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1.发明公开Modified silicalite catalysts and their preparation and process for the use thereof 失效改编者silicaliter Katalysator，seine Herstellung und Verfahren zu seiner Anwendung。
公开(公告)号：EP0154063A1
公开(公告)日：1985-09-11
申请号：EP84301345.9
申请日：1984-03-01
Applicant: THE STANDARD OIL COMPANY
Inventor： Desmond, Michael Joseph , Pepera, Marc Anthony
CPC classification number: B01J29/035 , C07C1/044 , C07C2523/72 , C07C2523/745 , C07C2529/03 , C10G2/332 , C10G2/334
Abstract: Catalysts comprising a silica molecular sieve modified by a metal which forms acidic oxides selected from the group consisting of Group VIB and VIIB elements and, a Fischer-Tropsch catalyst wherein the ratio of zeolite to Fischer-Tropsch component is from 0.1 to 10:1 can be employed to produce gasoline quality liquid hydrocarbons from synthesis gas. A process is employed which includes the step of contacting synthesis gas having a ratio of hydrogen to carbon oxides of from 0.1 to 10.0:1 over the foregoing catalyst at a reaction temperature of from 100 . C to 500°C and at a pressure of from one atmosphere (0.1 MPa) to 200 atmospheres (20 MPa) and at a gas hourly space velocity of from 10 to 100,000. A method is also provided for the preparation of the combination catalyst. The liquid hydrocarbon product is highly aromatic, essentially free of external olefins and totally free of detectable oxygenates.
Abstract translation: 包含由金属改性的二氧化硅分子筛的催化剂，其形成选自VIB族和VIIB族元素的酸性氧化物，以及费 - 托催化剂，其中沸石与费 - 托成分的比例为0.1-10:1 用于从合成气中生产汽油质量的液体烃。 使用的方法包括以下步骤：在上述催化剂中，在100℃至500℃的反应温度下，将氢气与碳氧化物的比例为0.1至10.0:1的合成气与 一个大气压（0.1MPa）至200个大气压（20MPa），气时空速为10至100,000。 还提供了用于制备组合催化剂的方法。 液体烃产物是高度芳族的，基本上不含外部烯烃，完全不含可检测的含氧化合物。
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2.发明公开Coated catalysts useful in the preparation of maleic anhydride, preparation thereof and use in the preparation of maleic anhydride 失效Trägerkatalysatorenfürdie Herstellung vonMaleinsäureanhydridund ihre Bereitung。
公开(公告)号：EP0072381A1
公开(公告)日：1983-02-23
申请号：EP81303776.9
申请日：1981-08-19
Applicant: THE STANDARD OIL COMPANY
Inventor： Dolhyj, Serge Roman , Pepera, Marc Anthony
CPC classification number: B01J23/22 , B01J23/002 , B01J27/198 , B01J2523/00 , C07C51/215 , C07C51/25 , C07C51/252 , C07C57/145 , B01J2523/397 , B01J2523/51 , B01J2523/55
Abstract: Catalysts particularly effective in the oxidation of n-butane, n-butenes, 1,3 butadiene and mixtures thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce maleic anhydride comprise an essentially inert, at least partially porous support to which is adhered on its outer surface, catalytically active mixed oxides of vanadium and phosphorus or of vanadium, phosphorus and uranium in an amount greater than 50% to about 80% by weight of the combined support and active oxide.
Abstract translation: 催化剂特别有效地在气相中氧化正丁烷，正丁烯，1,3-丁二烯及其与分子氧或含氧气体的混合物以产生马来酸酐，包括基本上惰性的至少部分多孔的载体 其附着在其外表面上，钒和磷或钒，磷和铀的催化活性混合氧化物的量大于组合的载体和活性氧化物的50重量％至约80重量％。
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3.发明授权Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate 失效用于乙烯生产乙酸乙烯酯的乙酰氧基化的流化床方法
公开(公告)号：EP0685449B1
公开(公告)日：1999-08-18
申请号：EP95301021.2
申请日：1995-02-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Benkalowycz, Nancy Christofferson , Blum, Patricia Rae , Paparizos, Christos , Cirjak, Larry Michael , Pepera, Marc Anthony , Lemanski, Michael Francis , Wagner, David Rudolph
IPC: C07C67/05 , C07C67/055
CPC classification number: B01J19/002 , B01J8/24 , B01J8/32 , B01J8/388 , C07C67/055 , C07C69/01 , C07C69/15
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4.发明授权
公开(公告)号：EP0072381B1
公开(公告)日：1985-03-06
申请号：EP81303776.9
申请日：1981-08-19
Applicant: THE STANDARD OIL COMPANY
Inventor： Dolhyj, Serge Roman , Pepera, Marc Anthony
CPC classification number: B01J23/22 , B01J23/002 , B01J27/198 , B01J2523/00 , C07C51/215 , C07C51/25 , C07C51/252 , C07C57/145 , B01J2523/397 , B01J2523/51 , B01J2523/55
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公开(公告)号：EP0518548B1
公开(公告)日：1996-11-06
申请号：EP92305076.9
申请日：1992-06-03
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Pepera, Marc Anthony
IPC: C07C53/08 , C07C51/215 , B01J27/195
CPC classification number: C07C51/215 , B01J23/002 , B01J23/22 , B01J27/198 , B01J2523/00 , C07C53/08 , B01J2523/51 , B01J2523/55 , B01J2523/74
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Patent Agency Ranking6.发明公开
公开(公告)号：EP0672453A2
公开(公告)日：1995-09-20
申请号：EP95301022.0
申请日：1995-02-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Cirjak, Larry Michael , Lemanski, Michael Francis , Paparizos, Christos , Pepera, Marc Anthony , Suresh, Devasirvatham Dhanarah
CPC classification number: B01J23/63 , B01J21/08 , B01J23/44 , B01J23/52 , B01J23/56 , B01J23/58 , B01J35/08 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0045 , C07C67/055 , C07C69/01 , C07C69/15
Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm³/g and the surface area is from 100 to 200 m²/g.
Abstract translation: 一种用于在流化床乙酸乙烯酯的制备方法，（VAM）催化剂，包含浸渍载体，其包含基本上惰性的微球颗粒的混合物与溶液包含钯和M，worin M包括钡，金，镧一个无卤化物金属盐 ，铌，铈，锌，铅，钙，锶，锑或它们的混合物，还原金属盐以形成钯和M的支撑表面上的沉积物和与至少一种无卤化物的碱金属盐浸渍载体。 用于微球形载体颗粒的至少50％具有低于100微米的粒度，优选低于60微米。 论文颗粒的孔体积为0.2至0.7厘米<3> /克，表面积为100至200m <2> / g以下。
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7.发明授权Synthesis of molecular sieving metallosilicates using silica-transition metal oxide sols 失效使用二氧化硅 - 过渡金属氧化物溶胶分子筛金属化合物的合成
公开(公告)号：EP0183391B1
公开(公告)日：1993-02-03
申请号：EP85307762.6
申请日：1985-10-28
Applicant: THE STANDARD OIL COMPANY
Inventor： Pepera, Marc Anthony , Callahan, James Louis , Desmond, Michael Joseph
CPC classification number: C01B33/2884 , B01J29/04 , C01B33/2876
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8.发明公开
公开(公告)号：EP0672453A3
公开(公告)日：1996-01-17
申请号：EP95301022.0
申请日：1995-02-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Cirjak, Larry Michael , Lemanski, Michael Francis , Paparizos, Christos , Pepera, Marc Anthony , Suresh, Devasirvatham Dhanarah
CPC classification number: B01J23/63 , B01J21/08 , B01J23/44 , B01J23/52 , B01J23/56 , B01J23/58 , B01J35/08 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0045 , C07C67/055 , C07C69/01 , C07C69/15
Abstract: A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns. The pore volume of these particles is from 0.2 to 0.7cm³/g and the surface area is from 100 to 200 m²/g.
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公开(公告)号：EP0685451A1
公开(公告)日：1995-12-06
申请号：EP95301023.8
申请日：1995-02-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Blum, Patricia Rae , Cirjak, Larry Michael , Lemanski, Michael Francis , Paparizos, Christos , Pepera, Marc Anthony
CPC classification number: B01J23/63 , B01J23/44 , B01J23/52 , B01J23/58 , B01J23/89 , B01J37/0036 , B01J37/0072 , B01J37/0205 , C07C67/055 , C07C69/01 , C07C69/15
Abstract: A process of producing a fluid bed oxacylation catalyst for olefins and diolefins having the following formula Pd-M-A where
M = Ba, Au, Cd, Bi, Cu, Mn, Fe, Co, Ce, U or mixtures thereof,
A = an alkali metal or mixture thereof, and
M is present in the range of from 0 to 5 wt%,
A is present in the range of greater than 0 to 10 wt%,
comprising milling a fixed bed oxacylation catalyst precursor comprising Pd-M on a fixed support with a fluid bed catalyst binder material to form a uniform slurry, drying the slurry to form microspheroidal particles of solid fluid bed catalyst precursor and optionally impregnating the microspheroidal particles with a solution of alkali metal salt to form the fluid bed catalyst. The catalyst is particularly useful in the manufacture of vinyl acetate from ethylene, acetic acid and oxygen.Abstract translation: 制备用于烯烃流化床氧酰化作用的催化剂和具有下式的Pd-MA二烯烃，其中M =钡，金，镉，铋，铜，锰，铁，钴，铈，U或其混合物，A =碱的方法 金属或它们的混合物，M是存在于从0到5重量％的范围内，A为存在于大于0至10重量％的范围内，包括研磨的固定床氧酰化作用的催化剂前体上的固定包含钯-M 与流化床催化剂粘合剂材料载体上以形成均匀的淤浆，干燥该浆料以形成固体流化床催化剂前体的微球状颗粒并任选地与碱金属的盐的溶液浸渍的微球状颗粒，以形成流化床催化剂。 该催化剂是在制造乙酸乙烯酯的由乙烯，乙酸和氧气是特别有用的。
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10.发明公开Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate 失效Fliessbett-Verfahren zur Acetoxylierung vonÄthylenzur Herstellung von Vinylacetat。
公开(公告)号：EP0685449A1
公开(公告)日：1995-12-06
申请号：EP95301021.2
申请日：1995-02-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Benkalowycz, Nancy Christofferson , Blum, Patricia Rae , Paparizos, Christos , Cirjak, Larry Michael , Pepera, Marc Anthony , Lemanski, Michael Francis , Wagner, David Rudolph
IPC: C07C67/05 , C07C67/055
CPC classification number: B01J19/002 , B01J8/24 , B01J8/32 , B01J8/388 , C07C67/055 , C07C69/01 , C07C69/15
Abstract: A fluid bed process for the manufacture of vinyl acetate from ethylene, acetic acid and oxygen comprising feeding ethylene and acetic acid into a fluid bed reactor through one or more inlets, introducing the oxygen into the reactor through at least one further inlet, co-joining the oxygen, ethylene and acetic acid in the reactor in contact with a fluid bed catalyst to produce vinyl acetate. The particle size diameter of the particulate catalyst material preferably has a range of 60% of the particles being below 200 microns (0.2 mm) with no more than 40% of the particles being below 40 microns (0.04 mm).
Abstract translation: 一种用于从乙烯，乙酸和氧气制造乙酸乙烯酯的流化床方法，包括通过一个或多个入口将乙烯和乙酸进料到流化床反应器中，通过至少一个另外的入口将氧引入反应器中，共连接 反应器中的氧气，乙烯和乙酸与流化床催化剂接触以产生乙酸乙烯酯。 颗粒催化剂材料的粒度直径优选具有小于200微米（0.2mm）的颗粒的60％的范围，不超过40％的颗粒低于40微米（0.04mm）。
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