的至少一种2-氰基-3-(卤代)烷氧基 - 苯磺酰胺化合物和/或至少一种农业上受到保护的种子,土壤,表面或空间免于动物攻击或侵染 其可接受的盐; 一种用于保护种子免受土壤昆虫以及所得植物的根和茎由土壤和叶面昆虫引起的方法,包括在播种之前和/或在萌芽后使种子与2-氰基-3-(卤代)烷氧基 - 苯磺酰胺 通式(I)的化合物。

    3-HETEROARYL SUBSTITUTED 5-METHYLOXYMETHYL ISOXAZOLINES USED AS HERBICIDES
    4.
    发明申请
    3-HETEROARYL SUBSTITUTED 5-METHYLOXYMETHYL ISOXAZOLINES USED AS HERBICIDES 审中-公开
    3 - 杂芳基 - 取代的异恶唑啉5甲氧基甲基-AS除草剂

    公开(公告)号:WO03090539A8

    公开(公告)日:2004-12-16

    申请号:PCT/EP0304136

    申请日:2003-04-22

    Abstract: The invention relates to 3-heteroaryl substituted isoxazolines of formula (I), or to their salts that can be used for agricultural purposes. In said formula, the variables are defined as follows: X represents a substituted 5-membered heteroaryl comprising between one and four nitrogen atoms, or between one and three nitrogen atoms and one oxygen or sulphur atom, or one oxygen or sulphur atom, or represents a substituted 6-membered heteroaryl comprising between one and four nitrogen atoms, whereby the aforementioned 5-membered heteroaryl is not pyrazolyl or thienyl; R - R represent hydrogen, alkyl or haloalkyl; Y represents an optionally substituted aryl, or benzo[1,4]dioxonyl, benzo[1,3]dioxolanyl, 2,3-dihydrobenzofuranyl or benzimidazole, or an optionally substituted 5- to 6-membered heteroaryl. The invention also relates to methods and intermediate products for the production of said compounds, in addition to the use thereof or of agents containing the compounds for controlling undesired plants.

    Abstract translation: 本发明涉及式(I)的3- heteroarylsubstituerte异恶唑啉:其中各变量具有以下含义:X为取代的具有一至四个氮原子或具有一至三个氮原子和一个氧或硫原子,或具有5元杂芳基 一个氧或硫原子; 的或取代的具有一至四个氮原子的6元杂芳基; 其中,上述的5元杂芳基未被吡唑基或噻吩基; [R <1> - R的<7>是氢,烷基或卤代烷基; Y是任选取代的芳基,或苯并[1,4] dioxonyl,苯并[1,3]二氧戊环基,2,3-二氢苯并呋喃基或苯并咪唑; 或任选取代的5-至6-元杂芳基; 及其可农用盐,它们的制备方法和中间体; 和使用这些化合物或包含用于控制不希望的植物的装置这些化合物。

    METHOD FOR PRODUCING 1-SUBSTITUTED 5- OR 3-HYDROXYPYRAZOLES
    6.
    发明申请
    METHOD FOR PRODUCING 1-SUBSTITUTED 5- OR 3-HYDROXYPYRAZOLES 审中-公开
    制备1-取代的5-或3-羟基吡唑的方法

    公开(公告)号:WO0031042A3

    公开(公告)日:2000-10-26

    申请号:PCT/EP9908516

    申请日:1999-11-06

    CPC classification number: C07D231/20

    Abstract: The invention relates to a method for producing 1-substituted 5- and/or 3-hydroxypyrazoles of formulas (I) and (II), wherein R represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or a cyclic ring system with 3-14 ring atoms, by reacting a 3-alkoxyacrylic acid alkyl ester of formula (III), wherein R , R independently mean C1-C6-alkyl or C3-C6-cycloalky, with a hydrazine of formula (IV), wherein R has the above cited meaning, a) at a pH value of 6-11 to form 5-hydroxypyrazoles of formula (I), or b) at a pH value of 11-14 to form 3-hydroxypyrazoles of formula (II).

    Abstract translation: 本发明涉及一种制备1-取代的5和/或所述式(I)和(II),其中R <1> C1-C6-烷基,C2-C6链烯基,C2-C6的3-羟基吡 炔基,C3-C6环烷基或C1-C4烷氧基,其中这些基团被卤素,C1-C4烷氧基,苯氧基,C1-C6烷氧羰基,C1-C6烷硫基羰基或具有3-14个环原子的环系 可以由式(III)的烷基3- alkoxyacrylates被取代,其中R <2>,R <3>独立地是C1-C6烷基或C3-C6环烷基与式的肼(Ⅳ) 其中R <1>具有上面给出的含义,a)在pH值下式I)的6-11(约5-羟基吡唑反应而,或b)在pH为11-14,得到3- hydroxypyrazoles 的式(II)。

    AMIDRAZONE COMPOUNDS FOR COMBATING ANIMAL PESTS
    9.
    发明申请
    AMIDRAZONE COMPOUNDS FOR COMBATING ANIMAL PESTS 审中-公开
    用于组合动物疫苗的咪唑啉酮化合物

    公开(公告)号:WO2006097279A8

    公开(公告)日:2007-05-18

    申请号:PCT/EP2006002331

    申请日:2006-03-14

    CPC classification number: C07C259/20 A01N37/52 C07C2601/02

    Abstract: The present invention relates to new amidrazone compounds which are useful for combating animal pests, in particular insects, arachnids and nematodes. The invention also relates to a method for combating insects, nematodes and arachnids. The amidrazone compounds are of the general formula (I) including the tautomers of I and the salts thereof; wherein X and Y are hydrogen or together form a chemical bond; Ar is an aromatic radical selected from phenyl and a 5- or 6-membered heteroaryl having 1 , 2, 3 or 4 heteroatoms as ring members, which are selected, independently of one another, from O, N and S, and where the aromatic radical may have 1 , 2, 3, 4 or 5 substituents R a ; R 1 is selected from the group consisiting of C 1 -C 1O -alkyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, cyano-C 1 -C 4 -alkyl, hydroxy-C 1- C 4 -alkyl, C 1 -C 10 -haloalkyl, tri-(C 1 -C 4 -alkyl)-silyl-C 1 - C 4 -alkyl, C 2 -C 10 -alkenyl, C 2 -C 10 -haloalkenyl, C 2 -C 10 -alkynyl, C 2 -C 10 -haloalkynyl, C 3 -C 10 -cycloalkyl, phenyl, heteroaryl, C 3 -C 10 -cycloalkyl-C 1 C 4 -alkyl, phenyl-C 1 -C 4 - alkyl and heteroaryl-C 1 C 4 alkyl, wherein C 3 -C 10 -cycloalkyl, heteroaryl and phenyl in the last six mentioned radicals may be unsubstituted or carry 1 , 2, 3, 4 or 5 substituents R b as defined above; R 2 is selected from the group consisiting of C 1- C 1 0-alkyl, c 1- c 4 -alkoxy- C 1- C 4 -alkyl, C 1- C 10 -haloalkyl, C 2 -C 10 -alkenyl, C 2 -C 10 -haloalkenyl, C 2 -C 10 -alkynyl, C 2 -C 10 - haloalkynyl,c 3 -C 10 -cycloalkyl, phenyl, heteroaryl, C 3 -C 10 -cycloalkyl-C 1- C 4 -alkyl, phenyl-C 1 -C 4 -alkyl and heteroaryI-C 1- C 4 -alkyl, wherein C 3 -C 10 -cycloalkyl, heteroaryl and phenyl in the last six mentioned radicals may be unsubstituted or carry 1 , 2, 3, 4 or 5 substituents R b as defined above.

    Abstract translation: 本发明涉及可用于对抗动物害虫,特别是昆虫,蜘蛛和线虫的新的氨基腙化合物。 本发明还涉及一种防治昆虫,线虫和蜘蛛的方法。 氨基腙化合物具有通式(I),其包括I的互变异构体及其盐; 其中X和Y是氢或一起形成化学键; Ar是选自苯基和具有1,2,3或4个杂原子作为环成员的5-或6-元杂芳基的芳族基团,其彼此独立地选自O,N和S,并且其中芳族 基团可以具有1,2,3,4或5个取代基R a, R 1选自C 1 -C 10 - 烷基,C 1 -C 1 - 烷基, C 1 -C 4烷基,C 1 -C 4烷基,C 1 -C 4烷基,氰基-C 1 -C 4烷基, C 1 -C 6烷基,羟基-C 1 -C 4 - 亚烷基,C 1 -C 10 - 烷基, 卤代烷基,三 - (C 1 -C 4 - 烷基) - 甲硅烷基-C 1 -C 4 - 烷基,C 2 -C 10 - 烯基,C 2 -C 10 - 卤代烯基,C 1 -C 10 - C 2 -C 10 - 炔基,C 2 -C 10 - 卤代炔基,C 3 - C 10 - 环烷基,苯基,杂芳基,C 3 -C 10 - 环烷基-C 1 -C C 1-4烷基,苯基-C 1 -C 4 - 烷基和杂芳基-C 1 -C 4烷基, 其中C 3 -C 10 - 环烷基,杂芳基和苯基在后面六个提及的基团中可以是未取代的或携带1,2,3,4或4个 5个取代基R b如上所定义; R 2选自C 1 -C 1-4烷基,C 1 -C 4烷基, C 1-4烷基,C 1 -C 10烷基,C 1 -C 4烷基,C 1〜 亚烷基,C 2 -C 10 - 烯基,C 2 -C 10 - 卤代烯基,C C 2 -C 10 - 炔基,C 2 -C 10 - 卤代炔基,C 3 - C 1 -C 10 - 环烷基,苯基,杂芳基,C 3 -C 10 - 环烷基-C 1 - C 1 -C 4 - 烷基,苯基-C 1 -C 4 - 烷基和杂芳基C 1 -C 其中C 3 -C 10 - 环烷基,最后六个所述基团中的杂芳基和苯基可以是未取代的或携带1, 2,3,4或5个如上定义的取代基R b。

    1-(1,2-DIPHENYL-ETHYL)-3-(2-HYDROXYETHYL)-THIOUREA COMPOUNDS FOR COMBATING ANIMAL PESTS
    10.
    发明申请
    1-(1,2-DIPHENYL-ETHYL)-3-(2-HYDROXYETHYL)-THIOUREA COMPOUNDS FOR COMBATING ANIMAL PESTS 审中-公开
    1-(1,2-二苯基乙基)-3-(2-羟基乙基) - 硫脲化合物,用于组合动物饲料

    公开(公告)号:WO2006125745A3

    公开(公告)日:2007-05-10

    申请号:PCT/EP2006062413

    申请日:2006-05-18

    CPC classification number: C07C335/12 A01N47/28

    Abstract: The present invention relates to a method of combating animal pests which comprises contacting the animal pest, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal at- tack or infestation, with a pesticidally effective amount of at least one 1-(1 ,2-diphenyl- ethyl)-3-(2-hydroxyethyl)-thiourea compound I or an agriculturally acceptable salt thereof, wherein m is 0 to 5, n is 0 to 5, R 3 and R 4 are H or optionally substituted alkyl, haloalkyl, cycloalkyl, phenyl or benzyl, R 7 , R 8 , R 9 and R 10 are H or optionally substituted C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, C 1 -C 6 - alkylamino, C 1 -C 6 -alkoxy, C 3 -C 6 -cycloalkyl, phenyl or benzyl and the variables R 1 , R 2 , R 5 and R 6 are as defined in the claims. The invention relates also to a method for protecting crops from attack or infestation by animal pests, a method for protecting non-living materials from attack or infestation by animal pests, novel 1-(1 ,2-diphenyl-ethyl)-3-(2-hydroxyethyl)-thiourea compounds I and their agriculturally acceptable salts as well as to an agricultural composition comprising a 1-(1 ,2-diphenyl-ethyl)-3-(2-hydroxyethyl)-thiourea compound I or a salt thereof.

    Abstract translation: 本发明涉及一种防治动物害虫的方法,包括使动物害虫,其习惯,繁殖地,食物供应,植物,种子,土壤,区域,动物害虫生长或可能生长的物质或环境接触;或 防止动物死亡或侵染的材料,植物,种子,土壤,表面或空间,具有杀虫有效量的至少一种1-(1,2-二苯基 - 乙基)-3-(2-羟乙基 ) - 硫脲化合物I或其农业上可接受的盐,其中m为0至5,n为0至5,R 3和R 4为H或任选取代的烷基 ,卤代烷基,环烷基,苯基或苄基,R 7,R 8,R 9和R 10是H 或任选取代的C 1 -C 6 - 烷基,C 1 -C 6 - 卤代烷基,C 1,R 2,R 5和R 6如权利要求中所定义。 本发明还涉及一种保护作物免受动物害虫侵袭或侵袭的方法,一种保护非生物材料免受动物害虫侵袭或侵染的方法,新的1-(1,2-二苯基 - 乙基)-3-( 2-羟乙基) - 硫脲化合物I及其农业上可接受的盐,以及包含1-(1,2-二苯基 - 乙基)-3-(2-羟乙基) - 硫脲化合物I或其盐的农业组合物。

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