Abstract:
Hetaroyl derivatives having the formula (I) are disclosed, as well as their salts useful in agriculture. In the formula, the variables have the following meanings: R1, R2 are hydrogen, nitro, halogen, cyano, rhodano, hydroxy, mercapto, optionally substituted and/or functionalised C¿1?-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 alkoxysulfonyl, or optionally substituted phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl; Z is an optionally substituted, 4-membered, unsaturated, partially or completely saturated chain with three carbon atoms and one nitrogen atom; and Q is optionally substituted cyclohexan-1,3-dione linked at position 2. Also disclosed is a process for preparing the hetaroyl derivatives, agents containing the same, as well as the use of these derivatives or the agents containing the same for controlling undesirable plants.
Abstract:
4-benzoylisothiazoles have the general formula (1), in which the substituents have the following meanings: X stands for oxygen or sulphur; R1 stands for hydrogen, alkyl, alkenyl, alkinyl, optionally substituted alkoxycarbonyl, aryl, heterocyclyl or hetaryl; R2 stands for hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkenyl, whereas these radicals can bear one or several halogen, alkyl, alkenyl or alkinyl groups, or R2 stands for aryl, hetaryl or heterocyclyl; R3 stands for a radical of general formula (2), in which Z and the R?4, R5, R6 and R7¿ substituents have the meanings given in claim 1. Also disclosed are the salts commonly used in agriculture of the 4-benzoylisothiazoles of general formula (1), a process for preparing the same and their use as herbicides.
Abstract:
The invention concerns substituted 2-phenylpyridines of formula (I) and their salts, in which X = a bond, 1,2-ethinediyl, an optionally substituted methylene-, 1,2-ethanediyl- or 1,3-propylene bridge, optionally substituted methyleneoxymethylene, methylenethiamethylene, ethene-1,2-diyl, optionally substituted oxymethylene, thiamethylene, oxyethylene or thiaethylene bonded to the phenyl ring via the heteroatom; Y = -O-, -S-; -Z1 = -O-, -S-, -N(R?7)-; Z2 = -O¿2-, -S-, -N(R?8)-; R1, R2, R7, R8¿ = H, C¿1?-C6-alkyl, C1-C6-alkyl halide, hydroxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4alkoxy-C1-C4alkyl, C1-C4alkoxy halide-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkoxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di-(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthiohalide-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4alkinylthio-C1-C4-alkyl, C1-C4-alkylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphinylhalide-C1-C4-alkyl, C3-C4-alkenylsulphinyl-C1-C4-alkyl, C3-C4-alkinylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphonyl-C1-C4-alkyl, C1-C4-alkylsulphonyl halide-C1-C4-alkyl, C3-C4-alkenylsulphonyl-C1-C4-alkyl, C3-C4-alkinylsulphonyl-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-alkenyl halide, cyano-C3-C6-alkenyl, C3-C6-alkinyl, C3-C6-alkinyl halide, cyano-C3-C6-alkinyl, hydroxycarbonyl-C1-C4-alkyl, (C1-C4-alkoxy)-carbonyl-C1-C4-alkyl, (C1-C4-alkylthio)carbonyl-C1-C4-alkyl, amino-carbonyl-C1-C4-alkyl, (C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di-(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-members heterocyclyl or heterocyclyl-C1-C4-alkyl, wherein all the heterocycles can contain a (thio)carbonyl ring member, or R?1 + R2¿ and/or R1 + R7 and/or R2 + R8 together in each case are an optionally substituted 1,2-ethanediyl-, 1,3-propylene-, tetramethylene-, pentamethylene- or ethyleneoxyethylene chain; or R1 + R2 together are optionally substituted 1,2-phenylene; R3 = CN, halogen, C¿1?-C4-alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or C1-C4 halkoxy halide; R?4, R5¿ are H, halogen; R6 is halogen, C¿1?-C4 alkyl halide; and n = 0,1. The invention further concerns the use of these substances as herbicides and for desiccating/defoliating plants.
Abstract:
The invention concerns substituted aromatic phosphonic acid derivatives (I) and their salts, wherein: Eth = 1,2-ethinediyl, an optionally substituted ethane or ethene-1,2-diyl chain; y1 = O, S; y2, y3 = O, S or -N(R?6)-; R1, R2, R6, R7¿ = H, C¿1?-C6-alkyl, C1-C6 alkyl halide, hydroxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy halide-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkoxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, Di-(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkyl halide-thio-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4-alkinylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-C1-C4-alkyl, C1-C4-alkyl halide sulfinyl-C1-C4-alkyl, C3-C4-alkenylsulfinyl-C1-C4-alkyl, C3-C4-alkinylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfonyl-C1-C4-alkyl, C1-C4-alkyl halide sulfonyl-C1-C4-alkyl, C3-C4-alkenylsulfonyl-C1-C4-alkyl, C3-C4-alkinylsulfonyl-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-alkenyl halide, cyano-C3-C6-alkenyle, C3-C6-alkenyl halide, cyano-C3-C6-alkenyl, C3-C6-alkinyl, C3-C6-alkinyl halide, cyano-C3-C6-alkinyl, hydroxycarbonyl-C1-C4-alkyl, (C1-C4-alkoxy)-carbonyl-C1-C4-alkyl, (C1-C4-alkylthio)carbonyl-C1-C4alkyl, aminocarbonyl-C1-C4-alkyl, (C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, Di-(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl ou phenyl-C1-C4-alkyl optionally substituted 3- to 7-member heterocyclyl or heterocyclyl-C1-C4 alkyl, wherein all the heterocyclenes can optionally contain a carbonyl- or thiocarbonyl ring member; or R?1 and R2¿ and/or R?1 and R6¿ and/or R?2 and R7¿ together are an optionally substituted 1,2-ethanediyl-, 1,3-propylene-, tetramethylene-, pentamethylene or ethyleneoxyethylene chain; or R?1 and R2¿ together are an optionally substituted 1,2-phenylene; R3 = CN, halogen, C¿1?-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or C1-C4 alkoxy halide; R?4¿ = H, halogen; and R5 = a given heterocyclic ring. The invention further concerns the use of these substances as herbicides and for the desiccation/defoliation of plants.
Abstract:
The invention pertains to 5-pyrazolylbenzoic acid derivatives of formula (I), wherein R2 is C1-C4 alkoxy, C1-C4 alkylthio, C1-C4 alkoxy halide or C1-C4 alkylthio halide, used as herbicides and plant desiccatives or defoliants.
Abstract:
N-aminopyridone derivatives of the formula (I), in which the substituents R?1 to R12¿ have the meanings given in claim 1, a process for their production and their use in suppressing undesired plant growth.
Abstract:
The invention concerns isoxazol-4-yl-benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)mR7 or -(Y)¿n-CO-R?8 group; Z represents a five to six-membered heterocyclic saturated or unsaturated group which contains one to three heteroatoms selected from the group comprising oxygen, sulphur or nitrogen and can optionally be substituted by halogen, cyano, nitro, an -CO-R8 group, C¿1?-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can be present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide, or a C1-C4 alkyl halide, form a bicyclic system; Y represents O or NR?9¿; n is 0 or 1; m is 0, 1 or 2; R7 represents C¿1?-C4 alkyl, C1-C4 alkyl halide or NR?9R10; R8¿ represents C¿1?-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR?9R10; R9¿ represents hydrogen or C¿1?-C4 alkyl; R?10¿ represents C¿1?-C4 alkyl; Q represents an isoxazole ring connected at position 4 and of formula (II) in which R?1¿ represents hydrogen or -CO¿2R?3, R2 represents hydrogen, C¿1?-C4 alkyl or C3-C6 cycloalkyl which can optionally be substituted by one or more halogen atoms or C1-C4 alkyl, R?3¿ representing a C¿1?-C4 alkyl; J represents a carbonyl group CO or a -CHR?4¿ group, R4 representing an OH group, a hydroxyl group optionally acylated with C¿2?-C4 acyl, or a chlorine atom. The invention also concerns salts of compounds of formula (I) usually utilized in agriculture.
Abstract:
Mélanges d'éthers de cyclohexénone-oximes optiquement actifs à configuration R et S dans la partie éther d'oxime de formule (I), où R1 = alkyle en C1-C6; Z = (a), (b), (c), (d), (e); X = alkyle en C1-C4, halogénoalkyle en C1-C4; m = 0-3 ou 1-4 dans le cas où tous les X représentent l'halogène; n = 0-3 ou 1-5 dans le cas où tous les X représentent l'halogène; R2 = C1-C4-alcoxy-C1-C6-alkyle, C1-C4-alkylthio-C1-C6-alkyl, cycloalkyle en C3-C7 éventuellement substitué, cycloalkényle en C5-C7 éventuellement substitué, hétérocycle saturé à 5 chaînons éventuellement substitué, hétérocycle à 6 ou 7 chaînons éventuellement substitué, hétéroaromate à 5 chaînons éventuellement substitué, phényle ou pyridyle éventuellement substitué; ainsi que leur sels et leurs esters d'acides carboxyliques en C1-C10 et d'acides anorganiques à usage agricole.