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98 records (took 0.024 seconds)

    94.
    发明专利
    未知

    公开(公告)号：FR2336972A1

    公开(公告)日：1977-07-29

    申请号：FR7639786

    申请日：1976-12-31

    Applicant: STANDARD OIL CO

    Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY

    IPC: B01J23/88 ,  B01J23/00 ,  B01J23/18 ,  B01J23/22 ,  B01J23/28 ,  B01J23/887 ,  B01J37/02 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

    Abstract: A process for obtaining acrylic acid or methacrylic acid from acrolein or methacrolein, respectively, comprising the steps of mixing the aldehyde, molecular oxygen and water vapor in a molar ratio within the range of 1/0.5-5/0-20, respectively; contacting said mixture with a catalyst at a temperature of about 200º to 500º c, said catalyst having a composition represented by the empirical formula ** (formula) ** wherein x is a metal selected from the group consisting of antimony and germanium, or both, and where a is a number from 6 to about 18, b, c and d are, individually, from about 0.1 to about 6, and e is the number of oxygen atoms required to meet the valence requirements of the other metals present; and recover the unsaturated acid. (Machine-translation by Google Translate, not legally binding)

    97.
    发明专利
    未知

    公开(公告)号：DE2332880A1

    公开(公告)日：1974-01-31

    申请号：DE2332880

    申请日：1973-06-28

    Applicant: STANDARD OIL CO OHIO

    Inventor： CALLAHAN JAMES LOUIS ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

    IPC: B01J2/02 ,  B01J37/00

    Abstract: 1444572 Hollow particles STANDARD OIL CO 13 July 1973 [13 July 1972] 7199/76 Divided out of 1444571 Heading C1A [Also in Division B5] An aggregate, Fig. 1, of solid particles having a rounded shape, a void centre and a single cavity in the external surface communicating with the void centre is produced by the process described in the parent Specification 1,444,571 modified by feeding the droplets of the slurry containing the solid particles on to a static particle bed so that the total droplet is not immersed in the bed and is allowed to dry in the bed without agitation. Specified materials include clay, ammonium nitrate and metal oxides.

    98.
    发明专利
    未知

    公开(公告)号：DE2229358A1

    公开(公告)日：1973-01-18

    申请号：DE2229358

    申请日：1972-06-16

    Applicant: STANDARD OIL CO OHIO

    Inventor： MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE ,  BLYTHE HUGH MICHAEL

    IPC: B01J23/28 ,  B01J23/88 ,  B01J27/19 ,  B01J11/32

    Abstract: 1397119 Making fluidizable, supported molybdenum oxide-containing catalysts STANDARD OIL CO 22 June 1972 [28 June 1971] 29325/72 Heading B1E Catalysts are made by adding incrementally a sol containing SiO 2 , Al 2 O 3 , TiO 2 and/or ZrO 2 to an aqueous suspension and/or solution of a heptamolybdate or a dimolybdate and optionally an alkali metal hydroxide or nitrate at a temperature below 150‹F, spray drying the resulting slurry at a temperature below 1000‹F, collecting the dried spherical particles and calcining them. Optionally to the slurry an acid of P, As or B may be added below (150‹F) after the sol. As a further option a nitrate, carbonate, oxalate and/or acetate of an alkali metal, Mg, Ca, Zn, Cd, a rare earth metal, Sn, Nb, Ta, Sb, Bi, Te, Mn, Fe, Co and/or Ni may be added in solution to the slurry (below 150‹F) but after the acid if that is also used. Further sol may be added with the nitrate, carbonate, oxalate and/or acetate and/ or with the acid.

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