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公开(公告)号：KR840000985B1
公开(公告)日：1984-07-13
申请号：KR810002827
申请日：1981-08-04
Applicant: STANDARD OIL CO OHIO
Inventor： SHAW WILFRID GARSIDE , RING JAMES EDWARD , PAPARIZOS CHRISTOS
IPC: C07C57/055 , B01J23/76 , B01J27/198 , B01J27/199 , C01B25/45 , C07B61/00 , C07C51/00 , C07C51/235 , C07C51/25 , C07C67/00
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公开(公告)号：KR840000986B1
公开(公告)日：1984-07-13
申请号：KR810002828
申请日：1981-08-04
Applicant: STANDARD OIL CO OHIO
Inventor： SHAW WILFRID GARSIDE , KUCH PHILIP LAWRENCE , PAPARIZOS CHRISTOS
IPC: C07C57/055 , B01J23/76 , B01J27/198 , B01J27/199 , C07B61/00 , C07C51/00 , C07C51/235 , C07C51/25 , C07C67/00
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公开(公告)号：DE3672245D1
公开(公告)日：1990-08-02
申请号：DE3672245
申请日：1986-04-16
Applicant: STANDARD OIL CO OHIO
Inventor： PAPARIZOS CHRISTOS , SHAW WILFRID GARSIDE , CALLAHAN JAMES LOUIS
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公开(公告)号：DE3169964D1
公开(公告)日：1985-05-23
申请号：DE3169964
申请日：1981-06-26
Applicant: STANDARD OIL CO OHIO
Inventor： SHAW WILFRID GARSIDE , RINZ JAMES EDWARD , PAPARIZOS CHRISTOS
IPC: C07C57/055 , B01J23/76 , B01J27/198 , B01J27/199 , C01B25/45 , C07B61/00 , C07C51/00 , C07C51/235 , C07C51/25 , C07C67/00 , B01J27/18 , B01J23/88 , C07C57/04
Abstract: Catalytic compositions of the empirical formula: Mo12 P0.1-3 Bi0.01-2 M0.1-3 Cu0.01-2 V0.01-3 Xa YbOc where M is at least one of K, Rb and Cs; x is at least one of Ba, Zn, Ga, Cd and Ti when a > 0; Y is at least one of Ca, Mg, Ta, Zr, Ce, Ni, Co, Cr, Fe and Tl when b > 0; a is a number of 0 to about 2; b is a number of 0 to about 2; and c is a number that satisfies the valence requirements of the other elements present, are excellent catalysts for the oxidation of methacrolein to methacrylic acid.
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公开(公告)号：DE3260617D1
公开(公告)日：1984-10-04
申请号：DE3260617
申请日：1982-02-15
Applicant: STANDARD OIL CO OHIO
Inventor： CALLAHAN JAMES LOUIS , SHAW WILFRID GARSIDE , GRASSELLI ROBERT KARL
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Patent Agency Ranking
公开(公告)号：DE3163879D1
公开(公告)日：1984-07-05
申请号：DE3163879
申请日：1981-07-24
Applicant: STANDARD OIL CO OHIO
Inventor： SHAW WILFRID GARSIDE , RINZ JAMES EDWARD , PAPARIZOS CHRISTOS
IPC: C07C69/533 , B01J27/00 , C07B61/00 , C07C51/00 , C07C51/377 , C07C57/03 , C07C57/05 , C07C67/00 , C07C69/52 , C07C67/317
Abstract: Saturated, lower aliphatic acids and esters are oxydehydrogenated to the corresponding unsaturated acids and esters by use of a catalyst of the empirical formula: Mo12P0.1-3Bi0.01-2M0.1-3Cu0.01-2V0.01-3XaM'bOc (I) where M is at least one of K, Rb and Cs; X is at least one of Ba, Zn, Ga, Cd, Ti, when a>0; M' is at least one of Ca, Mg, Ta, Zr, Ce, Ni, Co, Cr, Fe and Tl when b>0; a is a number of 0 to about 2; b is a number of 0 to about 2; and c is a number that satisfies the valence requirements of the other elements present.
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7.发明专利
公开(公告)号：DE3162972D1
公开(公告)日：1984-05-10
申请号：DE3162972
申请日：1981-08-05
Applicant: STANDARD OIL CO OHIO
Inventor： SHAW WILFRID GARSIDE , PAPARIZOS CHRISTOS , KUCH PHILIP LAWRENCE
IPC: C07C69/533 , B01J27/00 , C07B61/00 , C07C51/00 , C07C51/377 , C07C57/03 , C07C57/05 , C07C67/00 , C07C69/52 , C07C67/317
Abstract: Olefinic acids and esters, such as methacrylic acid and methylmethacrylate, are prepared by contacting in the presence of molecular oxygen the corresponding saturated acid or ester, such as isobutyric acid or methylisobutyrate with the catalyst of the empirical formula: Mo12P0.1-3M0.1-3Cu0.01-2V0.01-2X0.01-2M'aOb (I) where M is at least one of K, Rb and Cs; X is at least one of Ba, La, Ga, Al, Ag, Cd, Ti, Tl, Hg, Pb and Zn; M' is at least one of Fe, Co, Ni, Sr, Mn, In, Ta, Ge, S and Be when a >0; a is a number of 0 to about 2; and b is a number that satisfies the valence requirements of the other elements present.
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公开(公告)号：FI62959B
公开(公告)日：1982-12-31
申请号：FI257074
申请日：1974-09-03
Applicant: STANDARD OIL CO OHIO
Inventor： GRASSELLI ROBERT KARL , MILLER ARTHUR FRANCIS , SHAW WILFRID GARSIDE
IPC: C07C27/14 , B01J23/88 , B01J23/882 , B01J23/883 , B01J23/887 , B01J23/888 , B01J23/89 , B01J27/192 , B01J27/198 , B01J27/199 , C07B35/04 , C07B61/00 , C07C5/333 , C07C5/48 , C07C27/00 , C07C27/12 , C07C45/00 , C07C45/34 , C07C45/35 , C07C47/20 , C07C47/22 , C07C51/25 , C07C57/05 , C07C67/00 , C07C253/00 , C07C255/08 , B01J23/84
Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.
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公开(公告)号：DE3218936A1
公开(公告)日：1982-12-23
申请号：DE3218936
申请日：1982-05-19
Applicant: STANDARD OIL CO OHIO
Inventor： CALLAHAN JAMES LOUIS , SHAW WILFRID GARSIDE , MILLER ARTHUR FRANCIS
IPC: B01J27/188 , B01J27/19 , B01J37/02 , C07C51/235 , C07C51/25 , C07C57/055 , B01J27/18
Abstract: Process for preparing highly active catalysts on the basis of phosphomolybdic acid by preparing a solution of hydrated phosphomolybdic acid in an essentially anhydrous alkyl alcohol, optionally with the addition of a base to the solution, evaporating the solution to prepare a catalyst powder, and final drying and calcining of the powder to form the active catalyst. A further preparation process comprises preparing a solution of hydrated phosphomolybdic acid in an essentially anhydrous alkyl alcohol, evaporation of the solution to prepare a concentrate, impregnating a catalyst support material with the concentrate, bringing the impregnated support into contact with ammonia gas in an amount which is sufficient to form an insoluble precipitate of ammonium alkyl phosphomolybdic acid within the pore structure of the support material, followed by drying and calcining the impregnated support material to form a laminar catalyst.
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公开(公告)号：ATA582280A
公开(公告)日：1982-10-15
申请号：AT582280
申请日：1980-11-28
Applicant: STANDARD OIL CO OHIO
Inventor： TENG HARRY HO I , BREMER NOEL JEROME , SHAW WILFRID GARSIDE
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