公开(公告)号：FI922990A

公开(公告)日：1992-12-29

申请号：FI922990

申请日：1992-06-26

Applicant: BASF AG

Inventor： MUELLER HAN-JOACHIM ,  KONRAD RAINER ,  SCHWEIER GUENTHER ,  WEBER SIEGFRIED ,  SAIVE ROLAND ,  KOELLE PETER

IPC: C08F4/02 ,  C08F4/24 ,  C08F4/60 ,  C08F4/69 ,  C08F10/00 ,  C08F10/02

Abstract: A novel Phillips catalyst for the homopolymerisation of ethylene and the copolymerisation of ethylene with alpha -olefins contains, as catalytically active components, a specific aluminium phosphate-supported chromium catalyst and cocatalysts of the general formulae I to IV MR M R2 M R 3-nXn MM RR@ (I) (II) (III) (IV> in which the index and variables have the following meanings: M is lithium, sodium or potassium, M is magnesium or zinc, M is boron or aluminium, R is C1- to C10-alkyl or C6- to C20-aryl, R is R or C1- to C10-alkoxy or C6- to C20-aryloxy, X is chlorine, bromine or iodine, N is 0, 1 or 2. The aluminium phosphate-supported chromium catalyst is obtainable by applying chromium compounds to a finely divided aluminium phosphate having a P:Al molar ratio of close or equal to 1 and a pore volume of > 1 cm /g, and activating the resulting intermediate at elevated temperatures in an oxidising atmosphere. The novel Phillips catalyst has an extremely long mean service life, and its productivity can be further increased by adding hydrogen.

公开(公告)号：ES2133195T3

公开(公告)日：1999-09-01

申请号：ES96925665

申请日：1996-07-05

Applicant: BASF AG

Inventor： NEUMANN PETRA ,  WEBER SIEGFRIED ,  LILGE DIETER ,  GORTZ HANS-HELMUT

IPC: C08L23/04 ,  C08J5/18 ,  C08L23/06 ,  C08L23/08 ,  D01F6/04

Abstract: PCT No. PCT/EP96/02958 Sec. 371 Date Dec. 11, 1997 Sec. 102(e) Date Dec. 11, 1997 PCT Filed Jul. 5, 1996 PCT Pub. No. WO97/04025 PCT Pub. Date Feb. 6, 1997Molding compositions are based on polymers of ethylene made from (A) from 40 to 65% by weight of an ethylene polymer having a density in the range from 0.948 to 0.964 g/cm3, a melt flow index (MFI) of from 6 to 20 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 2 to 5, (B) from 35 to 60% by weight of an ethylene polymer having a density in the range from 0.935 to 0.953 g/cm3, a melt flow index (MFI) of from 0.1 to 0.35 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 6 to 20, and (C) from 0 to 6% by weight of the usual additives for thermoplastics, where the density of the molding compositions is in the range from 0.948 to 0.957 g/cm3, the melt flow index is in the range from 1.0 to 2.0 g/10 min, the mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n is in the range from 3 to 10 and the difference of the densities of components A and B ( DELTA D=D(A)-D(B)) is in the range from 0 to 0.029 g/cm3.

公开(公告)号：DE59602011D1

公开(公告)日：1999-07-01

申请号：DE59602011

申请日：1996-07-05

Applicant: BASF AG

Inventor： NEUMANN PETRA ,  WEBER SIEGFRIED ,  LILGE DIETER ,  GOERTZ HANS-HELMUT

IPC: C08L23/04 ,  C08J5/18 ,  C08L23/06 ,  C08L23/08 ,  D01F6/04

Abstract: PCT No. PCT/EP96/02958 Sec. 371 Date Dec. 11, 1997 Sec. 102(e) Date Dec. 11, 1997 PCT Filed Jul. 5, 1996 PCT Pub. No. WO97/04025 PCT Pub. Date Feb. 6, 1997Molding compositions are based on polymers of ethylene made from (A) from 40 to 65% by weight of an ethylene polymer having a density in the range from 0.948 to 0.964 g/cm3, a melt flow index (MFI) of from 6 to 20 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 2 to 5, (B) from 35 to 60% by weight of an ethylene polymer having a density in the range from 0.935 to 0.953 g/cm3, a melt flow index (MFI) of from 0.1 to 0.35 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 6 to 20, and (C) from 0 to 6% by weight of the usual additives for thermoplastics, where the density of the molding compositions is in the range from 0.948 to 0.957 g/cm3, the melt flow index is in the range from 1.0 to 2.0 g/10 min, the mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n is in the range from 3 to 10 and the difference of the densities of components A and B ( DELTA D=D(A)-D(B)) is in the range from 0 to 0.029 g/cm3.

公开(公告)号：AT180504T

公开(公告)日：1999-06-15

申请号：AT96925665

申请日：1996-07-05

Applicant: BASF AG

Inventor： NEUMANN PETRA ,  WEBER SIEGFRIED ,  LILGE DIETER ,  GOERTZ HANS-HELMUT

IPC: C08J5/18 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  D01F6/04

Abstract: PCT No. PCT/EP96/02958 Sec. 371 Date Dec. 11, 1997 Sec. 102(e) Date Dec. 11, 1997 PCT Filed Jul. 5, 1996 PCT Pub. No. WO97/04025 PCT Pub. Date Feb. 6, 1997Molding compositions are based on polymers of ethylene made from (A) from 40 to 65% by weight of an ethylene polymer having a density in the range from 0.948 to 0.964 g/cm3, a melt flow index (MFI) of from 6 to 20 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 2 to 5, (B) from 35 to 60% by weight of an ethylene polymer having a density in the range from 0.935 to 0.953 g/cm3, a melt flow index (MFI) of from 0.1 to 0.35 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 6 to 20, and (C) from 0 to 6% by weight of the usual additives for thermoplastics, where the density of the molding compositions is in the range from 0.948 to 0.957 g/cm3, the melt flow index is in the range from 1.0 to 2.0 g/10 min, the mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n is in the range from 3 to 10 and the difference of the densities of components A and B ( DELTA D=D(A)-D(B)) is in the range from 0 to 0.029 g/cm3.

公开(公告)号：FI922990A0

公开(公告)日：1992-06-26

申请号：FI922990

申请日：1992-06-26

Applicant: BASF AG

Inventor： MUELLER HANS-JOACHIM ,  KONRAD RAINER ,  SCHWEIER GUENTHER ,  WEBER SIEGFRIED ,  SAIVE ROLAND ,  KOELLE PETER

IPC: C08F4/02 ,  C08F4/24 ,  C08F4/60 ,  C08F4/69 ,  C08F10/00 ,  C08F10/02 ,  C08F

Abstract: A novel Phillips catalyst for the homopolymerisation of ethylene and the copolymerisation of ethylene with alpha -olefins contains, as catalytically active components, a specific aluminium phosphate-supported chromium catalyst and cocatalysts of the general formulae I to IV MR M R2 M R 3-nXn MM RR@ (I) (II) (III) (IV> in which the index and variables have the following meanings: M is lithium, sodium or potassium, M is magnesium or zinc, M is boron or aluminium, R is C1- to C10-alkyl or C6- to C20-aryl, R is R or C1- to C10-alkoxy or C6- to C20-aryloxy, X is chlorine, bromine or iodine, N is 0, 1 or 2. The aluminium phosphate-supported chromium catalyst is obtainable by applying chromium compounds to a finely divided aluminium phosphate having a P:Al molar ratio of close or equal to 1 and a pore volume of > 1 cm /g, and activating the resulting intermediate at elevated temperatures in an oxidising atmosphere. The novel Phillips catalyst has an extremely long mean service life, and its productivity can be further increased by adding hydrogen.