91.
    发明专利
    未知

    公开(公告)号:DE59901144D1

    公开(公告)日:2002-05-08

    申请号:DE59901144

    申请日:1999-07-12

    Applicant: BASF AG

    Inventor: GLUECK GUISCARD

    Abstract: The invention relates to a process for the preparation of expandable able styrene polymers containing particles of graphite by polymerization merization of styrene in aqueous suspension in the presence of particles of graphite having a mass density of less than 1.8 g/cm3.

    94.
    发明专利
    未知

    公开(公告)号:BR9915378A

    公开(公告)日:2001-07-31

    申请号:BR9915378

    申请日:1999-11-05

    Applicant: BASF AG

    Inventor: GLUECK GUISCARD

    Abstract: The invention relates to expandable polystyrene beads which comprise graphite particles with an average particle size of more than 50 mum, and also to a process for their preparation by free-radical polymerization of styrene in aqueous suspension. The graphite particles, suspended in styrene, are added to the polymerization mixture at a conversion of from 10 to 100%.

    97.
    发明专利
    未知

    公开(公告)号:DE19852678A1

    公开(公告)日:2000-05-18

    申请号:DE19852678

    申请日:1998-11-16

    Applicant: BASF AG

    Inventor: GLUECK GUISCARD

    Abstract: The invention relates to particulate, expandable styrene polymers containing graphite particles with an average particle size of more than 50 mu m, and to a method for producing said styrene polymers by radical polymerisation of styrene in aqueous suspension, the graphite particles, which are suspended in styrene, being added to the polymerisation charge with a conversion of 10 to 100 %.

    Expandable slightly foamed styrene polymerizate particles of coarse cell structure, useful as insulating or packing materials

    公开(公告)号:DE19819058A1

    公开(公告)日:1999-11-04

    申请号:DE19819058

    申请日:1998-04-29

    Applicant: BASF AG

    Abstract: Expandable slightly foamed styrene polymerizate (ESP) particles have a coarse cell structure so that their bulk density is 0.1-20% lower than the initial bulk density of the unformed ESP particles. Independent claims are included for: (1) production of slightly foamed ESP particles by extrusion of a polystyrene melt containing a propellant in a water bath, cooling of the melt strand, and underwater granulation of the cooled strand. The water bath is held at a temperature of 50-90 deg C and is optionally in a closed system in which the pressure is 2-20 bar; (2) production of slightly foamed ESP particles by suspension polymerization of styrene in the presence of a propellant at increased temperature and pressure, cooling to 60-90 deg C, and evaporation of the suspension; (3) production of slightly foamed ESP particles by mixing the particles with conventional coating agents in a mixing unit at a temperature of 60-90 deg C; (4) production of slightly foamed ESP particles by treatment of the particles with hot air or steam for 0.5-5 seconds at 60-100 deg C; (5) production of foamed ESP particles of coarse cell structure corresponding to a cell number of 1-6 cells per mm at a bulk density of 8-20 g/liter obtained as in (4) above.

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