公开(公告)号：KR840000986B1

公开(公告)日：1984-07-13

申请号：KR810002828

申请日：1981-08-04

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  KUCH PHILIP LAWRENCE ,  PAPARIZOS CHRISTOS

IPC: C07C57/055 ,  B01J23/76 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00

公开(公告)号：KR870001317B1

公开(公告)日：1987-07-13

申请号：KR810003303

申请日：1981-09-04

Applicant: STANDARD OIL CO

Inventor： SHAW WILFRID GARSIDE ,  RINZ JAMES EDWARD ,  PAPARIZOS CHRISTOS

IPC: C07C69/533 ,  B01J27/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/377 ,  C07C57/03 ,  C07C57/05 ,  C07C67/00

公开(公告)号：KR870001316B1

公开(公告)日：1987-07-13

申请号：KR810003316

申请日：1981-09-05

Applicant: STANDARD OIL CO

Inventor： SHAW WILFRID GARSIDE ,  KUCH PHILIP LAWRENCE ,  PAPARIZOS CHRISTOS

IPC: C07C69/533 ,  B01J27/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/377 ,  C07C57/03 ,  C07C57/05 ,  C07C67/00

公开(公告)号：KR840000985B1

公开(公告)日：1984-07-13

申请号：KR810002827

申请日：1981-08-04

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  RING JAMES EDWARD ,  PAPARIZOS CHRISTOS

IPC: C07C57/055 ,  B01J23/76 ,  B01J27/198 ,  B01J27/199 ,  C01B25/45 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00

公开(公告)号：DE3672245D1

公开(公告)日：1990-08-02

申请号：DE3672245

申请日：1986-04-16

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE ,  CALLAHAN JAMES LOUIS

IPC: C07B61/00 ,  B01J23/00 ,  B01J27/00 ,  C07C67/39 ,  C07C69/54

公开(公告)号：DE3169964D1

公开(公告)日：1985-05-23

申请号：DE3169964

申请日：1981-06-26

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  RINZ JAMES EDWARD ,  PAPARIZOS CHRISTOS

IPC: C07C57/055 ,  B01J23/76 ,  B01J27/198 ,  B01J27/199 ,  C01B25/45 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00 ,  B01J27/18 ,  B01J23/88 ,  C07C57/04

Abstract: Catalytic compositions of the empirical formula: Mo12 P0.1-3 Bi0.01-2 M0.1-3 Cu0.01-2 V0.01-3 Xa YbOc where M is at least one of K, Rb and Cs; x is at least one of Ba, Zn, Ga, Cd and Ti when a > 0; Y is at least one of Ca, Mg, Ta, Zr, Ce, Ni, Co, Cr, Fe and Tl when b > 0; a is a number of 0 to about 2; b is a number of 0 to about 2; and c is a number that satisfies the valence requirements of the other elements present, are excellent catalysts for the oxidation of methacrolein to methacrylic acid.

公开(公告)号：DE3260617D1

公开(公告)日：1984-10-04

申请号：DE3260617

申请日：1982-02-15

Applicant: STANDARD OIL CO OHIO

Inventor： CALLAHAN JAMES LOUIS ,  SHAW WILFRID GARSIDE ,  GRASSELLI ROBERT KARL

IPC: C07C57/05 ,  B01J23/84 ,  B01J27/192 ,  B01J35/00 ,  B01J37/02 ,  B01J37/04 ,  C07B61/00 ,  C07C45/00 ,  C07C45/35 ,  C07C47/22 ,  C07C51/00 ,  C07C51/215 ,  C07C67/00 ,  C07C51/25

公开(公告)号：DE3163879D1

公开(公告)日：1984-07-05

申请号：DE3163879

申请日：1981-07-24

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  RINZ JAMES EDWARD ,  PAPARIZOS CHRISTOS

IPC: C07C69/533 ,  B01J27/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/377 ,  C07C57/03 ,  C07C57/05 ,  C07C67/00 ,  C07C69/52 ,  C07C67/317

Abstract: Saturated, lower aliphatic acids and esters are oxydehydrogenated to the corresponding unsaturated acids and esters by use of a catalyst of the empirical formula: Mo12P0.1-3Bi0.01-2M0.1-3Cu0.01-2V0.01-3XaM'bOc (I) where M is at least one of K, Rb and Cs; X is at least one of Ba, Zn, Ga, Cd, Ti, when a>0; M' is at least one of Ca, Mg, Ta, Zr, Ce, Ni, Co, Cr, Fe and Tl when b>0; a is a number of 0 to about 2; b is a number of 0 to about 2; and c is a number that satisfies the valence requirements of the other elements present.

公开(公告)号：DE3162972D1

公开(公告)日：1984-05-10

申请号：DE3162972

申请日：1981-08-05

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  PAPARIZOS CHRISTOS ,  KUCH PHILIP LAWRENCE

IPC: C07C69/533 ,  B01J27/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/377 ,  C07C57/03 ,  C07C57/05 ,  C07C67/00 ,  C07C69/52 ,  C07C67/317

Abstract: Olefinic acids and esters, such as methacrylic acid and methylmethacrylate, are prepared by contacting in the presence of molecular oxygen the corresponding saturated acid or ester, such as isobutyric acid or methylisobutyrate with the catalyst of the empirical formula: Mo12P0.1-3M0.1-3Cu0.01-2V0.01-2X0.01-2M'aOb (I) where M is at least one of K, Rb and Cs; X is at least one of Ba, La, Ga, Al, Ag, Cd, Ti, Tl, Hg, Pb and Zn; M' is at least one of Fe, Co, Ni, Sr, Mn, In, Ta, Ge, S and Be when a >0; a is a number of 0 to about 2; and b is a number that satisfies the valence requirements of the other elements present.

公开(公告)号：FI62959B

公开(公告)日：1982-12-31

申请号：FI257074

申请日：1974-09-03

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: C07C27/14 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  B01J27/198 ,  B01J27/199 ,  C07B35/04 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/20 ,  C07C47/22 ,  C07C51/25 ,  C07C57/05 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/84

Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.