公开(公告)号：DE50301146D1

公开(公告)日：2005-10-13

申请号：DE50301146

申请日：2003-01-30

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  VAN LAAR FREDERIK ,  VOSS HARTWIG ,  OEHLENSCHLAEGER STEFFEN ,  MACKENROTH WOLFGANG ,  MORGENSCHWEIS KONRAD ,  PENZEL ULRICH ,  WEIDNER BERND

IPC: C07C29/36 ,  C07C209/36 ,  C07C209/86

Abstract: The invention provides a process for preparing amines by catalytic hydrogenation of nitroaromatics and subsequent removal of the catalysts from the reaction mixture, which contains at least one aromatic amine and water, which comprises carrying out the removal of the catalysts by means of membrane filtration, which is carried out at a pressure on the suspension side of from 5 to 50 bar, a pressure difference between the suspension side and the permeate side of at least 0.3 bar and a flux rate on the suspension side of from 1 to 6 m/s.

公开(公告)号：HU229646B1

公开(公告)日：2014-03-28

申请号：HU0400780

申请日：2002-05-16

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  MUELLER JOERN ,  PENZEL ULRICH ,  GEORGI GUNTER ,  WEIDNER BERND ,  TITTELBACH-HELMRICH DIETRICH ,  DAHLHAUS JUERGEN

IPC: B01J23/755 ,  B01J23/76 ,  B01J21/06 ,  B01J23/78 ,  B01J23/83 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C209/36 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: A catalyst comprising nickel on a TiO 2 support is obtainable by coprecipitation of nickel and at least one further metal selected from among Si, Zr, Hf, alkaline earth metals, Y, La and Ce, and optionally at least one dopant metal selected from groups 5 to 11 of the Periodic Table of the Elements, from a solution in which the corresponding metal salts are present onto a particulate TiO 2 support, subsequent drying, calcination and reduction and optionally passivation to give the nickel-containing catalyst. It is used, in particular, for the hydrogenation of nitroaromatic compounds.

公开(公告)号：DE50206151D1

公开(公告)日：2006-05-11

申请号：DE50206151

申请日：2002-05-16

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  MUELLER JOERN ,  PENZEL ULRICH ,  GEORGI GUNTER ,  WEIDNER BERND ,  TITTELBACH-HELMRICH DIETRICH ,  DAHLHAUS JUERGEN

IPC: B01J23/755 ,  B01J23/76 ,  B01J21/06 ,  B01J23/78 ,  B01J23/83 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C209/36 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: A catalyst comprising nickel on a TiO 2 support is obtainable by coprecipitation of nickel and at least one further metal selected from among Si, Zr, Hf, alkaline earth metals, Y, La and Ce, and optionally at least one dopant metal selected from groups 5 to 11 of the Periodic Table of the Elements, from a solution in which the corresponding metal salts are present onto a particulate TiO 2 support, subsequent drying, calcination and reduction and optionally passivation to give the nickel-containing catalyst. It is used, in particular, for the hydrogenation of nitroaromatic compounds.

公开(公告)号：DE10124600A1

公开(公告)日：2002-11-28

申请号：DE10124600

申请日：2001-05-21

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  MUELLER JOERN ,  PENZEL ULRICH ,  GEORGI GUNTER ,  WEIDNER BERND ,  TITTELBACH-HELMRICH DIETRICH ,  DAHLHAUS JUERGEN

IPC: B01J23/76 ,  B01J21/06 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C209/36 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51 ,  C07C211/44

Abstract: Production of a supported nickel catalyst involves co-precipitating nickel and at least one other metal (M), selected from silicon, zirconium, hafnium, alkaline earth metals, yttrium, lanthanum and cerium, and optionally a Group 5-11 metal dopant, from a solution containing the corresponding metal salts onto a particulate titania (TiO2) support, and drying, calcining, reducing and optionally passivating the product. An Independent claim is included for a process in which the above catalyst is used.

公开(公告)号：DE10349095A1

公开(公告)日：2005-05-19

申请号：DE10349095

申请日：2003-10-17

Applicant: BASF AG

Inventor： LAAR FREDERIK VAN ,  SCHWAB EKKEHARD ,  OEHLENSCHLAEGER STEFFEN ,  VOS HARTWIG ,  MACKENROTH WOLFGANG ,  MORGENSCHWEIS KONRAD ,  PENZEL ULRICH ,  WEIDNER BERND

IPC: B01J21/18 ,  B01J23/89 ,  B01J37/03 ,  B01J37/14 ,  B01J37/18 ,  C07C209/36 ,  C07C211/51

Abstract: The present invention provides a process for hydrogenating aromatic nitro compounds to the corresponding amines in the presence of hydrogenation catalysts, which comprises using hydrogenation catalysts in which nickel and platinum are present on a support in the form of an alloy having an atomic ratio of nickel to platinum in the alloy of between 30:70 and 70:30.

公开(公告)号：HU0400780A2

公开(公告)日：2004-07-28

申请号：HU0400780

申请日：2002-05-16

Applicant: BASF AG

Inventor： DAHLHAUS JUERGEN ,  GEORGI GUNTER ,  MUELLER JOERN ,  PENZEL ULRICH ,  SCHWAB EKKEHARD ,  TITTELBACH-HELMRICH DIETRICH ,  VANOPPEN DOMINIC ,  WEIDNER BERND

IPC: B01J23/76 ,  B01J21/06 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C209/36 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: A catalyst comprising nickel on a TiO 2 support is obtainable by coprecipitation of nickel and at least one further metal selected from among Si, Zr, Hf, alkaline earth metals, Y, La and Ce, and optionally at least one dopant metal selected from groups 5 to 11 of the Periodic Table of the Elements, from a solution in which the corresponding metal salts are present onto a particulate TiO 2 support, subsequent drying, calcination and reduction and optionally passivation to give the nickel-containing catalyst. It is used, in particular, for the hydrogenation of nitroaromatic compounds.

公开(公告)号：AU2003218967A1

公开(公告)日：2003-09-02

申请号：AU2003218967

申请日：2003-01-30

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  LAAR FREDERIK VAN ,  VOSS HARTWIG ,  OEHLENSCHLAGER STEFFEN ,  MACKENROTH WOLFGANG ,  MORGENSCHWEIS KONRAD ,  PENZEL ULRICH ,  WEIDNER BERND

IPC: C07C29/36 ,  C07C209/36 ,  C07C209/86

Abstract: The invention provides a process for preparing amines by catalytic hydrogenation of nitroaromatics and subsequent removal of the catalysts from the reaction mixture, which contains at least one aromatic amine and water, which comprises carrying out the removal of the catalysts by means of membrane filtration, which is carried out at a pressure on the suspension side of from 5 to 50 bar, a pressure difference between the suspension side and the permeate side of at least 0.3 bar and a flux rate on the suspension side of from 1 to 6 m/s.