PROCESS FOR FORMING A TITANIA-CONTAINING PREFORM SILICA GLASS BLANK
    1.
    发明申请
    PROCESS FOR FORMING A TITANIA-CONTAINING PREFORM SILICA GLASS BLANK 审中-公开
    用于形成含钛的预制二氧化硅玻璃空白的方法

    公开(公告)号:WO9800372A3

    公开(公告)日:1998-02-26

    申请号:PCT/US9709988

    申请日:1997-06-09

    CPC classification number: C03B37/01413 C03B37/01446 C03B2201/42 C03C13/045

    Abstract: The present invention is directed to a process for forming a preform suitable for consolidation to a glass blank for producing an optical waveguide fiber. The preform comprises a core portion and an inner cladding layer surrounding the core portion and contains SiO2 and TiO2. A portion of the TiO2 in the preform is in a crystalline form that is predominantly rutile. In addition to SiO2 and TiO2, the preform contains an additive compound that is preferentially sacrificed instead of TiO2 when the preform is consolidated. The process includes oxidizing Si and Ti containing compounds as well as a precursor of the additive compound to form SiO2, TiO2, and the additive compound. The preform containing these materials is then formed. In addition, the preform can be converted to a glass blank by consolidation of the preform.

    INCREASING THE RETENTION OF GEO2 DURING PRODUCTION OF GLASS ARTICLES

    公开(公告)号:CA2230976A1

    公开(公告)日:1997-03-13

    申请号:CA2230976

    申请日:1996-09-04

    Applicant: CORNING INC

    Abstract: A method is disclosed for forming a GeO2-doped SiO2 glass article by depositing glass particles to form a porous preform and then drying and sintering the porous preform. A precursor of SnO2 is also present in the reactant stream used to form the particles, whereby the reaction produces particles of glass that contain GeO2, SiO2 and SnO2. The presence of SnO2 in the particles reduces the reaction of GeO2 with chlorine to form GeCl4 during the drying step. The GeC14 that would have formed would have either escaped from the porous preform or caused GeO2 to be re-deposited in an undesirable portion of the preform. The retention of GeO2 in the article is therefore enhanced.

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