Abstract:
The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. The present invention relates to a process comprising bringing a compound of general formula (I) into the gaseous or aerosol state and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein M is Mn, Ni or Co, X is a ligand which coordinates M, n is 0, 1, or 2, R1, R2 are an alkyl group, an alkenyl group, an aryl group or a silyl group, m is 1, 2, or 3, R3, R4, and R5 are an alkyl group, an alkenyl group, an aryl group, an alkoxy group, or an aryloxy group, and p is 1, 2 or 3.
Abstract:
A nitrate salt composition comprising A) an alkali metal nitrate and optionally an alkali metal nitrite in a total amount in the range from 90 to 99.84% by weight and B)an alkali metal compound selected from the group B1) alkali metal oxide, B2) alkali metal carbonate, B3) alkali metal compound which decomposes into alkali metal oxide or alkali metal carbonate in the temperature range from 250° C. to 600° C., B4) alkali metal hydroxide MetOH, in which Met is lithium, sodium, potassium, rubidium, cesium, B5) alkali metal peroxide Met2O2, in which Met is lithium, sodium, potassium, rubidium, cesium, and B6) alkali metal superoxide MetO2, in which Met is sodium, potassium, rubidium, cesium, in a total amount in the range from 0.16 to 10% by weight, in each case based on the nitrate salt composition.
Abstract:
Process for the recovery of transition metal from spent lithium ion batteries containing nickel, wherein said process comprises the steps of (a) heating a lithium containing transition metal oxide material to a temperature in the range of from 400 to 1200° C., (b) treating said heat-treated material with water, (c) treating the solid residue from step (b) with an acid selected from sulfuric acid, hydrochloric acid, nitric acid, methanesulfonic acid, oxalic acid and citric acid, (d) adjusting the pH value to 2.5 to 8, (e) removing compounds of Al, Cu, Fe, Zn or combinations of at least two of the foregoing from the solution or slurry obtained in step (d).
Abstract:
A pipeline system in a linearly concentrating solar power station comprises at least one pipeline which is connected at one end to a converger and at a second end to a distributor. The converger and the distributor are arranged at a different geodetic height. When the converger lies on top pressurized gas can be fed into the converger and the distributor is connected to a drainage container. When the distributor lies on top pressurized gas can be fed into the distributor and the converger is connected to a drainage container. The drainage container is lower than the converter and the distributor.
Abstract:
Method of maintaining or widening the long-term operating temperature range of a heat transfer medium and/or heat storage medium comprising a nitrate salt composition selected from the group consisting of alkali metal nitrate and alkaline earth metal nitrate and optionally alkali metal nitrite and alkaline earth metal nitrite, wherein all or part of the nitrate salt composition is brought into contact with an additive composed of a combination of elemental oxygen and nitrogen oxides.
Abstract:
Disclosed herein are methods for leaching a material comprising one or more metals in a zero oxidation state and one or more chosen from metal oxides, metal hydroxides, and combinations thereof, wherein the method comprises contacting the material with an oxidizing acidic aqueous solution having a pH less than 6, and subsequently reducing the one or more chosen from metal oxides, metal hydroxides, and combinations thereof with a reducing agent. Also disclosed are methods comprising leaching a material to obtain an aqueous solution comprising metal ions, and separating the metal ions to obtain at least one essentially pure metal ion solution and/or at least one essentially pure solid metal ion salt. Further disclosed are methods comprising mechanically comminuting a material to obtain a black mass, and leaching the black mass.
Abstract:
The invention relates to an apparatus for heating a pipeline system, comprising at least two pipelines (1), along which in each case one electrical resistance heating element extends, wherein a potential close to the ground potential is set at each electrical resistance heating element at at least one end (3, 5), and the electrical resistance heating element is connected to a terminal of a DC source or to in each case one phase (7) of an n-phase AC source (9) at a position remote from this end (3, 5), where, when using an n-phase AC source (9), n is an integer equal to or greater than 2.
Abstract:
Nitrate salt composition comprising as significant constituentsA) an alkali metal nitrate and optionally an alkali metal nitrite in a total amount in the range from 90 to 99.84% by weight and B) an alkali metal compound selected from the group B1) alkali metal oxide, B2) alkali metal carbonate, B3) alkali metal compound which decomposes into alkali metal oxide or alkali metal carbonate in the temperature range from 250° C. to 600° C., B4) alkali metal hydroxide MetOH, in which Met is lithium, sodium, potassium, rubidium, cesium, B5) alkali metal peroxide Met2O2, in which Met is lithium, sodium, potassium, rubidium, cesium, and B6) alkali metal superoxide MetO2, in which Met is sodium, potassium, rubidium, cesium, in a total amount in the range from 0.16 to 10% by weight, in each case based on the nitrate salt composition.
Abstract:
The present invention is in the field of processes for preparing inorganic metal- or semimetal-containing films. The process for preparing inorganic metal- or semimetal-containing films comprising (a) depositing a metal- or semimetal-containing compound from the gaseous state onto a solid substrate and (b) bringing the solid substrate with the deposited metal- or semimetal-containing compound in contact with a compound of general formula (I) or (II) wherein Z is NR2, PR2, OR, SR, CR2, SiR2, X is H, R′ or NR′2, wherein at least one X is H, n is 1 or 2, and R and R′ is an alkyl group, an alkenyl group, an aryl group, or a silyl group.
Abstract:
The invention relates to a method for operating a linearly concentrating solar power plant (1), in which a heat transfer medium flows through a pipeline loop (47) having at least one receiver, the heat transfer medium having a flow velocity which is such that the flow in the pipeline loop (47) is turbulent, at least part of the heat transfer medium, upon exit from the pipeline loop (47), being extracted and recirculated into the pipeline loop (47). Furthermore, the invention relates to a linearly concentrating solar power plant with at least one pipeline loop (47) having at least one receiver in which a heat transfer medium flowing through the pipeline loop (47) is heated by irradiating solar energy, a mixing device (27) being comprised, in which at least part of the heat transfer medium flowing through the pipeline loop (47) is mixed with heat transfer medium to be delivered.