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公开(公告)号：AU670653B2
公开(公告)日：1996-07-25
申请号：AU5504994
申请日：1994-02-10
Applicant: HOECHST AG
Inventor： BENNETT CYNTHIA , BREKNER MICHAEL-JOACHIM , HERRMANN-SCHOENHERR OTTO , OSAN FRANK
IPC: B32B27/32 , B29C55/02 , B65D65/02 , C08F32/00 , C08F32/08 , C08J5/18 , C08L45/00 , G09F9/00 , G11B11/105 , H01B3/30 , H01G4/18 , C09D123/18 , C09D5/25 , C09D123/20
Abstract: The invention relates to a rigid, single- or multilayer, unoriented or monoaxially or biaxially oriented film in which at least one layer contains a cycloolefin copolymer, characterised in that the cycloolefin copolymer has an intrinsic modulus of elasticity Ei which has the following dependence on the glass transition temperature Tg: Ei = (0.0025 GPa/@C] x Tg[@C]) + B[GPa] where B = 2.93 to 3.19.i
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公开(公告)号：MX9401120A
公开(公告)日：1994-08-31
申请号：MX9401120
申请日：1994-02-11
Applicant: HOECHST AG
Inventor： OSAN FRANK , BENNETT CYNTHIA , BREKNER MICHAEL-JOACHIM , HERRMANN-SCHOENHERR OTTO
IPC: B32B27/32 , B29C55/02 , B65D65/02 , C08F32/00 , C08F32/08 , C08J5/18 , C08L45/00 , G09F9/00 , G11B11/105 , H01B3/30 , H01G4/18 , C08F255/08
Abstract: The invention relates to a rigid, single- or multilayer, unoriented or monoaxially or biaxially oriented film in which at least one layer contains a cycloolefin copolymer, characterised in that the cycloolefin copolymer has an intrinsic modulus of elasticity Ei which has the following dependence on the glass transition temperature Tg: Ei = (0.0025 GPa/@C] x Tg[@C]) + B[GPa] where B = 2.93 to 3.19.i
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公开(公告)号：ZA939066B
公开(公告)日：1994-08-04
申请号：ZA939066
申请日：1993-12-03
Applicant: HOECHST AG
Inventor： EPPLE ULRICH , BREKNER MICHAEL-JOACHIM
IPC: C08J5/08 , C08F255/02 , C08F277/00 , C08K7/00 , C08K7/14 , C08L23/18 , C08L51/06 , C08L , C08K , C08J , C08F
Abstract: A glass-fibre-reinforced cycloolefin polymer material comprises from 1 to 99% by weight of at least one cycloolefin polymer, in particular a norbornene-ethylene copolymer, and from 99 to 1% by weight of glass fibres. The absolute value for the refractive index difference (refractive index of glass of glass fibres minus refractive index of cycloolefin polymer) is at most 0.015 for each cycloolefin polymer, and the refractive index of the glass fibres is in the range from 1.510 to 1.560. The materials have good mechanical properties and good light transparency. The glass fibres employed preferably contain no sizes.
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公开(公告)号：NO934409L
公开(公告)日：1994-06-06
申请号：NO934409
申请日：1993-12-03
Applicant: HOECHST AG
Inventor： BREKNER MICHAEL-JOACHIM , EPPLE ULRICH
IPC: C08J5/08 , C08F255/02 , C08F277/00 , C08K7/00 , C08K7/14 , C08L23/18 , C08L51/06 , C08L45/00
Abstract: A glass-fibre-reinforced cycloolefin polymer material comprises from 1 to 99% by weight of at least one cycloolefin polymer, in particular a norbornene-ethylene copolymer, and from 99 to 1% by weight of glass fibres. The absolute value for the refractive index difference (refractive index of glass of glass fibres minus refractive index of cycloolefin polymer) is at most 0.015 for each cycloolefin polymer, and the refractive index of the glass fibres is in the range from 1.510 to 1.560. The materials have good mechanical properties and good light transparency. The glass fibres employed preferably contain no sizes.
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公开(公告)号：ZA932789B
公开(公告)日：1993-11-16
申请号：ZA932789
申请日：1993-04-21
Applicant: HOECHST AG
Inventor： EPPLE ULRICH , BREKNER MICHAEL-JOACHIM
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Patent Agency Ranking
公开(公告)号：ZA926638B
公开(公告)日：1993-04-28
申请号：ZA926638
申请日：1992-09-02
Applicant: HOECHST AG
Inventor： EPPLE ULRICH , ULRICH EPPLE , BREKNER MICHAEL-JOACHIM , MICHAEL-JOACHIM BREKNER , CHERDRON HARALD , HARALD CHERDRON
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公开(公告)号：HU913539D0
公开(公告)日：1992-01-28
申请号：HU353991
申请日：1991-11-12
Applicant: HOECHST AG
Inventor： BREKNER MICHAEL-JOACHIM , OSAN FRANK , ROHRMANN JUERGEN , ANTBERG MARTIN
IPC: C08F4/642 , C08F4/60 , C08F4/6592 , C08F6/26 , C08F10/14 , C08F32/00 , C08F32/08 , C08F210/00 , C08F232/08
Abstract: Polymers of polycyclic olefins such as, for example, norbornene or tetracyclododecene, or copolymers of polycyclic olefins with cycloolefins and/or 1-olefins are obtained without ring opening, in high space-time yield, with high cycloolefin incorporation rate and at industrially favourable polymerisation temperatures by a bulk polymerisation in which the catalyst used consists of an aluminoxane and of a stereorigid, chiral metallocene compound of an element of groups IVb to VIb, where the hydrocarbon radicals forming the sandwich structure are different.
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公开(公告)号：PT96487A
公开(公告)日：1991-10-31
申请号：PT9648791
申请日：1991-01-15
Applicant: HOECHST AG
IPC: C08G65/40 , C08L67/00 , C08L67/03 , C08L69/00 , C08L71/00 , C08L71/08 , C08L71/10 , C08L81/06 , C08L , B29C
Abstract: For optical applications, transparent, amorphous thermoplastics, such as polyaryl ether ketones, are of considerable interest. However, polyaryl ether ketones have inadequate UV stability and weathering resistance, while amorphous polyaryl esters do not have these adverse properties. The properties can be improved by means of polymer alloys, and weathering-resistant materials made from homogeneously mixed polymers comprising at least one amorphous polyaryl ether ketone and at least one amorphous polyaryl ester are thus obtained.
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公开(公告)号：CA2034232A1
公开(公告)日：1991-07-17
申请号：CA2034232
申请日：1991-01-15
Applicant: HOECHST AG
IPC: C08G65/40 , C08L67/00 , C08L67/03 , C08L69/00 , C08L71/00 , C08L71/08 , C08L71/10 , C08L81/06 , C08L61/00
Abstract: HOE: 90/F 009 Weathering-resistant polymer alloys For optical applications, transparent amorphous thermoplastics, such as polyaryl ether ketones, are of considerable interest. However, polyaryl ether ketones have inadequate W stability and weathering resistance while amorphous polyaryl esters do not have these negative properties. The properties can be improved by means of polymer alloys, giving weathering-resistant materials from homogeneously mixed polymers which comprise at least one amorphous polyaryl ether ketone and at least one amorphous polyaryl ester.
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公开(公告)号：ZA905308B
公开(公告)日：1991-04-24
申请号：ZA905308
申请日：1990-07-06
Applicant: HOECHST AG
Inventor： BREKNER MICHAEL-JOACHIM , MICHAEL-JOACHIM BREKNER , ROHRMANN JURGEN , JURGEN ROHRMANN , SPALECK WALTER , WALTER SPALECK , ANTBERG MARTIN , MARTIN ANTBERG
IPC: C08F4/642 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/6192 , C08F4/622 , C08F4/626 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/6592 , C08F10/00 , C08F32/00 , C08F32/04 , C08F32/08 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F232/00 , C08F232/04 , C08F232/08 , C08G61/08 , C08F
Abstract: The prodn. of cycloolefin polymers (COC) comprises the polymerisation of (a) 0.1-100 wt.% monomer(s) of formula (I), (II), (III) or (IV), (b) 0-99.9 wt.% cycloolefin of formula (V) and (c) acyclic 1-olefin(s) of formula (VI), at -78 to +150 degrees C and 0.5-64 bar in soln., suspension, monomer melt or gas phase, in the presence of a catalyst consisting of a metallocene component of formula (IX) and linear and/or cyclic aluminoxane(s) of formula (VII) and/or (VIII). R -R = H or 1-8 C alkyl; n = 2-10; R = 1-6 C alkyl, Ph or benzyl; m = 2-50; M = Ti, Zr, Hf, V, Nb or Ta; R , R = H, halo, 1-10 C alkyl or alkoxy, 2-10 C alkenyl, 6-10 C aryl or aryloxy, 7-40 C aralkyl or alkaryl, or 8-40 C aralkenyl; R , R = mono- or poly-nuclear hydrocarbon residue which can form a sandwich structure with M ; R = -X-, -X-M R R -, -X-C(R )2-, -CR R -, -O-X-, -CR R -CR R - or -BR -; X = -M R R -; M = Si, Ge or Sn; R -R = H, halo, 1-10 C alkyl, fluoroalkyl or alkoxy, 6-10 C aryl or fluoroalkyl, 2-10 C alkenyl, 7-40 C aralkyl or alkaryl, or 8-40 C aralkenyl; or R +R or R +R or R +R may form a ring with their linking atom. Also claimed are COC polymers obtd. by this process, esp. with a content of more than 40 mole% norbornene units. Also claimed are extruded parts, injection moulded prods. and polymer alloys contg. the above COC polymer(s).
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