Abstract:
The invention relates to a solid crop protection formulation comprising a) cinidon-ethyl as a crop protection agent; b) at least one random radical copolymer comprising as polymerized units at least one hydrophilic and at least one hydrophobic monomer; and c) optionally further additives, wherein at least 50 % of the dispersed cinidon-ethyl particles in said solid crop protection formulation are in an X-ray amorphous state and an aqueous dispersion formulation thereof. Additionally, the invention relates to processes for preparing said formulations and the use of said formulations in agriculture. Further, the invention relates to a random radical copolymer essentially consisting of as polymerized units a) 5 to 95 % by weight of styrene as component A; b) 5 to 95 % by weight of DMAPMAM (dimethylaminopropyl methacrylic amide) as component B; c) 0 to 98 % by weight of methyl acrylate and/or vinyl acetate as component C.
Abstract translation:本发明涉及一种固体作物保护制剂,其包含作为作物保护剂的cinidon-ethyl b至少一种无规自由基共聚物,其包含作为聚合单元的至少一种亲水和至少一种疏水性单体和c任选的其它添加剂,其中至少50 所述固体作物保护制剂中分散的cinidon-ethyl颗粒的%为X射线无定形状态及其水分散体制剂。 此外,本发明涉及制备所述制剂的方法和所述制剂在农业中的用途。 此外,本发明涉及一种无规自由基共聚物,其基本上由作为聚合单元的组分为5至95重量%的苯乙烯作为组分A b 5至95重量%的DMAPMAM二甲基氨基丙基甲基丙烯酰胺作为组分B c 0至98重量% 的丙烯酸甲酯和/或乙酸乙烯酯作为组分C.
Abstract:
4-benzoyl-pyrazoles having the formula (I) are disclosed, in which the substituents have the following meanings: R1, R2 stand for hydrogen, mercapto, nitro, halogen, cyano, rhodano, C¿1?-C6-alkyl, halogenated C1-C6-alkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkinyl, -OR?10, -OCOR10¿, -OSO¿2R?10, -S(O)¿n?R?10, -SO¿2OR10, -SO2NR?3OR10, -NR10SO¿2R?10 or -NR10¿COR; Q stands for a pyrazol linked at position 4 and having formula (II), in which R11 stands for C¿1?-C6-alkyl, halogenated C1-C6-alkyl, phenyl or phenyl which is partially or entirely halogenated and/or bears one to three of the following radicals: nitro, cyano, C1-C4-alkyl, halogenated C1-C4-alkyl, C1-C4-alkoxy, halogenated C1-C4-alkoxy; R?12¿ stands for hydrogen, C¿1?-C6-alkyl, halogenated C1-C6-alkyl, C1-C6-alkylcarbonyl, halogenated C1-C6-alkylcarbonyl, C1-C6-alkoxycarbonyl, C1-C6-alkylsulfonyl, halogenated C1-C6-alkylsulfonyl, phenylcarbonyl, phenylcarbonylmethyl, phenoxycarbonyl or phenylsulfonyl, the last four substituents being unsubstituted or the phenyl ring being partially or entirely halogenated and/or bearing one to three of the following radicals: nitro, cyano, C1-C4-alkyl, halogenated C1-C4-alkyl, C1-C4-alkoxy, halogenated C1-C4-alkoxy; R?13¿ stands for hydrogen, C¿1?-C6-alkyl or halogenated C1-C6-alkyl; A stands for a group of formulas (IIIa), (IIIb) or (IV), in which the substituents have the meanings indicated in the first claim. Also disclosed are the salts of these compounds useful in agriculture.
Abstract:
The invention relates to 2-benzoyl-cyclohexane-1,3 diones of formula (I) wherein the substituents have the following meanings: R1, R2 stands for hydrogen, mercapto, nitro, halogen, cyano, rhodano, C¿1?-C6 alkyl, C1-C6 alkyl halide, C1-C6 alkoxy, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, -OR?10, -OCOR10¿, -OSO¿2R?10, -S(O)¿n?R?10, -SO¿2OR10, -SO2NR?3R10, -NR10SO¿2R?10 or -NR10¿COR; Q represents an optionally substituted cyclohexane-1,3-dione-ring bonded in position 2; and A means a group of formula (IIa), (IIb) or (III) wherein the substituents have the meaning cited in Claim 1. The invention also relates to the salts of said compounds which can be used in agriculture.
Abstract:
The invention concerns a process for preparing sulphurous 2-chloro-3-(4,5-dihydroisoxazol-3-yl)-benzoic acids of general formula (I) in which the substituents have the meanings given in the description.
Abstract:
The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR?5, -OCOR6¿, -OSO¿2R?6, -SH, -S(O)¿n?R?7, -SO¿2OR5, -SO2NR?5R8, -NR8SO¿2R?6 or -NR8COR6; R3¿ stands for hydrogen, alkyl, halogen alkyl or alkinyl; R4 stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R?9, -COSR9¿ or -CONR8R9; X stands for oxygen or sulphur; m equals 0 or 1; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted cyclohexan-1,3-dione ring linked in position 2, whereas m equals 1 when R3 stands for hydrogen. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.
Abstract:
The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR?5, -OCOR6¿, -OSO¿2R?6, -SH, -S(O)¿n?R?7, -SO¿2OR5, -SO2NR?5R8, -NR8SO¿2R?6 or -NR8COR6; R3¿ stands for hydrogen, cyano, alkyl, halogen alkyl, -OR?7, -SR7 or -NR7R10; R4¿ stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R?9, -COSR9¿ or -CONR8R9; X stands for oxygen or NR8; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for an optionally substituted cyclohexan-1,3-dione ring linked in position 2. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.
Abstract translation:本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮,其中R1,R2各自为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基,-OR5,-OCOR6,-OSO2R6, -SH,-S(O)nR7,-SO2OR5,-SO2NR5R8,-NR8SO2R6或-NR8COR6; R3是氢,氰基,烷基,卤代烷基,-OR7,-SR7或-NR7R10; R4是氢,取代或未取代的烷基, 环烷基,烯基,环烯基,炔基,-COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X是氧或NR 8; n是0,1或2; R 5是氢,烷基,卤代烷基,烷氧基烷基,烯基或炔基; 烷基或卤代烷基; R 7是烷基,卤代烷基,烷氧基烷基,烯基或炔基; R 8是氢或烷基; R 9是烷基,烯基,炔基,苯基或苄基; R 10是烷基,卤代烷基,链烯基或炔基; Q是环己烷-1 具有或不具有取代基的2-二酮环,其位置2;及其农业上有用的盐;制备式I化合物的方法和中间体; 包含它们的组合物; 以及使用这些衍生物或包含它们的组合物来控制不期望的植物。
Abstract:
Herbicide N-[(pyrimidin-2-yl)aminocarbonyl] benzene sulphonamides of general formula I, wherein the substituents represent the following: R1 represents methyl or ethyl; R2 represents hydrogen or methyl; R3 represents optionally substituted alkyl; or a group ER6, in which E stands for O or S, and R6 represents optionally fluorine-susbtituted alkyl except difluoromethoxy or, if E represents O and simultaneously R5 represents trifluoromethyl, can represent methyl sulphonyl, ethyl sulphonyl, trifluoromethyl sulphonyl, allyl sulphonyl, or propargyl sulphonyl; or NO¿2? or OH; or a dialkyl group, if R?5¿ represents fluorine; or a C¿1?-C2- alkyl sulphonyl group which can contain 1-3 halogen atoms; R?4¿ represents hydrogen, methyl, ethyl, methoxy, ethoxy, fluorine, chlorine, methylthio, ethylthio, or C¿1?-C2- halogen alkoxyl; R?5¿ represents fluorine or trifluoromethyl, as well as their environmentally acceptable salts and process for their manufacture and their use.
Abstract:
A liquid mixture contains: A) 2-chloro-(2',6'-dimethyl-N-pyrazol-1-yl-methyl)-acetanilide, that may be substituted up to 40 % of its weight by one or several other plant protecting agents; B) a copolymer obtained by copolymerising (b1) one or several C2-C20-mono-olefins; (b2) one or several mono-olefinically unsaturated C4-C8-anhydrides; and (b3) if required other mono-olefinically unsaturated compounds copolymerisable with comonomers (b1 and b2), and whose anhydride and possibly other hydrolysable groups and/or free carboxyl groups may be at least partially converted into salts; C) water; and D) usual auxiliary agents of compositions. Also disclosed is a process for preparing this mixture and its use for controlling undesirable plant growth.