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公开(公告)号:FI114712B
公开(公告)日:2004-12-15
申请号:FI962620
申请日:1996-06-25
Applicant: BASF AG
Inventor: LUX MARTIN , SAIVE ROLAND , LANGHAUSER FRANZ , MICKLITZ WOLFGANG , GOERTZ HANS-HELMUT , LILGE DIETER
IPC: C08F2/06 , C08F2/14 , C08F4/606 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/626 , C08F2/18
Abstract: PCT No. PCT/EP94/04125 Sec. 371 Date Jun. 26, 1996 Sec. 102(e) Date Jun. 26, 1996 PCT Filed Dec. 13, 1994 PCT Pub. No. WO95/18160 PCT Pub. Date Jul. 6, 1995Homopolymers of ethylene or copolymers of ethylene with other olefins or mixtures thereof are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are those which contain, as active components, A) a finely divided carrier treated with trialkylaluminum, B) a metallocene complex, C) an open-chain or cyclic alumoxane compound and D) an alkali metal alkyl or alkaline earth metal alkyl or a mixture thereof.
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公开(公告)号:DE19935407A1
公开(公告)日:2001-02-01
申请号:DE19935407
申请日:1999-07-30
Applicant: BASF AG
Inventor: MIHAN SHARAM , LILGE DIETER , SCHWEIER GUENTHER , KOEHN RANDOLF , SEIFERT GUIDO
IPC: C08F4/42 , C08F4/69 , C08F10/00 , C08F110/02 , C08F4/78
Abstract: Polymerization of olefins in presence of a catalyst that comprises: (i) at least one complex (A) of a transition metal and a tridentate macrocyclic ligand (L) that has at least one substituent with donor function; and (ii) optionally one or more activator compounds (B). Independent claims are also included for the following: (a) catalyst system comprising (A) and (B); and (b) olefin polymers produced by this method.
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公开(公告)号:ES2133195T3
公开(公告)日:1999-09-01
申请号:ES96925665
申请日:1996-07-05
Applicant: BASF AG
Inventor: NEUMANN PETRA , WEBER SIEGFRIED , LILGE DIETER , GORTZ HANS-HELMUT
Abstract: PCT No. PCT/EP96/02958 Sec. 371 Date Dec. 11, 1997 Sec. 102(e) Date Dec. 11, 1997 PCT Filed Jul. 5, 1996 PCT Pub. No. WO97/04025 PCT Pub. Date Feb. 6, 1997Molding compositions are based on polymers of ethylene made from (A) from 40 to 65% by weight of an ethylene polymer having a density in the range from 0.948 to 0.964 g/cm3, a melt flow index (MFI) of from 6 to 20 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 2 to 5, (B) from 35 to 60% by weight of an ethylene polymer having a density in the range from 0.935 to 0.953 g/cm3, a melt flow index (MFI) of from 0.1 to 0.35 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 6 to 20, and (C) from 0 to 6% by weight of the usual additives for thermoplastics, where the density of the molding compositions is in the range from 0.948 to 0.957 g/cm3, the melt flow index is in the range from 1.0 to 2.0 g/10 min, the mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n is in the range from 3 to 10 and the difference of the densities of components A and B ( DELTA D=D(A)-D(B)) is in the range from 0 to 0.029 g/cm3.
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公开(公告)号:DE59602011D1
公开(公告)日:1999-07-01
申请号:DE59602011
申请日:1996-07-05
Applicant: BASF AG
Inventor: NEUMANN PETRA , WEBER SIEGFRIED , LILGE DIETER , GOERTZ HANS-HELMUT
Abstract: PCT No. PCT/EP96/02958 Sec. 371 Date Dec. 11, 1997 Sec. 102(e) Date Dec. 11, 1997 PCT Filed Jul. 5, 1996 PCT Pub. No. WO97/04025 PCT Pub. Date Feb. 6, 1997Molding compositions are based on polymers of ethylene made from (A) from 40 to 65% by weight of an ethylene polymer having a density in the range from 0.948 to 0.964 g/cm3, a melt flow index (MFI) of from 6 to 20 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 2 to 5, (B) from 35 to 60% by weight of an ethylene polymer having a density in the range from 0.935 to 0.953 g/cm3, a melt flow index (MFI) of from 0.1 to 0.35 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 6 to 20, and (C) from 0 to 6% by weight of the usual additives for thermoplastics, where the density of the molding compositions is in the range from 0.948 to 0.957 g/cm3, the melt flow index is in the range from 1.0 to 2.0 g/10 min, the mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n is in the range from 3 to 10 and the difference of the densities of components A and B ( DELTA D=D(A)-D(B)) is in the range from 0 to 0.029 g/cm3.
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公开(公告)号:AT180504T
公开(公告)日:1999-06-15
申请号:AT96925665
申请日:1996-07-05
Applicant: BASF AG
Inventor: NEUMANN PETRA , WEBER SIEGFRIED , LILGE DIETER , GOERTZ HANS-HELMUT
Abstract: PCT No. PCT/EP96/02958 Sec. 371 Date Dec. 11, 1997 Sec. 102(e) Date Dec. 11, 1997 PCT Filed Jul. 5, 1996 PCT Pub. No. WO97/04025 PCT Pub. Date Feb. 6, 1997Molding compositions are based on polymers of ethylene made from (A) from 40 to 65% by weight of an ethylene polymer having a density in the range from 0.948 to 0.964 g/cm3, a melt flow index (MFI) of from 6 to 20 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 2 to 5, (B) from 35 to 60% by weight of an ethylene polymer having a density in the range from 0.935 to 0.953 g/cm3, a melt flow index (MFI) of from 0.1 to 0.35 g/10 min and a mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n in the range from 6 to 20, and (C) from 0 to 6% by weight of the usual additives for thermoplastics, where the density of the molding compositions is in the range from 0.948 to 0.957 g/cm3, the melt flow index is in the range from 1.0 to 2.0 g/10 min, the mean molar mass distribution +E,ovs M+EE w/+E,ovs M+EE n is in the range from 3 to 10 and the difference of the densities of components A and B ( DELTA D=D(A)-D(B)) is in the range from 0 to 0.029 g/cm3.
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公开(公告)号:ES2108563T3
公开(公告)日:1997-12-16
申请号:ES95904458
申请日:1994-12-13
Applicant: BASF AG
Inventor: LUX MARTIN , SAIVE ROLAND , LANGHAUSER FRANZ , MICKLITZ WOLFGANG , GORTZ HANS-HELMUT , LILGE DIETER
IPC: C08F2/06 , C08F2/14 , C08F4/606 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
Abstract: PCT No. PCT/EP94/04125 Sec. 371 Date Jun. 26, 1996 Sec. 102(e) Date Jun. 26, 1996 PCT Filed Dec. 13, 1994 PCT Pub. No. WO95/18160 PCT Pub. Date Jul. 6, 1995Homopolymers of ethylene or copolymers of ethylene with other olefins or mixtures thereof are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are those which contain, as active components, A) a finely divided carrier treated with trialkylaluminum, B) a metallocene complex, C) an open-chain or cyclic alumoxane compound and D) an alkali metal alkyl or alkaline earth metal alkyl or a mixture thereof.
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公开(公告)号:NO962696L
公开(公告)日:1996-06-26
申请号:NO962696
申请日:1996-06-26
Applicant: BASF AG
Inventor: LUX MARTIN , SAIVE ROLAND , LANGHAUSER FRANZ , MICKLITZ WOLFGANG , GORTZ HANS-HELMUT , LILGE DIETER
IPC: C08F2/06 , C08F2/14 , C08F4/606 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
Abstract: PCT No. PCT/EP94/04125 Sec. 371 Date Jun. 26, 1996 Sec. 102(e) Date Jun. 26, 1996 PCT Filed Dec. 13, 1994 PCT Pub. No. WO95/18160 PCT Pub. Date Jul. 6, 1995Homopolymers of ethylene or copolymers of ethylene with other olefins or mixtures thereof are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are those which contain, as active components, A) a finely divided carrier treated with trialkylaluminum, B) a metallocene complex, C) an open-chain or cyclic alumoxane compound and D) an alkali metal alkyl or alkaline earth metal alkyl or a mixture thereof.
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公开(公告)号:FI962620A
公开(公告)日:1996-06-25
申请号:FI962620
申请日:1996-06-25
Applicant: BASF AG
Inventor: LUX MARTIN , SAIVE ROLAND , LANGHAUSER FRANZ , MICKLITZ WOLFGANG , GOERTZ HANS-HELMUT , LILGE DIETER
IPC: C08F2/06 , C08F2/14 , C08F4/606 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F
Abstract: PCT No. PCT/EP94/04125 Sec. 371 Date Jun. 26, 1996 Sec. 102(e) Date Jun. 26, 1996 PCT Filed Dec. 13, 1994 PCT Pub. No. WO95/18160 PCT Pub. Date Jul. 6, 1995Homopolymers of ethylene or copolymers of ethylene with other olefins or mixtures thereof are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are those which contain, as active components, A) a finely divided carrier treated with trialkylaluminum, B) a metallocene complex, C) an open-chain or cyclic alumoxane compound and D) an alkali metal alkyl or alkaline earth metal alkyl or a mixture thereof.
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公开(公告)号:DE10206988A1
公开(公告)日:2003-08-21
申请号:DE10206988
申请日:2002-02-19
Applicant: BASF AG
Inventor: KRISTEN MARC OLIVER , EIBECK PETER , GREGORIUS HEIKE , LILGE DIETER
IPC: C08F4/642 , B01J19/00 , C08F2/00 , C08F2/01 , C08F4/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/06 , C08F110/06 , C40B40/14
Abstract: A process for determining the quality of polymerization catalysts includes: (a) catalyst preparation; (b) polymerization of a monomer with the catalysts; (c) isolation of the polymers obtained under (b); and (d) characterization of the polymers. The process is carried out automatically in an arrangement of n vessels, steps (a) to (d) are all parallel steps, all sequential steps, or some in parallel and the rest in sequence and n at least 2. An Independent claim is included for an automated device for determining catalyst quality comprising: (A) a synthesis module and (B) an analysis module for determination of soluble and insoluble polymer fractions, where A and/or B contain at least 4 vessels and cumulative volume of the A and B vessels does not exceed 100000 ml.
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公开(公告)号:ES2154417T3
公开(公告)日:2001-04-01
申请号:ES96927701
申请日:1996-08-07
Applicant: BASF AG
Inventor: ROHDE WOLFGANG , SAIVE ROLAND , LILGE DIETER , LUX MARTIN , BAUER PETER
IPC: C08J5/18 , C08F4/02 , C08F4/24 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/646 , C08F4/69 , C08F4/78 , C08F10/00 , C08F10/02 , C08F210/16
Abstract: Polymers of ethylene are obtainable by polymerization of ethylene and, if desired, further comonomers in the presence of a catalyst system comprising as active constituentsI) a Phillips catalyst,II) a solid which is different from I) and comprises a component which is derived from the metallocene complexes of the formula (A) in which the substituents and indices have the following meanings: R1 to R10 are hydrogen, C1-C10-alkyl, 5-to 7-membered cycloalkyl which may in turn bear C1-C6-alkyl groups as substituents, C6-C15-aryl or aryalkyl, where two adjacent radicals may also together form a cyclic group having from 4 to 15 carbon atoms, or Si(R11)3, where R11 is C1-C10-alkyl, C6-C15-aryl or C3-C10-cycloalkyl, or the radicals R4 and R9 together form a group -[Y(R12R13)]m-, where Y is silicon, germanium, tin or carbon, and R12, R13 are hydrogen C1-C10-alky, C3-C10-cycloalyl or C6-C15-aryl,M is a metal of transition groups IV to VIII or a metal of the lanthanide series,Z1, Z2 are fluorine, chlorine, bromine, iodine, hydrogen, C1-C20-alkyl or aryl, -OR14, -OOCR14, where R14 is hydrogen or C1-C20-alkyl; R15 is C1-C20-alkyl; m is 1,2,3 or 4; n is 0, or 2; r is 0, 1 or 2; the sum n+r is likewise 0, 1 or 2, and, if desired,III) an organometallic component selected from groups IA, IIA, IIB and IIIA of the Periodic Table of the Elements.
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