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公开(公告)号：KR1020130054312A
公开(公告)日：2013-05-24
申请号：KR1020130052647
申请日：2013-05-09
Applicant: 한국에너지기술연구원
Abstract: PURPOSE: A method for manufacturing raw oil for biodiesel and a method for manufacturing the biodiesel using the raw oil are provided to effectively remove phospholipid from oil obtained from biomass and to raise the yield rate of the raw oil. CONSTITUTION: A method for manufacturing raw oil for biodiesel includes: a step of removing solid matters from oil obtained from biomass containing the oil and fat; a step of determining the amounts of a sulfuric acid catalyst and methanol using a central composite design based on a response surface method; and a step of esterifying the oil without degumming under a condition in which the sulfuric acid catalyst and the methanol exist with the determined amounts in order to remove phospholipid and free fatty acid from the oil below a predetermined content. The biomass from gum tree is a tropical crop containing over 40 ppm of the phospholipid. A reaction system includes below 0.6 to 1.0 percentages of the sulfuric acid catalyst against the weight of the oil according to the central composite design based on the response surface method. The reaction system includes 20 to 30 percentages of the methanol against the weight of the oil, and the content of the phospholipid removed through esterification is 10 ppm or less. [Reference numerals] (S300) Remove solid matters; (S302) Esterify; (S304) Remove methanol and moisture; (S306) Transesterify
Abstract translation: 目的：提供生物柴油原油的制造方法以及使用该原料油的生物柴油的制造方法，从生物质中获得的油中有效地除去磷脂，提高原油的成品率。 构成：生产生物柴油的原料的方法包括：从含有油脂的生物质中得到的油中除去固体物质的步骤; 基于响应面法使用中心复合设计确定硫酸催化剂和甲醇的量的步骤; 以及在硫酸催化剂和甲醇以确定的量存在的条件下不脱胶而酯化油的步骤，以便从低于预定含量的油中除去磷脂和游离脂肪酸。 来自树胶树的生物量是含有超过40ppm磷脂的热带作物。 基于响应面法，反应体系根据中心复合设计，包含0.6至1.0％的硫酸催化剂与油的重量。 反应体系含有20-30％的甲醇与油的重量，通过酯化除去的磷脂的含量为10ppm以下。 （附图标记）（S300）去除固体物质; （S302）酯化; （S304）除去甲醇和水分; （S306）酯交换
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公开(公告)号：KR1020130022112A
公开(公告)日：2013-03-06
申请号：KR1020110084879
申请日：2011-08-25
Applicant: 한국에너지기술연구원
Abstract: PURPOSE: A photo-bioreator with a carbon dioxide mixing and guiding device, and a method for culturing microalgae using the same are provided to enhance photosynthesis efficiency by activating the mixture of carbon dioxide with the microalgae in a chamber. CONSTITUTION: A photo-bioreactor with a carbon dioxide mixing and guiding device comprises a chamber(1), a carbon dioxide supply unit(2), an oxygen discharge unit(3), and the carbon dioxide mixing and guiding device. The chamber has a cover(11) at the upper portion, and contains microalgae and a culture medium. The carbon dioxide supply unit supplies carbon dioxide into the chamber. The oxygen discharge unit discharges oxygen generated from the carbon dioxide inside the chamber through the photosynthesis of the microalgae. The carbon dioxide mixing and guiding device induces the mixture of the carbon dioxide and the microalgae.
Abstract translation: 目的：提供一种具有二氧化碳混合和引导装置的光生物反应器，以及使用其的微藻培养方法，以通过在室中活化二氧化碳与微藻的混合物来提高光合作用效率。 构成：具有二氧化碳混合引导装置的光生物反应器包括室（1），二氧化碳供应单元（2），氧气排放单元（3）和二氧化碳混合引导装置。 该室在上部具有盖（11），并且包含微藻和培养基。 二氧化碳供应单元向室提供二氧化碳。 氧气放电单元通过微藻的光合作用来释放室内二氧化碳产生的氧气。 二氧化碳混合引导装置引起二氧化碳和微藻的混合物。
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93.发明公开바이오디젤 생산을 위한 전처리 반응에서 발생한 메탄올과 산 촉매의 혼합용액으로부터 메탄올을 회수하는 방법 및 회수된 메탄올을 재활용하는 방법 有权甲磺酸从生产生物柴油预反应生成甲醇和酸催化剂的混合溶液中的回收方法及回收甲醇的再利用方法
公开(公告)号：KR1020120078274A
公开(公告)日：2012-07-10
申请号：KR1020100140521
申请日：2010-12-31
Applicant: 한국에너지기술연구원
CPC classification number: Y02E50/13 , Y02P20/582 , Y02P30/20
Abstract: PURPOSE: A collecting method of methanol of specific purity from mixed solution is provided to obtain methanol of high purity by only distilling method because of using mixed solution of methanol, and acid catalyst as a base raw material generated from pretreatment method for manufacturing biodiesel. CONSTITUTION: A collecting method of methanol of specific purity from mixed solution comprises: a step of pretreatment reaction after adding methanol and acid catalyst to vegetable or animal fats and fatty oils; a step of separating mixed solution of the methanol and the acid catalyst in an upper layer, and pretreated fats or fatty oil in a lower layer; and a step of supplying mixed solution of the separated the mixed solution to a vaporizer, vaporizing the mixed solution by heating under the temperature condition of 30-75 °C and the pressure condition of 200-800mbar, and obtaining condensed methanol by passing vaporized materials into one or more condensers.
Abstract translation: 目的：提供从混合溶液中提取特定纯度的甲醇的收集方法，因为使用甲醇混合溶液和酸催化剂作为生产生物柴油预处理方法生成的基础原料，仅通过蒸馏法获得高纯度甲醇。 构成：从混合溶液中收集特定纯度的甲醇的收集方法包括：向蔬菜或动物脂肪和脂肪油中加入甲醇和酸催化剂后的预处理反应步骤; 在上层分离甲醇和酸催化剂的混合溶液，在下层中分离预处理的脂肪或脂肪油的步骤; 将分离的混合溶液的混合溶液供给到蒸发器的步骤，在30-75℃的温度条件和200-800mbar的压力条件下加热蒸发混合溶液，并通过蒸发的材料获得冷凝的甲醇 进入一个或多个电容器。
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94.发明公开유사 다단 ＣＳＴＲ반응기 및 연속식 메탄올 회수장치를이용한 단일 단계 연속식 바이오디젤 제조 방법 및 그 장치 有权单阶段生物多样性生产方法多阶段连续搅拌罐反应器和连续甲醇回收设备及其设备
公开(公告)号：KR1020090064714A
公开(公告)日：2009-06-22
申请号：KR1020070132017
申请日：2007-12-17
Applicant: 한국에너지기술연구원
Abstract: A method for manufacturing the single step continuation type biodiesel by using a pseudo-multistage CSTR reactor and a continuous methanol collection device, and its apparatus are provided to reduce the cost for equipment and to decrease the energy cost by collecting the unreacted alcohol. A method for manufacturing the single step continuation type biodiesel by using a pseudo-multistage CSTR reactor and a continuous methanol collection device comprises the steps of mixing a catalyst solution comprising a homogeneous basic catalyst dissolved in an alcohol and a preheated animal or vegetable oil to supply continuously to the lower end of a pseudo-multistage CSTR reactor(4) constituted with a single reactor with stirring for transesterification; transferring the produced mixture such as glycerin, fatty acid alkyl ester and unreacted alcohol to a continuous evaporator of the reduced pressure state with the same flux, thereby collecting the unreacted alcohol; transferring the glycerin phase and the fatty acid ester phase to a separator to separate them; and transferring the separated glycerin phase to a glycerin processing equipment and transferring the fatty acid ester phase to a washing process to wash it, to remove moisture and to filter it to produce biodiesel.
Abstract translation: 通过使用伪多级CSTR反应器和连续甲醇收集装置制造单步连续型生物柴油的方法及其装置，以减少设备成本并通过收集未反应的醇来降低能量成本。 通过使用假多级CSTR反应器和连续甲醇收集装置制造单级连续型生物柴油的方法包括以下步骤：将包含溶解在醇中的均匀碱性催化剂和预热动物或植物油的催化剂溶液混合以供应 连续地连接到由具有搅拌进行酯交换反应的单个反应器构成的假多级CSTR反应器（4）的下端; 将产生的混合物如甘油，脂肪酸烷基酯和未反应的醇转移到具有相同通量的减压状态的连续蒸发器中，从而收集未反应的醇; 将甘油相和脂肪酸酯相转移到分离器中以分离它们; 并将分离的甘油相转移到甘油加工设备中并将脂肪酸酯相转移到洗涤过程中以洗涤，除去水分并过滤以产生生物柴油。
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公开(公告)号：KR100782127B1
公开(公告)日：2007-12-05
申请号：KR1020060004036
申请日：2006-01-13
Applicant: 한국에너지기술연구원
IPC: C10G3/00
CPC classification number: Y02P30/20
Abstract: 본 발명은 이온성 액체 촉매를 이용한 오일 중의 유리지방산의 제거방법에 관한 것으로서 보다 상세하게는 이온성 액체 촉매 존재하에서 알콜과 유리지방산을 함유하는 오일을 에스테르화 반응시켜 오일 중에 포함된 유리지방산의 제거방법에 관한 것이다.
본 발명은 이온성 액체 촉매 존재하에서 알콜과 유리지방산을 함유하는 오일을 에스테르화 반응(esterification reaction)시켜 유리지방산을 바이오디젤유의 주요성분인 에스테르로 전환시켜 바이오디젤유 제조 원료유에 포함된 불순물인 유리지방산을 제거하는 방법을 제공할 수 있다.-
Patent Agency Ranking
公开(公告)号：KR1020070074807A
公开(公告)日：2007-07-18
申请号：KR1020060002813
申请日：2006-01-10
Applicant: 한국에너지기술연구원
CPC classification number: B01J21/066 , B01J23/30 , B01J35/026 , B01J2523/48
Abstract: A tungsten oxide zirconia catalyst and a method for removing a free fatty acid contained in oil using the same are provided to improve the activity of the tungsten oxide zirconia catalyst in removing the free fatty acid from waste oil. A tungsten oxide zirconia catalyst is obtained by putting metatungstate into a carrier of zirconium or a compound including zirconium, and then stirring, drying, and plasticizing the resultant compound. The carrier is composed of Zr(OH)4. The carrier is composed of one or more selected from ZrO2, XZ16122(Mono/Tetrag, SiO2(
Abstract translation: 提供氧化钨氧化锆催化剂和使用其除去油中所含的游离脂肪酸的方法以提高氧化钨氧化锆催化剂从废油中除去游离脂肪酸的活性。 通过将偏钨酸盐放入锆或包含锆的化合物的载体中，然后搅拌，干燥和塑化所得化合物，得到氧化钨氧化锆催化剂。 载体由Zr（OH）4组成。 载体由选自ZrO 2，XZ16122（Mono / Tetrag，SiO 2（<0.2％）），XZ31107（形成的氧化锆/二氧化硅），SZ23118（Monoclinic，SiO 2（<0.2％））中的一种或多种构成。
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公开(公告)号：KR100566107B1
公开(公告)日：2006-03-30
申请号：KR1020030022078
申请日：2003-04-08
Applicant: 한국에너지기술연구원
IPC: C10G3/00
Abstract: 본 발명은 폐식용유중의 유리지방산 제거방법에 관한 것으로 보다 상세하게는 폐식용유에 함유된 유리지방산을 불균질계 무기 고체 산촉매(heterogeneous solid acid catalyst)를 이용하여 폐식용유중의 유리지방산을 제거하는 방법에 관한 것이다.
본 발명은 바이오디젤유의 제조의 원료로 사용할 수 있도록 폐식용유중에 함유된 유리지방산을 불균질계 무기 고체 산촉매를 이용하여 제거할 수 있는 폐식용유중의 유리지방산 제거방법 제공을 목적으로 한다.
본 발명의 폐식용유중의 유리지방산 제거방법은 폐식용중의 유리지방산 제거에 있어서, 불균질계 무기 고체 산촉매하에서 알콜과 유리지방산을 함유한 폐식용유를 반응시키는 단계를 포함한다.-
公开(公告)号：KR1020040054318A
公开(公告)日：2004-06-25
申请号：KR1020020081344
申请日：2002-12-18
Applicant: 한국에너지기술연구원
IPC: C10L1/16
CPC classification number: Y02E50/13 , C10G3/44 , B01J37/04 , B01J37/08 , C10G2300/1011 , C10G2300/70 , C10G2400/04
Abstract: PURPOSE: Provided are a method for preparing a bio-diesel oil by using a heterogeneous catalyst and a bio-diesel oil prepared thereby. CONSTITUTION: The method comprises a step of esterifying an oil and fat and an alcohol in the presence of a heterogeneous catalyst, wherein the oil and fat is selected from the group consisting of soybean oil, corn oil, canola oil, linseed oil, poppy oil, walnut oil, peanut oil, cottonseed oil, bran oil, camellia oil, castor oil, beef tallow, lard, sheep fat, fish oil and whale oil, the heterogeneous catalyst is Na/NaOH/γ-Al2O3 or CsxO/γ-Al2O3 (x is 0.1-2) and the alcohol is selected from the group consisting of methanol, ethanol, propanol, butanol and combinations thereof.
Abstract translation: 目的：提供一种通过使用非均相催化剂和由此制备的生物柴油来制备生物柴油的方法。 方案：该方法包括在多相催化剂存在下酯化油脂和醇的步骤，其中油脂选自大豆油，玉米油，菜籽油，亚麻子油，罂粟油 核桃油，花生油，棉籽油，糠麸油，山茶油，蓖麻油，牛油，猪油，羊脂，鱼油和鲸油，多相催化剂为Na / NaOH /γ-Al2O3或CsxO /γ-Al2O3 （x为0.1-2），醇选自甲醇，乙醇，丙醇，丁醇及其组合。
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公开(公告)号：KR100311057B1
公开(公告)日：2002-04-22
申请号：KR1019980012731
申请日：1998-04-06
Applicant: 한국에너지기술연구원
Abstract: PURPOSE: A photo-bioreactor and a method for culturing photosynthetic bacteria using the same are provided, thereby optimally culturing photosynthetic bacteria, regardless of the outside temperature. CONSTITUTION: A vertical pipe type photo-bioreactor(1) comprises a circulating pipe; a heat exchanger(2) for regulating the temperature of the bioreactor regardless of the outside temperature; a circulating hole(14) positioned under the circulating pipe; an air dispersing plate(3) with an air introducing hole(4) for supplying air to the bioreactor which is positioned in the lower outside of the circulating pipe. A method for culturing photosynthetic bacteria using the photo-bioreactor comprises maintaining the temperature of a medium in the bioreactor to 25 to 35 deg. C and supplying air to the medium in the bioreactor, thereby microorganisms cultured in the medium are circulated.
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公开(公告)号：KR1020010058065A
公开(公告)日：2001-07-05
申请号：KR1019990061537
申请日：1999-12-24
Applicant: 한국에너지기술연구원
IPC: C12P7/06
Abstract: PURPOSE: Provided is a method for producing high concentration ethanol from wood-saccharified solution by using pasteurization. Thereby ethanol can be produced in high concentration and productivity. CONSTITUTION: High concentration ethanol is manufactured from wood biomass using pasteurization followed by fermentation. Its production method comprises the steps of: pretreating and saccharifying wood biomass containing waste-woods and organic wastes; pasteurizing the wood-saccharified solution to remove toxic materials therefrom, wherein the saccharified solution is sterilized by heating at low temperature of 60 to 70 deg. C for 30 to 120 minutes; and inoculating Saccharomyces cerevisae into the saccharified solution then followed by batch-fermenting or continuous-fermenting it.
Abstract translation: 目的：提供通过巴氏杀菌从木糖化溶液中生产高浓度乙醇的方法。 由此可以高浓度和高生产率制备乙醇。 构成：高浓度乙醇由木材生物质采用巴氏灭菌发酵生产。 其生产方法包括以下步骤：预处理和糖化包含废木材和有机废物的木材生物质; 将木糖化溶液巴氏消毒以除去其中的有毒物质，其中糖化溶液通过在60至70℃的低温加热而灭菌。 C为30〜120分钟; 并将酿酒酵母接种到糖化溶液中，然后分批发酵或连续发酵。
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