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    91.
    发明专利
    未知

    公开(公告)号：ES2110483T3

    公开(公告)日：1998-02-16

    申请号：ES92870044

    申请日：1992-03-16

    Applicant: UCB SA

    Inventor： MOENS LUC ,  MAETENS DANIEL ,  LOUTZ JEAN-MARIE ,  BAUDOUR MICHEL

    IPC: C08G63/199 ,  C08G63/553 ,  C09D163/00 ,  C09D167/00 ,  C09D5/03

    Abstract: Polyesters containing terminal carboxyl groups comprising the products of reaction of (a) an aliphatic polyester containing terminal hydroxyl groups, prepared from 1,4-cyclohexanedicarboxylic acid and from an alcoholic constituent comprising (1) from 10 to 100 equivalents % of a cycloaliphatic diol and (2) from 90 to 0 equivalents % of at least one aliphatic polyol containing a straight or branched chain which has from 2 to 12 carbon atoms, with (b) an aliphatic and/or aromatic dicarboxylic acid or the corresponding anhydride, process for their preparation and heat-curable compositions in powder form based on these polyesters and polyepoxy compounds used for the production of varnishes and paints in powder form. These polyesters yield coatings which have an excellent resistance to inclement weather, combined with remarkable mechanical properties, even when the curing is performed at low temperature.

    COMPOSITIONS THERMODURCISSABLES EN POUDRE POUR REVETEMENTS.
    92.
    发明专利
    COMPOSITIONS THERMODURCISSABLES EN POUDRE POUR REVETEMENTS. 未知

    公开(公告)号：BE1009779A4

    公开(公告)日：1997-08-05

    申请号：BE9501000

    申请日：1995-12-06

    Applicant: UCB SA

    Inventor： MOENS LUC ,  LOOSEN PATRICK ,  MAETENS DANIEL ,  LOUTZ JEAN-MARIE

    IPC: C08L67/02 ,  C09D5/03 ,  C09D167/00 ,  C09D167/02

    Abstract: Compositions thermodurcissables en poudre comprenant comme liant un mélange de polyesters contenant des groupes carboxyle et d'un agent de réticulation ayant des groupes fonctionnels capables de réagir avec les groupes carboxyle. Les polyesters comprennent (a) un polyester semi-cristallin contenant des groupes carboxyle, constitué, par rapport au total des alcools, de 85 à 100 moles % de 1,4-cyclohexanediol et de 0 à 15 moles % d'au moins un autre polyol aliphatique et/ou cycloaliphatique, et, par rapport au total des acides, de 85 à 100 moles % d'un acide aliphatique dicarboxylique saturé à chaîne linéaire ayant de 4 à 14 atomes de carbone et de 0 à 15 moles % d'au moins un autre acide polycarboxylique aliphatique, et/ou cycloaliphatique et/ou aromatique, et (b) un polyester amorphe contenant des groupes carboxyle constitué, par rapport au total des acides, de 70 à 100 moles % d'acide isophtalique et de 0 à 30 moles % d'au moins un autreacide polycarboxylique aliphatique et/ou cycloaliphatique et/ou aromatique, et, par rapport au total des alcools, de 70 à 100 moles % de néopentylglycol et/ou de 2-butyl-2-éthyl-1,3-propanediol et de 0 à 30 moles % d'au moins...

    Powdered thermosetting compositions for coatings
    93.
    发明专利
    Powdered thermosetting compositions for coatings 未知

    公开(公告)号：AU1026297A

    公开(公告)日：1997-06-27

    申请号：AU1026297

    申请日：1996-12-05

    Applicant: UCB SA

    Inventor： MOENS LUC ,  MAETENS DANIEL ,  LOOSEN PATRICK ,  LOUTZ JEAN-MARIE

    IPC: C08L67/02 ,  C09D5/03 ,  C09D167/00 ,  C09D167/02

    Abstract: Thermosetting powder compositions comprising as binder a mixture of polyesters containing carboxyl groups and of a crosslinking agent having functional groups capable of reacting with the carboxyl groups.The polyesters comprise:(a) a semicrystalline polyester containing carboxyl groups, which comprises, with respect to the total amount of alcohols, of from 85 to 100 mol % of 1,4-cyclohexanediol and of from 0 to 15 mol % of at least one other aliphatic and/or cycloaliphatic polyol and, with respect to the total amount of acids, of from 85 to 100 mol % of a straight-chain saturated dicarboxylic aliphatic acid having from 4 to 14 carbon atoms and of from 0 to 15 mol % of at least one other aliphatic and/or cycloaliphatic and/or aromatic polycarboxylic acid; and(b) an amorphous polyester containing carboxyl groups, which comprises, with respect to the total amount of acids, of from 70 to 100 mol % of isophthalic acid and of from 0 to 30 mol % of at least one other aliphatic and/or cycloaliphatic and/or aromatic polycarboxylic acid and, with respect to the total amount of alcohols, of from 70 to 100 mol % of neopentyl glycol and/or of 2-butyl-2-ethyl-1,3-propanediol and of from 0 to 30 mol % of at least one other aliphatic and/or cycloaliphatic polyol.

    Powder compositions of crystalline polyesters containing methacrylyl end groups
    96.
    发明专利
    Powder compositions of crystalline polyesters containing methacrylyl end groups 未知

    公开(公告)号：ZA963270B

    公开(公告)日：1996-10-25

    申请号：ZA963270

    申请日：1996-04-24

    Applicant: UCB SA

    Inventor： MOENS LUC ,  LOUTZ JEAN-MARIE ,  MAETENS DANIEL ,  LOOSEN PATRICK ,  KERCKHOVE MARC VAN

    IPC: C08F290/00 ,  C08F290/06 ,  C08F299/04 ,  C08G63/58 ,  C09D5/03 ,  C09D5/46 ,  C09D167/06 ,  C09D167/07 ,  C08G ,  C08F ,  C09D ,  C08L

    Abstract: Radiation-curable powder coating compsns. contain crystalline polyester(s) with methacrylyl terminal gps. obtd. by reacting glycidyl methacrylate with a carboxy-terminated polyester of: (a) a polyester reaction prod. of: (1) an acid component contg.: (a.1.1) 85-100 mole% terephthalic acid or 1,4-cyclohexanedicarboxylic acid; and (a.1.2) 0-15 mole % of other aliphatic, cycloaliphatic or aromatic di- or polycarboxylic acid(s) with 4-14C, and (2) an alcohol component contg.: (a.2.1) 85-100 mole % of a 2-12C satd. aliphatic linear diol; and (a.2.2) 0-15 mole% of other aliphatic or cycloaliphatic di- or polyol(s) with 2-15C, and (b) a polyester reaction prod. of: (1) an acid component contg.: (b.1.1) 85-100 mole% of a satd. aliphatic linear dicarboxylic acid with 4-14C; and (b.1.2) 0-15 mole% of other aliphatic, cycloaliphatic or aromatic di- or polycarboxylic acid(s) with 4-14C, and (2) an alcohol component contg.: (b.2.1) 85-100 mole% of 1,4-cyclohexanediol, 1,4-cyclohexane-dimethanol or ethylene glycol; and (b.2.2) 0-15 mole % of other aliphatic or cycloaliphatic di- or polyol(s) with 2-15C. Also claimed are: (i) a process for coating an article; (ii) varnish and paint coating cured by exposure to electron beam radiation ; and (ii) varnish or paint coating cured by exposure to ultraviolet radiation.

    ONE-STEP PROCESS FOR THE PREPARATION OF CARBOXYL GROUP-TERMINATED POLYESTERS
    97.
    发明专利
    ONE-STEP PROCESS FOR THE PREPARATION OF CARBOXYL GROUP-TERMINATED POLYESTERS 未知

    公开(公告)号：GB2189498B

    公开(公告)日：1990-11-21

    申请号：GB8708622

    申请日：1987-04-10

    Applicant: UCB SA

    Inventor： MERCK YVES ,  MAETENS DANIEL ,  LOUTZ JEAN-MARIE

    IPC: C08G63/183 ,  C08G63/20 ,  C09D163/00 ,  C09D167/00 ,  H01B3/42

    Abstract: The present invention provides a process for the preparation of carboxyl group-terminated polyesters, which comprises reacting in one step at elevated temperatures, terephthalic acid and at least one dihydric aliphatic compound and optionally an aromatic polycarboxylic acid having three or more carboxyl groups and/or a polyhydric organic compound having three or more hydroxyl groups and/or a linear aliphatic or cycloaliphatic dicarboxylic acid, the proportions by weight of the respective reactants being such as to produce a polyester having an acid number of from 10 to 25 mg KOH/g and a hydroxyl number of at most 5 mg KOH/g. The present invention also provides a process for preparing a powdered thermosetting coating composition suitable for application as paint or varnish on electricity-conducting articles by electrostatic powder spray methods and fluidized bed coating processes, wherein the carboxyl group-terminated polyester prepared as described above is homogeneously mixed with and epoxy compound containing at least two epoxy groups. The present invention further provides the compositions thus prepared.

    99.
    发明专利
    未知

    公开(公告)号：DE69729463T2

    公开(公告)日：2004-11-04

    申请号：DE69729463

    申请日：1997-09-27

    Applicant: UCB SA

    Inventor： PEETERS STEPHAN ,  VERSCHUEREN KRIS ,  LOUTZ JEAN-MARIE

    IPC: B01J19/12 ,  C08G18/08 ,  C08G18/10 ,  C08G18/42 ,  C08G59/02 ,  C08G59/12 ,  C08G59/20 ,  C08G59/22 ,  C08G59/24 ,  C08G59/32 ,  C08G63/91 ,  C09D163/00 ,  G03F7/038 ,  G03F7/075

    Abstract: In order to offer coatings with improved resistance to solvents which can be prepared by cationic polymerization under irradiation, the choice is made of a composition comprising at least one monomer, oligomer or polymer of general formula (I):in which:A1 is chosen from polyester blocks, polyurethane blocks, hydrocarbon-comprising backbones of mono- or polycarboxylic acid and addition products of a polycarboxylic acid and of a cycloaliphatic diepoxide,m is a number from 1 to 6,R1 is a cycloaliphatic group carrying a hydroxyl group situated in the a position with respect to the oxygen atom to which R1 is bonded,R2 is a second cycloaliphatic group carrying an oxirane group situated at the chain end, andB is chosen from one or more covalent bonds, an oxygen atom and linear, branched or cyclic hydrocarbon-comprising radicals.

    100.
    发明专利
    未知

    公开(公告)号：NO314945B1

    公开(公告)日：2003-06-16

    申请号：NO982551

    申请日：1998-06-04

    Applicant: UCB SA

    Inventor： MOENS LUC ,  MAETENS DANIEL ,  LOOSEN PATRICK ,  LOUTZ JEAN-MARIE

    IPC: C09D5/03 ,  C09D167/00 ,  C08L67/02 ,  C09D167/02

    Abstract: Thermosetting powder compositions comprising as binder a mixture of polyesters containing carboxyl groups and of a crosslinking agent having functional groups capable of reacting with the carboxyl groups.The polyesters comprise:(a) a semicrystalline polyester containing carboxyl groups, which comprises, with respect to the total amount of alcohols, of from 85 to 100 mol % of 1,4-cyclohexanediol and of from 0 to 15 mol % of at least one other aliphatic and/or cycloaliphatic polyol and, with respect to the total amount of acids, of from 85 to 100 mol % of a straight-chain saturated dicarboxylic aliphatic acid having from 4 to 14 carbon atoms and of from 0 to 15 mol % of at least one other aliphatic and/or cycloaliphatic and/or aromatic polycarboxylic acid; and(b) an amorphous polyester containing carboxyl groups, which comprises, with respect to the total amount of acids, of from 70 to 100 mol % of isophthalic acid and of from 0 to 30 mol % of at least one other aliphatic and/or cycloaliphatic and/or aromatic polycarboxylic acid and, with respect to the total amount of alcohols, of from 70 to 100 mol % of neopentyl glycol and/or of 2-butyl-2-ethyl-1,3-propanediol and of from 0 to 30 mol % of at least one other aliphatic and/or cycloaliphatic polyol.

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