公开(公告)号：JP2000256279A

公开(公告)日：2000-09-19

申请号：JP2000057164

申请日：2000-03-02

Applicant: BASF AG

Inventor： SANDER MICHAEL ,  PEISKER DIETMAR ,  WELLNER KLAUS ,  BRAUNSBERG HOLGER ,  GEORGI GUNTER ,  PENZEL ULRICH

IPC: B01J35/02 ,  B01J21/06 ,  B01J23/755 ,  B01J35/10 ,  C07B61/00 ,  C07C209/36 ,  C07C211/50

Abstract: PROBLEM TO BE SOLVED: To provide an industrially practicable method for producing an amine by hydrogenation, consuming a small amount of a catalyst, greatly avoiding the occurrence of secondary reaction, capable of setting an excellent catalyst balance, excellently separating an inactive catalytic component. SOLUTION: This method comprises producing an amine by hydrogenating a compound containing at least one nitro group in the presence of a supported catalyst containing at least nickel as a catalytic active metal. The reduced and stabilized supported catalyst contains nickel microcrystal showing a two mode nickel microcrystal particle size distribution having maximum values at 30-80 Angstrom (300-800 nm) and 81-150 Angstrom (810-1,500 nm). The catalyst having 60-80 mass % nickel content, 0-20 mass % SiO2 content, 0-40 mass % ZrO2 content and 0-4 mass % HfO2 content in a reduced passivation state and at least 70% degree of reduction after further reduction for 1 hour at 100 deg.C is used.

公开(公告)号：HU229646B1

公开(公告)日：2014-03-28

申请号：HU0400780

申请日：2002-05-16

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  MUELLER JOERN ,  PENZEL ULRICH ,  GEORGI GUNTER ,  WEIDNER BERND ,  TITTELBACH-HELMRICH DIETRICH ,  DAHLHAUS JUERGEN

IPC: B01J23/755 ,  B01J23/76 ,  B01J21/06 ,  B01J23/78 ,  B01J23/83 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C209/36 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: A catalyst comprising nickel on a TiO 2 support is obtainable by coprecipitation of nickel and at least one further metal selected from among Si, Zr, Hf, alkaline earth metals, Y, La and Ce, and optionally at least one dopant metal selected from groups 5 to 11 of the Periodic Table of the Elements, from a solution in which the corresponding metal salts are present onto a particulate TiO 2 support, subsequent drying, calcination and reduction and optionally passivation to give the nickel-containing catalyst. It is used, in particular, for the hydrogenation of nitroaromatic compounds.

公开(公告)号：HU229267B1

公开(公告)日：2013-10-28

申请号：HU0301844

申请日：2001-05-21

Applicant: BASF AG

Inventor： WOELFERT ANDREAS ,  PENZEL ULRICH

IPC: B01F3/08 ,  B01F5/00 ,  B01J19/24 ,  B01F5/02 ,  B01F15/02 ,  C07B43/10 ,  C07B61/00 ,  C07C263/10 ,  C07C265/14

Abstract: Starting material streams are mixed in a mixer (13) for the phosgenation of amines by a process in which the reaction product (3) is removed in a closed loop and the starting material streams (1.2) contain organic solvents. The main streams (1.1, 2.1) and/or part-streams (1.2, 2.2) of the starting materials (1, 2) come into contact with one another according to the countercurrent principle.

公开(公告)号：PT1575908E

公开(公告)日：2006-12-29

申请号：PT03785813

申请日：2003-12-13

Applicant: BASF AG

Inventor： PENZEL ULRICH ,  MARTIN SOHN DR ,  ABEEL PETER VAN DEN ,  JACOBS JAN D ,  STROEFER ECKHARD ,  NEVEJANS FILIP ,  PALLASCH HANS-JUERGEN ,  DEBERDT FILIP ,  MACKENROTH WOLFGANG

IPC: C07C263/20

公开(公告)号：AT335721T

公开(公告)日：2006-09-15

申请号：AT03785813

申请日：2003-12-13

Applicant: BASF AG

Inventor： SOHN MARTIN ,  STROEFER ECKHARD ,  NEVEJANS FILIP ,  PENZEL ULRICH ,  PALLASCH HANS-JUERGEN ,  VAN DEN ABEEL PETER ,  DEBERDT FILIP ,  JACOBS JAN D ,  MACKENROTH WOLFGANG

IPC: C07C263/20

Abstract: The invention relates to a process for preparing isocyanates by reaction of amines with phosgene in the presence of inert organic solvents in a reactor and subsequent work-up of the reaction mixture leaving the reactor, wherein the solvent is separated off in a two-stage or multistage, preferably two-stage, distillation process in which the solvent is separated off at a pressure of 0.1-15 bar in a first apparatus and at 1-900 mbar in a second apparatus or further apparatuses, with the heat of condensation of the solvent vapor from the first apparatus being used for partial or complete vaporization of solvent in the second apparatus.

公开(公告)号：DE50206151D1

公开(公告)日：2006-05-11

申请号：DE50206151

申请日：2002-05-16

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  MUELLER JOERN ,  PENZEL ULRICH ,  GEORGI GUNTER ,  WEIDNER BERND ,  TITTELBACH-HELMRICH DIETRICH ,  DAHLHAUS JUERGEN

IPC: B01J23/755 ,  B01J23/76 ,  B01J21/06 ,  B01J23/78 ,  B01J23/83 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C209/36 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: A catalyst comprising nickel on a TiO 2 support is obtainable by coprecipitation of nickel and at least one further metal selected from among Si, Zr, Hf, alkaline earth metals, Y, La and Ce, and optionally at least one dopant metal selected from groups 5 to 11 of the Periodic Table of the Elements, from a solution in which the corresponding metal salts are present onto a particulate TiO 2 support, subsequent drying, calcination and reduction and optionally passivation to give the nickel-containing catalyst. It is used, in particular, for the hydrogenation of nitroaromatic compounds.

公开(公告)号：AU2003294849A1

公开(公告)日：2004-07-14

申请号：AU2003294849

申请日：2003-12-13

Applicant: BASF AG

Inventor： SOHN MARTIN ,  STROEFER ECKHARD ,  NEVEJANS FILIP ,  PENZEL ULRICH ,  PALLASCH HANS-JURGEN ,  ABEEL PETER VAN DEN ,  DEBERDT FILIP ,  JACOBS JAN D ,  MACKENROTH WOLFGANG

IPC: C07C263/20

Abstract: The invention relates to a process for preparing isocyanates by reaction of amines with phosgene in the presence of inert organic solvents in a reactor and subsequent work-up of the reaction mixture leaving the reactor, wherein the solvent is separated off in a two-stage or multistage, preferably two-stage, distillation process in which the solvent is separated off at a pressure of 0.1-15 bar in a first apparatus and at 1-900 mbar in a second apparatus or further apparatuses, with the heat of condensation of the solvent vapor from the first apparatus being used for partial or complete vaporization of solvent in the second apparatus.

公开(公告)号：AU2003293871A1

公开(公告)日：2004-07-14

申请号：AU2003293871

申请日：2003-12-13

Applicant: BASF AG

Inventor： SOHN MARTIN ,  STROEFER ECKHARD ,  NEVEJANS FILIP ,  PENZEL ULRICH ,  PALLASCH HANS-JURGEN ,  LEUTHOLD RENE ,  BRODHAGEN ANDREAS ,  WOLFERT ANDREAS ,  MACKENROTH WOLFGANG ,  MAURER MARKUS

IPC: C07C263/10 ,  C07C265/14

Abstract: The invention relates to a process for preparing polyisocyanates by reacting organic amines with phosgene, wherein the reaction is carried out in at least three stages, with the first stage being carried out in a mixing apparatus, the second stage in at least one residence apparatus and the third stage in at least one separation apparatus and the pressure in each successive stage being lower than that in the previous stage.

公开(公告)号：HU222987B1

公开(公告)日：2004-01-28

申请号：HU0201848

申请日：2000-06-16

Applicant: BASF AG

Inventor： NEVEJANS FILIP ,  PENZEL ULRICH ,  REIF MARTIN ,  SCHARR VOLKER ,  SCHWARZ HANS VOLKMAR ,  VAN DEN ABEEL PETER

IPC: C07C263/10 ,  C07C265/14 ,  C08G18/76

Abstract: A process is provided for preparing light-colored isocyanates which can be used for preparing urethane compounds, in particular polyurethanes, for example polyurethane foams.

公开(公告)号：HU0301313A2

公开(公告)日：2003-08-28

申请号：HU0301313

申请日：2001-06-29

Applicant: BASF AG

Inventor： PENZEL ULRICH ,  WOELFERT ANDREAS

IPC: B01F5/00 ,  B01F3/08 ,  B01F5/02 ,  B01F5/04 ,  B01F13/10 ,  B01F15/02 ,  B01J19/00 ,  B29B7/32 ,  C07B43/10 ,  C07B61/00 ,  C07C263/10 ,  C07C265/14

Abstract: In a process for mixing reactant streams ( 1, 2; 5 ) to produce a product stream ( 10 ) using a mixing configuration ( 15, 16 ) having a number of reactant feed points, an excess component stream of one reactant is divided into two reactant substreams ( 1, 2 ) and fed into the suction region ( 3, 4 ) of a mixing space ( 12 ) at right angles to a deficient component ( 5 ) entering the mixing space ( 12 ).