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公开(公告)号：KR100407855B1
公开(公告)日：2004-03-24
申请号：KR1019980061775
申请日：1998-12-30
Applicant: 제일모직주식회사
Abstract: PURPOSE: A resin prepared by applying a pentaerythritol phosphonate and a fluorine resin to a rubber modified styrene-based resin is provided which is excellent in mechanical properties, heat resistance and flame retardancy. CONSTITUTION: A resin comprises (A) 100 parts by weight of a rubber modified styrene-based resin, (B) 5 to 50 parts by weight of pentaerythritol phosphonate of formula 1 and (C) 0.05 to 2.0 parts by weight of a fluorine resin, wherein the rubber modified styrene-based resin comprises 20 to 100% by weight of a styrene-containing graft copolymer resin and 80 to 0% by weight of a styrene-containing copolymer resin. In formula, R1,R2 are each independently C1-10 alkyl, C5-7 cycloalkyl, C2-10 alkenyl, phenyl, C7-10 phenylalkyl or C8-10 phenylalkenyl.
Abstract translation: 目的：提供一种通过将季戊四醇膦酸酯和氟树脂应用于橡胶改性的苯乙烯基树脂而制备的树脂，其具有优异的机械性能，耐热性和阻燃性。 （A）100重量份的橡胶改性的苯乙烯基树脂，（B）5至50重量份的式1的季戊四醇膦酸酯和（C）0.05至2.0重量份的氟树脂 其中橡胶改性的苯乙烯基树脂包含20至100重量％的含苯乙烯的接枝共聚物树脂和80至0重量％的含苯乙烯的共聚物树脂。 式中，R 1，R 2各自独立地为C 1-10烷基，C 5-7环烷基，C 2-10烯基，苯基，C 7-10苯基烷基或C 8-10苯基链烯基。
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公开(公告)号：KR100401326B1
公开(公告)日：2003-10-10
申请号：KR1020010031956
申请日：2001-06-08
Applicant: 제일모직주식회사
IPC: C08L55/02
CPC classification number: C08L77/06 , C08K5/06 , C08K5/1515 , C08K5/49 , C08L51/04 , C08L53/00 , C08L55/02 , C08L61/06 , C08L67/02 , C08L69/00 , C08L71/12 , C08L71/123 , C08L77/00 , C08L77/02 , C08L2666/02 , C08L2666/24 , C08L2666/14 , C08L61/04 , C08L71/00
Abstract: 본 발명의 난연성 열가소성 수지 조성물은 (A) 열가소성 수지 100 중량부; (B) 폴리페닐렌 에테르 수지 0.1 내지 100 중량부; (C) 하기 화학식 1로 표시되는 페놀수지 유도체 0.1 내지 100 중량부; (D) 인계 화합물 0.1 내지 50 중량부로 이루어지는 것을 특징으로 한다:
[화학식 1]
상기식에서, R
1 은 C
1 -C
34 사이의 알킬기, 아릴기, 또는 알킬기가 치환된 아릴기; 또는 산소(O), 질소(N), 인(P), 황(S) 등이 포함된 알킬기, 아릴기 또는 알킬기가 치환된 아릴기이고, R
2 , R
3 , R
4 는 각각 독립적으로 수소; C
1 -C
34 사이의 알킬기, 아릴기, 또는 알킬기가 치환된 아릴기; 또는 산소(O), 질소(N), 인(P), 황(S) 등이 포함된 알킬기, 아릴기, 또는 알킬기가 치환된 아릴기이며, n은 1-10000의 값을 가지며, 기계적 물성 및 가공성을 고려하여 1-300 정도를 사용하는 것이 바람직하다.Abstract translation: 本发明涉及含有聚苯醚树脂和酚醛树脂衍生物的阻燃热塑性树脂组合物，无论基础树脂如何，它们均具有良好的成焦性。 本发明的阻燃热塑性树脂组合物含有（A）作为基础树脂的热塑性树脂100重量份，（B）聚苯醚约0.1〜100重量份，（C）约0.1〜100重量份 （D）约0.1〜50重量份的磷化合物或磷化合物的混合物。 基于100重量份的基础树脂，热塑性树脂组合物可以含有至多5.0重量份的防滴剂。
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公开(公告)号：KR100396404B1
公开(公告)日：2003-09-02
申请号：KR1020000082552
申请日：2000-12-27
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic flame retardant resin composition and a product prepared by using the composition are provided, to improve the flame retardancy by employing copper compounds without adding char compounds. CONSTITUTION: The composition comprises 100 parts by weight of a rubber-modified styrene-acrylonitrile copolymer resin which comprises (a1) 20-90 wt% of a styrene-acrylonitrile grafted copolymer resin whose rubber content is 10-68 wt% and whose acrylonitrile content except the rubber component is 18-65 wt%, and (a2) 10-80 wt% of a styrene-acrylonitrile grafted copolymer resin whose acrylonitrile content is 18-65 wt%; 2-30 parts by weight of an aromatic phosphate ester compound; and 0.01-20 parts by weight of at least one copper compound selected from the group consisting of oxides, sulfides, chlorides, fluorides, phosphates, sulfates, nitrates and salts of organic acids including monovalent or divalent copper. Optionally the composition comprises further 0-60 parts by weight of a polyphenylene ether resin.
Abstract translation: 目的：提供一种热塑性阻燃树脂组合物和使用该组合物制备的产品，以通过使用铜化合物而不添加焦化合物来提高阻燃性。 构成：该组合物包含100重量份的橡胶改性苯乙烯 - 丙烯腈共聚物树脂，其包含（a1）20-90重量％的苯乙烯 - 丙烯腈接枝共聚物树脂，其橡胶含量为10-68重量％，其丙烯腈含量 （a2）10-80重量％的丙烯腈含量为18-65重量％的苯乙烯 - 丙烯腈接枝共聚物树脂; 2-30重量份的芳族磷酸酯化合物; 和0.01-20重量份的至少一种选自氧化物，硫化物，氯化物，氟化物，磷酸盐，硫酸盐，硝酸盐和包括一价或二价铜的有机酸的盐的铜化合物。 任选地，组合物还包含0-60重量份的聚苯醚树脂。
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公开(公告)号：KR1020010113326A
公开(公告)日：2001-12-28
申请号：KR1020000033619
申请日：2000-06-19
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08J2300/22 , C08K5/521 , C08L25/08 , C08L25/12 , C08L53/02 , C08L71/12 , C08L2201/02 , C08L2205/02 , C08L2205/035
Abstract: 본 발명은 (A) (a
1 ) 스티렌 함유 그라프트 공중합체 수지 20∼90 중량부, (a
2 ) 스티렌 함유 공중합체 수지 0∼80 중량부 및 (a
3 ) 스티렌계 수지 5∼40 중량부로 이루어지는 고무변성 스티렌계 수지 40∼95 중량부; (B) 폴리페닐렌에테르계 수지 5∼60 중량부; (C) 상기 기초수지 (A)+(B) 100 중량부에 대하여 아크릴로니트릴 함량이 5∼18 중량%인 스티렌-아크릴로니트릴 공중합체 수지 2∼30 중량부; (D) 상기 기초수지 (A)+(B) 100 중량부에 대하여 방향족 인산에스테르계 화합물 5∼30 중량부; 및 (E) 상기 기초수지 (A)+(B) 100 중량부에 대하여 스티렌-고무 블록 공중합체 0.5∼5 중량부로 이루어지는 열가소성 수지 조성물에 관한 것이다.-
公开(公告)号：KR1020010107434A
公开(公告)日：2001-12-07
申请号：KR1020000028997
申请日：2000-05-29
Applicant: 제일모직주식회사
IPC: C08L25/12
CPC classification number: C08L51/06 , C08J2300/22 , C08K5/523 , C08K5/5317 , C08L25/12 , C08L71/12 , C08L2205/02 , C08L2205/03
Abstract: 본 발명의 열가소성 수지 조성물은 (A) 고무변성 스티렌계 수지 40∼95 중량부, (B) 폴리페닐렌에테르계 수지 5∼60 중량부, (C) 상기 (A)+(B) 100 중량부에 대하여 아크릴로니트릴 함량이 5∼18 중량인 스티렌-아크릴로니트릴 공중합체 수지 2∼30 중량부, (D) 상기 (A)+(B) 100 중량부에 대하여 폴리스티렌 또는 고무강화 폴리스티렌 수지 5∼50 중량부, (E) 상기 (A)+(B) 100 중량부에 대하여 인산에스테르 화합물 5∼30 중량부, 및 (F) 상기 (A)+(B) 100 중량부에 대하여 포스포네이트계 화합물 0.01∼20 중량부로 이루어진다.
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Patent Agency Ranking
公开(公告)号：KR100289941B1
公开(公告)日：2001-09-17
申请号：KR1019980036004
申请日：1998-09-02
Applicant: 제일모직주식회사
Abstract: 본 발명은 고무변성 스티렌계 수지(a
1 ) 40~95중량% 및 폴리페닐렌에테르 수지(a
2 ) 60~5중량%로 이루어지는 기초수지(A) 100중량부에 대하여 아크릴로니트릴의 함량이 5~18중량%인 스티렌-아크릴로니트릴 공중합체(B) 2~20중량부, 융점이 90℃ 이상인 방향족 인산에스테르 화합물(C) 5~30중량부 및 페놀수지(D) 3~30중량부를 혼합하여 제조되는 난연성을 갖는 열가소성 수지조성물에 관한 것이다. 상기 고무변성 스티렌계 수지(a
1 )는 스티렌 함유 그라프트 공중합체 수지(a
11 ) 20~100중량% 및 스티렌 함유 공중합체 수지(a
12 ) 0~80중량%로 이루어진다. 본 발명의 수지조성물은 필요에 따라 적하방지제, 가소제, 열안정제, 산화방지제, 광안정제, 상용화제, 무기물 첨가제, 안료 및/또는 염료 등이 첨가될 수 있다.-
公开(公告)号：KR1020010083602A
公开(公告)日：2001-09-01
申请号：KR1020000007474
申请日：2000-02-17
Applicant: 제일모직주식회사
IPC: C08K5/49
Abstract: PURPOSE: A thermoplastic flame-retardant resin composition is provided to produce the resin composition excluding halogen compound causing environmental pollution and having improved mechanical property, thermal stability and flame-retardant ability by comprising specific oxaphosphorane-based compound as a flame-retardant agent. CONSTITUTION: The resin composition comprises (A) 40-95 part by weight of rubber modified styrene resin composed of 20-100wt.% of styrene containing grafted copolymer resin(a1) and 80-0wt.% of another styrene containing copolymer resin(a2); (B) 5-60 part by weight of polyphenylene ether resin as a basic resin(A)+(B) in total 100 part by weight. The composition also includes 2-30 part by weight of styrene containing copolymer resin containing 5-18wt% of acrylonitrile. The composition further contains 0.5-20 part by weight of oxaphosphorane base compound having the following formula(1) (wherein R1 is hydrogen or C1-C4 alkyl group or C6-C10 aryl group; R2 and R3 are hydrogen, C1-C4 alkyl group and n is 1-3) 0-30 part by weight of phosphoric ester compound having the formula(2) (wherein R4, R5 and R6 are independently hydrogen or C1-C4 alkyl group; X is C6-C20 aryl group substituted or not substituted by alkyl group; and m is 0-4).
Abstract translation: 目的：提供一种热塑性阻燃树脂组合物，其通过包含特定的氧化磷酰基系化合物作为阻燃剂，制造除了卤素化合物引起环境污染且具有改善的机械性能，热稳定性和阻燃性的树脂组合物。 构成：树脂组合物包含（A）40-95重量份由20-100重量％的含苯乙烯接枝共聚物树脂（a1）和80-0重量％的另一种含苯乙烯共聚物树脂（a2）组成的橡胶改性苯乙烯树脂 ）; （B）5-60重量份作为碱性树脂（A）+（B）的聚苯醚树脂总计100重量份。 该组合物还包括2-30重量份含有5-18重量％丙烯腈的含苯乙烯的共聚物树脂。 该组合物还含有0.5-20重量份具有下式（1）的氧化磷酰基碱化合物（其中R 1是氢或C 1 -C 4烷基或C 6 -C 10芳基; R 2和R 3是氢，C 1 -C 4烷基 和n为1-3）0-30重量份具有式（2）的磷酸酯化合物（其中R 4，R 5和R 6独立地为氢或C 1 -C 4烷基; X为未被取代的C 6 -C 20芳基） 被烷基取代; m为0-4）。
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公开(公告)号：KR1020010009104A
公开(公告)日：2001-02-05
申请号：KR1019990027281
申请日：1999-07-07
Applicant: 제일모직주식회사
IPC: C08L69/00
CPC classification number: C08L69/00 , C08K5/523 , C08L25/12 , C08L27/12 , C08L51/04 , C08L51/00 , C08L2666/02
Abstract: PURPOSE: A thermoplastic resin composition comprising polycarbonate resin, a rubber modified graft copolymer, a vinyl based copolymer, a mixture of a polyphosphate compound derived from bisphenol A and a monophosphate ester compound and fluorinated polyolefin is provided, which has excellent heat stability during processing and is well balanced between excellent flame retardancy and impact resistance. CONSTITUTION: The resin composition comprises (A) 45 to 99 parts by weight of thermoplastic resin without containing halogen, (B) 1 to 50 parts by weight of a styrene based graft copolymer, (C) 0 to 50 parts by weight of a vinyl based copolymer or mixtures thereof, (D) 0.5 to 20 parts by weight of a mixture compound of 10 to 50% by weight of a polyphosphate compound of formula (I) and 90 to 50% by weight of a monophosphate compound of formula (II) based on 100 parts by weight of the composition (A) + (B) + (C) and (E) a flame retardant. In formula, R1, R2, R4 and R5 are each C6-20 aryl or alkyl substituted C6-C20 aryl; R3 is bisphenol-A derivatives and M represents an integer of more than 1.
Abstract translation: 目的：提供一种热塑性树脂组合物，其包含聚碳酸酯树脂，橡胶改性接枝共聚物，乙烯基类共聚物，衍生自双酚A的多磷酸盐化合物与单磷酸酯化合物和氟化聚烯烃的混合物，其在加工过程中具有优异的热稳定性， 在优异的阻燃性和耐冲击性之间具有良好的平衡性。 构成：树脂组合物包含（A）45〜99重量份的不含卤素的热塑性树脂，（B）1〜50重量份苯乙烯系接枝共聚物，（C）0〜50重量份乙烯基 （D）0.5〜20重量份10〜50重量％的式（I）的聚磷酸酯化合物和90〜50重量％的式（II）的一磷酸化合物的混合物， ）基于100重量份的组合物（A）+（B）+（C）和（E）阻燃剂。 在式中，R 1，R 2，R 4和R 5各自为C 6-20芳基或烷基取代的C 6 -C 20芳基; R3是双酚A衍生物，M表示大于1的整数。
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公开(公告)号：KR1020000018424A
公开(公告)日：2000-04-06
申请号：KR1019980036005
申请日：1998-09-02
Applicant: 제일모직주식회사
CPC classification number: C08L51/06 , C08J2300/22 , C08K5/527 , C08L53/02 , C08L61/06 , C08L71/12 , C08L2201/02 , C08L2201/22 , C08L2205/035
Abstract: PURPOSE: The thermoplastic resin having fire retardancy is provided by the compositions of the basic resin (A) to be formed from rubber modified styrene resin (a1) and polyphenylenether resin (a2); commercialization substance (B) like styrene-acrylonitrile copolymer and block copolymer of polystyrene; phosphoric ester compound (C) like aromatic phosphate; and phenol resin (D), which has the excellent characters of a hard-combustion, a heat-resistance, and the mechanics; has no a poisonous gas during process and combustion of resin; and has no the occurrence of an environmental pollution because of adding nothing of a halogen compound. CONSTITUTION: The composition a hard-combustible, thermoplastic resin consists of the followings: (A) the basic resin to be formed from (a1) rubber modified styrene resin 40 to 95 weight % and (a2) polyphenylenether resin 60 to 5 weight %; (B) 2 to 20 weight % of styrene-acrylonitrile copolymer and block copolymer of polystyrene; (C) aromatic phosphate compound 5 to 30 weight % having the melting point of 90°C or above and having the following structural formula 1 or 2; and (D) phenol resin 3 to 30 weight % as against (A) the basic resin 100 weight %.
Abstract translation: 目的：具有阻燃性的热塑性树脂是由橡胶改性苯乙烯系树脂（a1）和多苯基树脂（a2）形成的基础树脂（A）的组成提供的。 商品化物质（B），如苯乙烯 - 丙烯腈共聚物和聚苯乙烯嵌段共聚物; 磷酸酯化合物（C）如芳族磷酸酯; 和酚醛树脂（D），其具有优异的硬燃烧特性，耐热性和力学性能; 在树脂的加工和燃烧过程中没有有毒气体; 并且由于不添加卤素化合物而没有发生环境污染。 构成：可燃性热塑性树脂组合物由以下组成：（A）由（a1）橡胶改性苯乙烯树脂40〜95重量％形成的基础树脂和（a2）多苯基树脂60〜5重量％ （B）苯乙烯 - 丙烯腈共聚物2〜20重量％和聚苯乙烯嵌段共聚物; （C）熔点为90℃以上且具有以下结构式1或2的5〜30重量％的芳族磷酸酯化合物; 和（D）酚醛树脂，相对于（A）100重量％的碱性树脂，为3〜30重量％。
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公开(公告)号：KR1020000008555A
公开(公告)日：2000-02-07
申请号：KR1019980028430
申请日：1998-07-14
Applicant: 제일모직주식회사
CPC classification number: C08L69/00 , C08J2300/22 , C08K5/521 , C08K5/523 , C08L25/12 , C08L55/02 , C08L2201/02 , C08L2201/08
Abstract: PURPOSE: A composition comprising polycarbonate resin, rubber denatured graft copolymer, vinyl copolymer, specific phosphorous oligomer derived from bisphenol-A. and fluorinated polyolefin is provided which stress-crack resistance, heat stability and anti shocking property. CONSTITUTION: The composition comprises (A)45-95 wt. parts of thermoplastic carbonate resin,; 5-95 wt. parts of monomer mixture of (B)50-95 wt. parts of (B-1)(B-1.1) styrene, alpha-methylstyrene, halogen or methyl ring-substituted styrene, C1-C8 methacrylic acid ester, anhydrous malefic acid, C1-C4 alkyl or its mixture, and 5-50 wt. parts of (B-1.2) acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkylester, C1-C8 methacrylic acid ester, anhydrous maleic acid, C1-C4 alkyl or phenyl N-substituted maleimide or its mixture; 5-95 wt. parts of monomer mixture of 1-50 wt. parts of butadiene rubber, acrylic rubber, ethylene/propylene rubber, styrene/butadiene rubber, acrylonitrile/butadiene rubber, isoprene rubber, terpolymer(EPDM) of ethylene-propylene-diene, polyorganosiloxane/polyalkyl(metha)acrylate rubber composite; (C)50-95 wt, parts of (C-1)styrene, alpha-methylstyrene,, ring-substituted styrene, C1-C8 methacrylic acid alkylester, C1-C8 methacrylic acid ester, or its mixture. The composition is useful as a computer housing and other office instruments
Abstract translation: 目的：包含聚碳酸酯树脂，橡胶变性接枝共聚物，乙烯基共聚物，衍生自双酚A的特定磷低聚物的组合物。 并提供耐应力开裂性，热稳定性和抗冲击性的氟化聚烯烃。 构成：组合物包含（A）45-95重量％ 部分热塑性碳酸酯树脂; 5-95重量％ 部分单体混合物（B）50-95wt。 部分（B-1）（B-1.1）苯乙烯，α-甲基苯乙烯，卤素或甲基环取代的苯乙烯，C1-C8甲基丙烯酸酯，无水马来酸，C 1 -C 4烷基或其混合物，和5-50重量份 。 （B-1.2）丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯，C1-C8甲基丙烯酸酯，无水马来酸，C 1 -C 4烷基或苯基N-取代马来酰亚胺或其混合物的部分; 5-95重量％ 单体混合物的1-50wt。 丁二烯橡胶，丙烯酸橡胶，乙烯/丙烯橡胶，苯乙烯/丁二烯橡胶，丙烯腈/丁二烯橡胶，异戊二烯橡胶，乙烯 - 丙烯 - 二烯的三元共聚物（EPDM），聚有机硅氧烷/聚烷基（甲基）丙烯酸酯橡胶复合材料; （C）50-95重量份（C-1）苯乙烯，α-甲基苯乙烯，环取代苯乙烯，C1-C8甲基丙烯酸烷基酯，C1-C8甲基丙烯酸酯或其混合物。 该组合物可用作计算机外壳和其他办公用品
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