公开(公告)号：JPH10152543A

公开(公告)日：1998-06-09

申请号：JP23400797

申请日：1997-08-29

Applicant: BASF AG

Inventor： REICHELT MICHAEL ,  HEMSIEK RAINER

IPC: C08J9/12 ,  C07D233/56 ,  C08G18/28 ,  C08G18/48 ,  C08G18/65 ,  C08G101/00 ,  C08J9/14 ,  C08K5/09 ,  C08K5/3445 ,  C08L75/08

Abstract: PROBLEM TO BE SOLVED: To obtain a stably preservable frame-retardant-containing polyol compounding agent having satisfactory storage stability, providing a rigid urethane foam excellent in mechanical properties and thermal properties. SOLUTION: This frame-retardant-containing polyol compounding agent having storage stability comprises at least one polyol, optionally a relatively high-molecular weight compound containing at least two reactive hydrogen atoms, optionally a low-molecular weight chain extender and/or a cross-linking agent, a blowing agent, a catalyst, a stabilizer and optionally an auxiliary agent and/or an additive. In this case, the stabilizer used is an imidazole shown by the formula (R1 is an alkyl group, a hydroxyalkyl, etc.; R2 , R3 and R4 are each H, an alkyl group and/or formic acid). The compounding agent is reacted with an organic and/or a modified organic polyisocyanate to produce a rigid urethane foam derived from an isocyanate.

公开(公告)号：JPH11158244A

公开(公告)日：1999-06-15

申请号：JP27013998

申请日：1998-09-24

Applicant: BASF AG

Inventor： HEINZ MARION ,  WIEGMANN WERNER ,  ROTERMUND UDO ,  BIEDERMANN ANJA ,  REICHELT MICHAEL

IPC: C08J9/02 ,  C08G18/28 ,  C08G18/48 ,  C08G18/66 ,  C08G101/00 ,  C08J9/14

Abstract: PROBLEM TO BE SOLVED: To obtain an isocyanate-based rigid foam having an open-cell type micro pore by making an polyisocyanate react with a compound having a plural ity of active hydrogen atoms capable of reacting with the isocyanate in the presence of a water foaming agent, a catalyst, an auxiliary and an additive. SOLUTION: A polyisocyante is made to react with a compound containing a plurality of hydrogen atoms capable of reacting with an isocyante such as a hydroxyl group-containing ester represented by the formula having a functionally of 2-8 and a molecular weight of 300-8,000 in the presence of water and, if necessary, an organic compound acting as a physical foaming agent, a catalyst, an auxiliary and an additive to produce an open-cell type rigid foam represented by the formula (wherein (m) is 1-15; (n), (p), (r) and (t) are each 0-1; (o), (q), (s) and (v) are each 0-15; (u) is 0-10; X is 1-5; Y is 1-4; Z is 0-3; Zi is 0.1-3; R1 and R3 have each an aliphtic structure not containing a polyalcoholic hydroxyl group; and R2 is a group not containing COOH group of a polycarboxylic acid.

公开(公告)号：WO9961501A8

公开(公告)日：2000-01-27

申请号：PCT/EP9903195

申请日：1999-05-10

Applicant: BASF AG ,  REICHELT MICHAEL ,  ROTERMUND UDO ,  HEMPEL RENATE ,  FALKE PETER ,  VON MALOTKI PETER ,  SEIFERT HOLGER

Inventor： REICHELT MICHAEL ,  ROTERMUND UDO ,  HEMPEL RENATE ,  FALKE PETER ,  VON MALOTKI PETER ,  SEIFERT HOLGER

IPC: C08G18/10 ,  C08G18/50 ,  C08G18/76 ,  C09K3/10 ,  C08G18/48

CPC classification number: C09K3/1021 ,  C08G18/10 ,  C08G18/5006 ,  C08G18/7664 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/0083 ,  C08G18/6674

Abstract: The invention relates to prepolymers which contain isocyanate groups and which can be produced by reacting an isocyanate mixture, said mixture being predominantly comprised of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates, with a maximum proportion of two-core isomers of 74 wt.% with at least 4 functional polyols or with a mixture of polyols having an average functionality of at least 4. The polyols or polyol mixture comprise(s) a hydroxyl value ranging from 200 to 1650 mg KOH/g and an average molar mass of less than 1100 g/mol with an NCO content of at least 30.0 wt.%. In addition, the invention relates to a method for producing these prepolymers which contain isocyanate groups, to their use for producing polyurethanes, and to a method for producing polyurethanes by reacting at least one of the inventive prepolymers which contain isocyanate groups, optionally mixed with additional organic and/or modified organic isocyanates (a), with compounds having at least two reactive hydrogen atoms (b) in the presence of optional expanding agents (c), catalysts (d), optional additional auxiliary agents and/or additives (e).

Abstract translation: 本发明涉及含有可获得异氰酸酯基通过由二苯基甲烷二异氰酸酯和多苯基多亚甲基多异氰酸酯的主要的异氰酸酯混合物反应的预聚物，具有至少4官能的多元醇的不大于74重量％或具有至少4的平均官能度的多元醇的混合物两环异构体的比例 方法，其中所述多元醇或多元混合物具有的羟基数为200至1650毫克KOH /克和低于1100克/ mol的数均分子量，具有至少30.0重量％的NCO含量。 本发明的目的也可用于，任选地与另外的有机和/或改性的有机异氰酸酯的混合物制备含异氰酸酯基团，它们用于制备聚氨酯这些预聚物和含有异氰酸酯基的至少一种本发明的预聚物反应制备的聚氨酯的处理的方法（a）中 与具有化合物中的至少两个反应性氢原子（b）中，如果需要的话的情况下，发泡剂（C），催化剂（D），以及任选的其它助剂和/或添加剂（E）。

公开(公告)号：DE50108030D1

公开(公告)日：2005-12-15

申请号：DE50108030

申请日：2001-09-19

Applicant: BASF AG

Inventor： REICHELT MICHAEL ,  ROTERMUND UDO ,  BOEHME PETER

IPC: C07B63/00 ,  C08G18/38

公开(公告)号：DE59901540D1

公开(公告)日：2002-07-04

申请号：DE59901540

申请日：1999-12-15

Applicant: BASF AG

Inventor： HEINZ MARION ,  BIEDERMANN DR ,  ROTERMUND DR ,  REICHELT MICHAEL ,  WIEGMANN WERNER

IPC: B29C44/00 ,  E04B1/80 ,  F16L59/065 ,  F25D23/06

公开(公告)号：CA2354240A1

公开(公告)日：2002-01-28

申请号：CA2354240

申请日：2001-07-27

Applicant: BASF AG

Inventor： HOPPNER GERD ,  KNORR GOTTFRIED ,  REICHELT MICHAEL ,  DINSCH STEFAN ,  WINKLER JURGEN ,  MALOTKI PETER VON

IPC: C08G65/26 ,  C08G18/48

Abstract: Polyetherols based on solid initiator substances and liquid, hydroxyl-containing coinitiators are prepared by a catalyzed addition reaction of alkylene oxides by a process in which the initiator combination contains ethoxy structures, the ratio of the average number of hydroxyl groups per mole of initiator combination to the number of ethoxy structures in the polyetherol being from 1:0.2 to 1:1.8 and the ratio of the amounts by weight of the ethoxy structures to the average molecular weight of_the polyetherol being from 1:2 to 1:15. The polyetherols prepared by this process are used for the preparation of PUR, in particular rigid PUR foams.

公开(公告)号：GR3032290T3

公开(公告)日：2000-04-27

申请号：GR990403281

申请日：1999-12-30

Applicant: BASF AG

Inventor： VON MALOTKI PETER DR ,  HENSIEK RAINER ,  REICHELT MICHAEL

IPC: C08G18/28

Abstract: A fireproofed isocyanate-based rigid foam (I) is obtd. by reacting (a) polyisocyanates and/or modified polyisocyanates with (b) cpd(s). contg. isocyanate-reactive H atoms and opt. (c) low molecular wt. chain extenders and/or crosslinkers, in presence of (d) blowing agents, (e) catalysts, (f) bromine-contg. fire retardant(s) and opt. (g) other additives, etc.. Fire retardant (f) is tribromo-neopentyl alcohol (TBNPA), and the crosslinking index of all the cpds. with NCO-reactive H atoms (including (f)) is at least 3.0. Also claimed is prodn. of the foam as above.

公开(公告)号：DE59604020D1

公开(公告)日：2000-02-03

申请号：DE59604020

申请日：1996-07-23

Applicant: BASF AG

Inventor： VON MALOTKI PETER ,  HENSIEK RAINER ,  REICHELT MICHAEL

IPC: C08G18/28

Abstract: A fireproofed isocyanate-based rigid foam (I) is obtd. by reacting (a) polyisocyanates and/or modified polyisocyanates with (b) cpd(s). contg. isocyanate-reactive H atoms and opt. (c) low molecular wt. chain extenders and/or crosslinkers, in presence of (d) blowing agents, (e) catalysts, (f) bromine-contg. fire retardant(s) and opt. (g) other additives, etc.. Fire retardant (f) is tribromo-neopentyl alcohol (TBNPA), and the crosslinking index of all the cpds. with NCO-reactive H atoms (including (f)) is at least 3.0. Also claimed is prodn. of the foam as above.

公开(公告)号：CA2245009A1

公开(公告)日：1999-03-24

申请号：CA2245009

申请日：1998-09-23

Applicant: BASF AG

Inventor： WIEGMANN WERNER ,  ROTERMUND UDO ,  REICHELT MICHAEL ,  BIEDERMANN ANJA ,  HEINZ MARION

IPC: C08J9/02 ,  C08G18/28 ,  C08G18/48 ,  C08G18/66 ,  C08G101/00 ,  C08J9/14 ,  C08G18/68

Abstract: In a process for producing open-celled rigid foams by reacting a) polyisocyanates with b) compounds containing hydrogen atoms which are reactive toward isocyanates, in the presence of c) water, d) if desired, organic compounds acting as physical blowing agents, e) catalysts, auxiliaries and/or additives, the compounds containing reactive hydrogen atoms used are substances having the structure I: where m is 0 - 15 n is 0 - 1 o is 0 - 15 p is 0 - 1 q is 0 - 15 r is 0 - 1 s is 0 - 15 t is 0 - 1 u is 0 - 10 v is 0 - 15 x is 1 - 5 y is 1 - 4 or mixtures of 1 - 3 where r + n ~ 0 z is 0 - 3 z i is 0.1 -3 R1 is an aliphatic structure without OH groups based on the structure of polyhydric alcohols, preferably ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol and dipropylene glycol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, 1,3-butanediol, trimethylolpropane, trimethylolethane, glycerol, pentaerythritol, where these substances can also be used in the esterification as any mixture among one another and R1 can therefore also be a mixture of the corresponding structures, R2 is the radical of a polycarboxylic acid without COOH groups, eg. adipic acid, terephthalic acid, o-phthalic acid, R3 is an alcohol radical like R1.

公开(公告)号：MX9603147A

公开(公告)日：1997-09-30

申请号：MX9603147

申请日：1996-08-01

Applicant: BASF AG

Inventor： MALOTKI PETER VON ,  HENSIEK RAINER ,  REICHELT MICHAEL

IPC: C08G18/28 ,  C08G18/00

Abstract: Se producen espumas rígidas ignifugas basadas en isocianato mediante la reaccion de a) poliisocianatos orgánicos y/u orgánicos modificados con b) cuando menos un compuesto que contiene átomos de hidrogeno que reaccionan con isocianatos y, si se desea c) extendedores de cadena de bajo peso molecular y/o agentes de reticulacion en presencia de d) agentes de expulsion, e) catalizadores f) cuando menos un pirorretardante que contiene bromo y, si se desea, g) auxiliares y/o aditivos adicionales, donde se emplea en forma predominante alcohol tribromoneopentílico como pirorretardante que contiene bromo y el índice de reticulacion de todos los compuestos que contienen átomos de hidrogeno que reaccionan con isocianatos, incluyendo el pirorretardante que contiene bromo, es de cuando menos 3.0. Las espumas rígidas basadas en isocianato y producidas de conformidad con este procedimiento pueden emplearse como materiales de aislamiento.