公开(公告)号：WO02100537A2

公开(公告)日：2002-12-19

申请号：PCT/EP0206346

申请日：2002-06-10

Applicant: BASF AG ,  VANOPPEN DOMINIC ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK

Inventor： VANOPPEN DOMINIC ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK

IPC: C07H1/00 ,  B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C29/132 ,  C07C29/141 ,  C07C29/145 ,  C07C31/18 ,  C07C31/26 ,  C07H15/04 ,  C13B35/00

CPC classification number: C07C29/132 ,  B01J21/08 ,  B01J23/462 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1023 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/18 ,  C07C31/26 ,  C07C31/18

Abstract: The invention relates to novel ruthenium catalysts which can be obtained by: 1) single or multiple treatment of an amorphous silicon dioxide based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200 DEG C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350 DEG C, wherein step ii) is carried out directly after step i). The invention also relates to a method for the production and use thereof in catalytic hydrogenation of monosaccharides and disaccharides for the production of sugar alcohols with the exception of sorbit.

Abstract translation: 本发明涉及新的钌催化剂，其是通过以下步骤获得：基于无定形二氧化硅具有低分子量的钌化合物的无卤素的水溶液中，然后在低于200℃的温度下干燥所述处理过的载体材料i）一种或多种处理的载体材料，二 ）减少在我获得）固体用氢气产物在的范围内的温度100〜350℃，其特征在于步骤ii）中进行紧随其后的步骤i），它们的制备方法以及它们用于单的催化氢化中使用的过程 糖和二糖生产糖醇的，山梨糖醇除外。

公开(公告)号：WO02053520A2

公开(公告)日：2002-07-11

申请号：PCT/EP0200054

申请日：2002-01-05

Applicant: BASF AG ,  VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  BASSET JEAN-MARIE ,  THIVOLLE-CAZAT JEAN ,  TAOUFIK MOSTAPHA ,  SCHULZ MICHAEL ,  HOEHN ARTHUR

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  BASSET JEAN-MARIE ,  THIVOLLE-CAZAT JEAN ,  TAOUFIK MOSTAPHA ,  SCHULZ MICHAEL ,  HOEHN ARTHUR

IPC: C07C6/08 ,  C07C6/10

CPC classification number: C07C6/10 ,  C07C6/08 ,  C07C2531/12

Abstract: The invention relates to a method for producing hydrocarbons having a modified carbon skeleton by reacting aliphatic hydrocarbons a) with themselves, b) with another aliphatic hydrocarbon or c) with aromatic alkyl substituted hydrocarbons, in the presence of a metal organic catalyst or the hybrid thereof, at a temperature of between 20 - 400 DEG C and a pressure of between 0.2 - 100 bars, wherein the reaction takes place in the presence of hydrogen.

Abstract translation: 通过脂族烃反应制备具有改性碳骨架的烃的方法：a）与其本身; b）与另一种脂族烃或c）与芳族烷基取代的烃在有机金属催化剂或其杂化物存在下，在20-400℃的温度和0.2-100巴的压力下，通过在氢存在下 执行。

公开(公告)号：WO02100539A8

公开(公告)日：2003-12-24

申请号：PCT/EP0206349

申请日：2002-06-10

Applicant: BASF AG ,  VANOPPEN DOMINIC ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK

Inventor： VANOPPEN DOMINIC ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK

IPC: B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/26

CPC classification number: B01J23/462 ,  B01J21/08 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/18 ,  C07C29/132 ,  C07C31/26

Abstract: The invention relates to a method for the production of sorbit by catalytic hydrogenation of a monosaccharide forming sorbit during said hydrogenation in a liquid phase, characterized in that the catalyst is obtained by 1) single or multiple treatment of an amorphous silicon dioxide based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200° C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350° C, wherein step ii) is carried out directly after step i).

Abstract translation: 本发明涉及一种方法，用于由单糖，其形成于加氢山梨糖醇，在液相中，其特征在于，所述催化剂的催化氢化制备山梨糖醇是可获得的条件：i）一种或基于在载体材料上的多个治疗 具有低分子量的钌化合物的无卤素的水溶液的无定形二氧化硅，然后在低于200℃的温度下干燥所述处理过的载体材料，ii）降低在我获得）固体用氢气产物在100〜350℃的范围内的温度，得到 步骤ii）在步骤i）之后立即进行。

公开(公告)号：WO02100538A8

公开(公告)日：2003-11-20

申请号：PCT/EP0206348

申请日：2002-06-10

Applicant: BASF AG ,  BOETTCHER ARND ,  VANOPPEN DOMINIC ,  ARNDT JAN-DIRK

Inventor： BOETTCHER ARND ,  VANOPPEN DOMINIC ,  ARNDT JAN-DIRK

IPC: B01J21/08 ,  B01J23/46 ,  B01J37/18 ,  C07B61/00 ,  C07D303/30 ,  C08G59/14 ,  C08G59/24 ,  C07C5/10 ,  C07D303/02

CPC classification number: B01J37/18 ,  B01J21/08 ,  B01J23/462 ,  C07D303/30 ,  C08G59/1405 ,  C08G59/24

Abstract: A method for the production of cycloaliphatic compounds (I) having side chains with expoxy groups by heterogenous-catalytic hydrogenation of a compound (II) having at least one carbocyclic, aromatic group and at least one side chain with at least one epoxy group, on a ruthenium catalyst, characterized in that the ruthenium catalyst is obtained by i) single or multiple treatment of an amorphous silicon dioxide based carrier material with a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200 DEG C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350 DEG C, wherein step ii) is carried out directly after step i).

Abstract translation: 一种用于脂环族化合物（I）的制备方法中，侧链具有环氧基包括由Vebindung（II）的非均相-katalische氢化，具有至少一个碳环芳族基团和具有至少一个环氧基团的至少一个侧链，在钌催化剂 其特征在于，钌催化剂是通过以下步骤获得：基于无定形二氧化硅具有低分子量的钌化合物的无卤素的水溶液中，然后在低于200℃的温度下干燥所述处理过的载体材料i）一种或多种处理的载体材料; ii）降低）固体Wasserstof第（i中得到的产物在100至350℃，该方法包括执行步骤的温度范围（ⅱ）紧接步骤（i）。

公开(公告)号：HU0400780A2

公开(公告)日：2004-07-28

申请号：HU0400780

申请日：2002-05-16

Applicant: BASF AG

Inventor： DAHLHAUS JUERGEN ,  GEORGI GUNTER ,  MUELLER JOERN ,  PENZEL ULRICH ,  SCHWAB EKKEHARD ,  TITTELBACH-HELMRICH DIETRICH ,  VANOPPEN DOMINIC ,  WEIDNER BERND

IPC: B01J23/76 ,  B01J21/06 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C209/36 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: A catalyst comprising nickel on a TiO 2 support is obtainable by coprecipitation of nickel and at least one further metal selected from among Si, Zr, Hf, alkaline earth metals, Y, La and Ce, and optionally at least one dopant metal selected from groups 5 to 11 of the Periodic Table of the Elements, from a solution in which the corresponding metal salts are present onto a particulate TiO 2 support, subsequent drying, calcination and reduction and optionally passivation to give the nickel-containing catalyst. It is used, in particular, for the hydrogenation of nitroaromatic compounds.

公开(公告)号：AU2003218967A1

公开(公告)日：2003-09-02

申请号：AU2003218967

申请日：2003-01-30

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  LAAR FREDERIK VAN ,  VOSS HARTWIG ,  OEHLENSCHLAGER STEFFEN ,  MACKENROTH WOLFGANG ,  MORGENSCHWEIS KONRAD ,  PENZEL ULRICH ,  WEIDNER BERND

IPC: C07C29/36 ,  C07C209/36 ,  C07C209/86

Abstract: The invention provides a process for preparing amines by catalytic hydrogenation of nitroaromatics and subsequent removal of the catalysts from the reaction mixture, which contains at least one aromatic amine and water, which comprises carrying out the removal of the catalysts by means of membrane filtration, which is carried out at a pressure on the suspension side of from 5 to 50 bar, a pressure difference between the suspension side and the permeate side of at least 0.3 bar and a flux rate on the suspension side of from 1 to 6 m/s.

公开(公告)号：NO20033029D0

公开(公告)日：2003-07-02

申请号：NO20033029

申请日：2003-07-02

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  BASSET JEAN-MARIE ,  THIVOLLE-CAZAT JEAN ,  TAOUFIK MOSTAPHA ,  SCHULZ MICHAEL ,  HOEHN ARTHUR

IPC: C07C6/08 ,  C07C6/10

公开(公告)号：AU2002319210A1

公开(公告)日：2002-12-23

申请号：AU2002319210

申请日：2002-06-10

Applicant: BASF AG

Inventor： ARNDT JAN-DIRK ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  VANOPPEN DOMINIC

IPC: C07H1/00 ,  B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C29/132 ,  C07C29/141 ,  C07C29/145 ,  C07C31/18 ,  C07C31/26 ,  C07H15/04 ,  C13B35/00

Abstract: Providing a ruthenium catalyst for the production of sugar alcohols. Ruthenium catalysts (I) are prepared by: (A) a single or multiple treatment of an amorphous silicon dioxide support material with a halogen free solution of a low mol. wt. ruthenium compound followed by drying at below 200 [deg]C; (B) reduction of the resulting solid with hydrogen at 100-350 [deg]C such that step (B) is carried out immediately after step (A). An independent claim is included for a process for the production of sugar alcohols by catalytic hydrogenation of the corresponding mono- and oligosaccharides in the liquid phase at the heterogeneous catalyst (I), excluding a process for the production of sorbitol.

公开(公告)号：DE50301146D1

公开(公告)日：2005-10-13

申请号：DE50301146

申请日：2003-01-30

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  VAN LAAR FREDERIK ,  VOSS HARTWIG ,  OEHLENSCHLAEGER STEFFEN ,  MACKENROTH WOLFGANG ,  MORGENSCHWEIS KONRAD ,  PENZEL ULRICH ,  WEIDNER BERND

IPC: C07C29/36 ,  C07C209/36 ,  C07C209/86

Abstract: The invention provides a process for preparing amines by catalytic hydrogenation of nitroaromatics and subsequent removal of the catalysts from the reaction mixture, which contains at least one aromatic amine and water, which comprises carrying out the removal of the catalysts by means of membrane filtration, which is carried out at a pressure on the suspension side of from 5 to 50 bar, a pressure difference between the suspension side and the permeate side of at least 0.3 bar and a flux rate on the suspension side of from 1 to 6 m/s.

公开(公告)号：BR0210334A

公开(公告)日：2004-09-21

申请号：BR0210334

申请日：2002-06-10

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK

IPC: B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/26

Abstract: A process is described for preparing sorbitol by catalytic hydrogenation of a monosaccharide forming sorbitol on hydrogenation in the liquid phase, which comprises the catalyst being obtainable by: i) single or multiple treatment of an amorphous silicon dioxide based support material with a halogen-free aqueous solution of a low-molecular-weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reducing the solid obtained in i) with hydrogen at from 100 to 350° C., step ii) being carried out immediately after step i).