Abstract:
본 발명은 암모니아수 흡수용액을 이용하여 연소배가스로부터 이산화탄소를 선택적으로 흡수하기 위한 흡수탑; 상기 흡수탑에서 유출되는 암모니아를 세정하기 위한 세정탑; 이산화탄소가 흡수된 암모니아수로부터 이산화탄소를 고압에서 탈거시키기 위한 이산화탄소 탈거탑; 및 세정탑에서 생산된 세정탑-배출 암모니아수를 암모니아 기체와 물로 분리하는 암모니아 회수탑을 사용하는 이산화탄소 포집 방법에 있어서, 상기 흡수탑에서 증발하는 암모니아를 세정탑으로 공급하여 세정수로 세정한 후 암모니아 회수탑으로 이송하고, 상기 암모니아 회수탑에서 가열을 통해 생성된 수증기/암모니아 혼합 기체를 상기 암모니아 회수탑의 상단에 위치하는 열교환 부분 응축기로 이송하고, 상기 열교환 부분 응축기에서 수증기는 응축시켜 암모니아 회수탑으로 재순환시키며 회수 암모니아 기체는 암모니아 기체 이송관을 통해 흡수탑으로 재순환시키는 것을 특징으로 하는, 암모니아수 흡수용액을 사용하는 개선된 이산화탄소 포집 방법 및 상기 방법을 구현하는 장치를 제공한다.
Abstract:
PURPOSE: A sulfones separation process using two-step absorption which uses methanol as polar solvent is provided to minimize operation cost and energy consumed in the separation during a process of separating sulfones from fraction containing sulfones. CONSTITUTION: Diesel containing sulfones is passed through absorber and then sulfones is absorbed in the absorber. A polar solvent is supplied to the absorber, and the absorber is recycled by dissolving and dissembling the sulfones absorbed in the absorber with the polar solvent. The polar solvent, by which the sulfones is dissolved, is passed through active carbon, and the polar solvent is recycled by absorbing and separating the sulfones dissolved in the polar solvent with the active carbon. Hydrocarbon is supplied to the active carbon in which the sulfones is absorbed, and thus the sulfones is separated from the active carbon. The sulfones is separated and collected from the hydrocarbon by distilling the hydrocarbon in which the sulfones is included. The absorber uses acidified silica. The polar solvent uses methanol. The active carbon is made by increasing surface polarity by activating carbon powder, whose pore size is 0.3-0.6 nm, in the temperature of 800 - 1000°C for 4-6 hours as supplying CO2. [Reference numerals] (AA) Ultra low sulfur diesel; (BB) Polar solvent; (CC) Hydrocarbon; (DD) Adsorption or extraction; (EE) Adsorption of activated carbon; (FF) Distillation; (GG) Diesel with sulfur oxides; (HH) Sulfur oxides/polar solvent; (II) Sulfur oxides/hydrocarbon; (JJ) Sulfur oxides
Abstract:
PURPOSE: A capturing method of carbon dioxide and device thereof are provided to reduce the compressing cost for transferring ammonia gas, which is collected in an ammonia solution process in which the high pressure carbon dioxide is collected, to the removing tower of high pressure carbon dioxide, thereby increasing the collect rate of ammonia and the removal rate of carbon dioxide in the absorptive tower. CONSTITUTION: A capturing method of carbon dioxide uses an absorptive tower(3), a washing tower(13), a carbon dioxide removing tower(6), and an ammonia collecting tower(15). The absorptive tower selectively absorbs carbon dioxide from the combustion gas by using ammonia absorptive solution. The carbon dioxide removing tower removes the carbon dioxide from the ammonia solution, in which the carbon dioxide is absorbed, at high pressure. The ammonia collecting power separates the ammonia solution produced in the washing tower into the ammonia gas and water. The ammonia evaporating in the absorptive tower is supplied to the washing tower, is washed with cleaning water, and is transferred to the collecting tower. Vapor and ammonia gas mixture produced by being heated in the ammonia collecting tower are transferred to a heat exchanging partial condenser which is located on the top of the ammonia collecting tower. Vapor is condensed in the heat exchanging partial condenser and is recycled into the ammonia collecting tower, and the ammonia gas is recycled to the absorptive tower through an ammonia gas transferring pipe. [Reference numerals] (2) Combustion exhaust gas
Abstract:
PURPOSE: A reactor for manufacturing a semiconductor thin film and a manufacturing method are provided to secure a uniform thin film. CONSTITUTION: An inner container(120) is inserted into the inner space of an outer container(110). A substrate(200) is placed on the bottom surface of the inner container. A cover(130) for the inner container is prepared. An O-ring(140) is formed between the cover and the inner container. An optical unit(150) irradiates light to the substrate.
Abstract:
PURPOSE: Chlorella N113 with an excellent carbon dioxide fixation ability is provided to effectively remove carbon dioxide and to produce biodiesel. CONSTITUTION: A method for fixing carbon dioxide comprises a step of fixing carbon dioxide contained in coal-fired exhaust gas into Chlorella sp. N113. The coal-fired exhaust gas contains 10-20 wt% of carbon dioxide, 100-300 ppm of CO, 150-350 ppm of SOX, 150-350 ppm of NOX, and 5-15 mg/m^3 of dust. [Reference numerals] (AA) Air(0.035%); (BB) Synthetic CO_2(10%); (CC) Coal exhaust gas(CO_2 ~15%); (DD) KCTC strain 46 kinds + KR-1; (EE) KCTC strain 24 kinds + KR-1; (FF) KCTC strain 16 kinds + KR-1; (GG) Strain with superior CO_2 and temperature resistance
Abstract:
PURPOSE: An adsorbent for removing sulfur compounds in a C4 hydrocarbon mixture from a fluidized catalytic cracking process and a preparation method thereof are provided to increase the absorption amount of the absorbent. CONSTITUTION: An adsorbent for removing sulfur compounds in a C4 hydrocarbon mixture from a fluidized catalytic cracking process is zeolite having cation substituted with a transition metal. The transition metal is Ag(I) or Cu(I). The zeolite is one selected from a group including zeolite X, zeolite Y, beta-zeolite, and ultrastable Y. The ratio of SiO_2 to Al_2O_3 in the zeolite is in a range between 0.5 and 360. [Reference numerals] (AA) DMDS concentration; (BB) Time; (CC) Example 1; (DD) Example 2; (EE) Example 3
Abstract:
본 발명은 탄산칼슘과 칼슘산화물을 연소장치의 적절한 위치에 투입해서 전체 시스템의 효율을 향상시킨 화학적 열회수 방법을 이용한 순산소 연소시스템에 관한 것이다. 이러한 본 발명의 화학적 열회수 방법을 이용한 순산소 연소시스템은 산소를 조연제로 이용하는 순산소 연소장치에 있어서, 연소장치 하부의 산소가 연소되는 산소연소실로 공급되는 산소를 예열하며, 이산화탄소와 반응하여 열을 발생시키는 칼슘산화물이 저장된 예열기를 설치하여 구성되고, 상기 연소장치 상부의 연료가 연소되는 연료연소실이 과열되는 것을 방지하기 위해 연료연소실에 분해과정에서 열을 흡수하는 탄산칼슘이 공급됨을 특징으로 한다.
Abstract:
본 발명은 (S1) 생물체로부터 유래된 재생가능한 공급원으로부터 얻어지는 트리글리세라이드, 지방산 및 지방산 유도체 중 선택된 1종 이상인 원료물질을 제1 반응기에 공급한 후 하이드로탈사이트 촉매와 접촉시켜 탄화수소를 제조하는 반응 단계; (S2) 상기 제1 반응기 내 반응 종료 후 사용한 하이드로탈사이트를 재생시키는 촉매 재생 단계; (S3) 상기 하이드로탈사이트의 재생 동안 상기 원료물질을 제2 반응기에 공급한 후 하이드로탈사이트 촉매와 접촉시켜 탄화수소를 제조하는 반응 단계; 및 (S4) 상기 제2 반응기 내 반응 종료 후 사용한 하이드로탈사이트를 재생시키는 촉매 재생 단계를 포함하고, S1 내지 S4 단계를 반복 수행하되, S4 단계를 수행하면서 S1 단계를 동시에 수행하는 방식으로 반복 수행하는 것을 특징으로 하는 생물체에서 유래된 지질과 하이드로탈사이트를 이용하는 연속적인 탄화수소 생산 방법 및 그 장치에 관한 것이다. 본 발명에 따르면, 재생 가능한 하이드로탈사이트 촉매를 사용하여 사용된 촉매를 재사용할 수 있다는 측면에서도 경제적 효과를 제공할 수 있다. 본 발명에 따르면, 2 이상의 반응기를 사용하여 생물체로부터 유래된 원료물질과 하이드로탈사이트 촉매의 반응 및 하이드로탈사이트 촉매의 재생을 반복함으로써 탄화수소를 연속적으로 대량 제조할 수 있어 상업화에 적합하다.
Abstract:
PURPOSE: A composition for absorbing carbon dioxide, a composition for improving the absorbing speed of carbon dioxide and suppressing the evaporation of ammonia, and a method for the same are provided to improve the purify of collected carbon dioxide gas and reducing the discharge of ammonia from treated mixed gas. CONSTITUTION: A composition for absorbing carbon dioxide includes an amine-based additive and ammonia water. The ammine-based additive is capable of being a compound containing two or more amine groups. The amine-based additive is capable of being a heterocyclic compound containing a secondary or tertiary amine group in a ring structure. The amine-based additive is capable of being a compound substituted with a primary amine, secondary amine, tertiary amine, or hydroxyl group. The amine-based additive is capable of being selected from 2-hydroxyl ethyl piperazine, homopiperazine, 1-methylpiperazine, 2-methylpiperazine, 1,4-dimethylpiperazine, 1,4-bis(2-hydroxyethyl)piperazine, 1-(2-aminoethyl)piperazine, 2-piperazine-1-ethanol, and a combination of the same. The amine-based additive is capable of being selected from a group including triethylene triamine, triethylene tetraamine, and the combination of the same.
Abstract:
PURPOSE: A collecting method of lipids from microalgae is provided to effectively collect lipids among various components in microalgae by simple processes, and to manufacture a part of pure hydrocarbon consisting of only carbon and hydrogen by decomposing lipids during thermal decomposition. CONSTITUTION: A collecting method of lipids from microalgae comprises a step of primary thermal-decomposing microalgae biomass at 250-400 °C; a step of removing saccharides and proteins from the microalgae biomass; and a step of obtaining primary decomposed product; a step of secondary decomposing the primary decomposed product and collecting only lipids, which are able to be converted to fuel easily.