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公开(公告)号:DE59901144D1
公开(公告)日:2002-05-08
申请号:DE59901144
申请日:1999-07-12
Applicant: BASF AG
Inventor: GLUECK GUISCARD
Abstract: The invention relates to a process for the preparation of expandable able styrene polymers containing particles of graphite by polymerization merization of styrene in aqueous suspension in the presence of particles of graphite having a mass density of less than 1.8 g/cm3.
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公开(公告)号:DE10016626A1
公开(公告)日:2001-10-11
申请号:DE10016626
申请日:2000-04-04
Applicant: BASF AG
Inventor: GLUECK GUISCARD , MRONGA NORBERT , HAHN KLAUS
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公开(公告)号:DE59800946D1
公开(公告)日:2001-08-02
申请号:DE59800946
申请日:1998-09-08
Applicant: BASF AG
Inventor: GLUECK GUISCARD , HAHN KLAUS
IPC: C08F4/32 , C08F257/02 , C08J9/16
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公开(公告)号:BR9915378A
公开(公告)日:2001-07-31
申请号:BR9915378
申请日:1999-11-05
Applicant: BASF AG
Inventor: GLUECK GUISCARD
Abstract: The invention relates to expandable polystyrene beads which comprise graphite particles with an average particle size of more than 50 mum, and also to a process for their preparation by free-radical polymerization of styrene in aqueous suspension. The graphite particles, suspended in styrene, are added to the polymerization mixture at a conversion of from 10 to 100%.
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公开(公告)号:NO20012839L
公开(公告)日:2001-06-08
申请号:NO20012839
申请日:2001-06-08
Applicant: BASF AG
Inventor: GLUECK GUISCARD , DIETZEN FRANZ-JOSEF , HAHN KLAUS , EHRMANN GERD
IPC: C08J9/20 , B29C44/00 , C08F2/44 , C08F12/08 , C08J9/00 , C08J9/16 , C08K3/00 , C08K3/04 , C08K3/32 , C08K5/49 , C08K7/22 , C08L25/04 , C08L25/06 , C08F212/08
Abstract: A process for preparing expandable particulate styrene polymers wherein from 5 to 50% by weight of expanded graphite and also, if desired, from 2 to 20% by weight of a phosphorus compound, are present as flame retardants, by suspension polymerization of styrene in the presence of the flame retardants.
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公开(公告)号:DE19907136A1
公开(公告)日:2000-08-24
申请号:DE19907136
申请日:1999-02-19
Applicant: BASF AG
Inventor: BARGHOORN PETER , KLOSTERMANN RAINER , GLUECK GUISCARD
Abstract: Drying of coagulated water-containing rubber particles by treatment of the particles with an aqueous solution of a dissolved material, so that the particle surfaces are at least temporarily completely covered by the aqueous solution is new.
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公开(公告)号:DE19852678A1
公开(公告)日:2000-05-18
申请号:DE19852678
申请日:1998-11-16
Applicant: BASF AG
Inventor: GLUECK GUISCARD
Abstract: The invention relates to particulate, expandable styrene polymers containing graphite particles with an average particle size of more than 50 mu m, and to a method for producing said styrene polymers by radical polymerisation of styrene in aqueous suspension, the graphite particles, which are suspended in styrene, being added to the polymerisation charge with a conversion of 10 to 100 %.
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公开(公告)号:DE19835495A1
公开(公告)日:2000-02-10
申请号:DE19835495
申请日:1998-08-06
Applicant: BASF AG
Inventor: GLUECK GUISCARD , BATSCHEIDER KARL-HEINZ
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公开(公告)号:NO995552D0
公开(公告)日:1999-11-12
申请号:NO995552
申请日:1999-11-12
Applicant: BASF AG
Inventor: GLUECK GUISCARD , HAHAN KLAUS , BATSCHEIDER KARL-HEINZ , NAEGELE DIETER , KAEMPFER KNUT , HUSEMANN WOLFRAM , HOWILLER FRIEDER
Abstract: PCT No. PCT/EP97/02457 Sec. 371 Date Nov. 15, 1999 Sec. 102(e) Date Nov. 15, 1999 PCT Filed May 14, 1997 PCT Pub. No. WO98/51734 PCT Pub. Date Nov. 19, 1998In a process for preparing expandable styrene polymers containing graphite particles, styrene is polymerized in aqueous suspension in the presence of graphite particles.
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公开(公告)号:DE19819058A1
公开(公告)日:1999-11-04
申请号:DE19819058
申请日:1998-04-29
Applicant: BASF AG
Inventor: GLUECK GUISCARD , BATSCHEIDER KARL-HEINZ
Abstract: Expandable slightly foamed styrene polymerizate (ESP) particles have a coarse cell structure so that their bulk density is 0.1-20% lower than the initial bulk density of the unformed ESP particles. Independent claims are included for: (1) production of slightly foamed ESP particles by extrusion of a polystyrene melt containing a propellant in a water bath, cooling of the melt strand, and underwater granulation of the cooled strand. The water bath is held at a temperature of 50-90 deg C and is optionally in a closed system in which the pressure is 2-20 bar; (2) production of slightly foamed ESP particles by suspension polymerization of styrene in the presence of a propellant at increased temperature and pressure, cooling to 60-90 deg C, and evaporation of the suspension; (3) production of slightly foamed ESP particles by mixing the particles with conventional coating agents in a mixing unit at a temperature of 60-90 deg C; (4) production of slightly foamed ESP particles by treatment of the particles with hot air or steam for 0.5-5 seconds at 60-100 deg C; (5) production of foamed ESP particles of coarse cell structure corresponding to a cell number of 1-6 cells per mm at a bulk density of 8-20 g/liter obtained as in (4) above.
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