公开(公告)号：AU1372697A

公开(公告)日：1997-07-17

申请号：AU1372697

申请日：1996-12-16

Applicant: BASF AG

Inventor： KRECH RUDIGER ,  ROTERMUND UDO ,  BOLLMANN HEINZ ,  HEMPEL RENATE ,  SCHOLZ WOLFGANG ,  GENZ MANFRED

IPC: C08J9/36 ,  C08G18/08 ,  C08G18/76

Abstract: PCT No. PCT/EP96/05640 Sec. 371 Date Oct. 7, 1998 Sec. 102(e) Date Oct. 7, 1998 PCT Filed Dec. 16, 1996 PCT Pub. No. WO97/23535 PCT Pub. Date Jul. 3, 1997A microcellular PU elastomer having improved dynamic mechanical properties and based on an isocyanate component consisting essentially of 4,4'-MDI and further customary constituents has a physicochemical structure which, in the gel permeation chromatograph (GPC) of a solution of the microcellular polyurethane elastomer prepared at 90 DEG C. in N,N-dimethylformamide containing 1 percent of di-n-butylamine measured against polymethyl methacrylate (PMMA) as standard, displays a signal occurring in addition to low molecular weight main signal and comprising one or more peaks at an (apparent) molar mass of greater than 250,000 g/mol which becomes smaller or disappears on addition of lithium chloride to this solution, and a urea content of from 14 to 18% by weight. A process is also provided for preparing such a microcellular PU elastomer having improved dynamic mechanical properties. The microcellular PU elastomers can be used for producing damping elements.

公开(公告)号：AU7217296A

公开(公告)日：1997-05-07

申请号：AU7217296

申请日：1996-09-30

Applicant: BASF AG

Inventor： GENZ MANFRED ,  HELLMANN GERHARD ,  HASELHORST WALTER ,  JESCHKE TORSTEN ,  BRUNS UTE ,  BOLLMANN HEINZ ,  STRAUSS MICHAEL ,  SCHOLZ WOLFGANG ,  PEUKER HARTMUT ,  VOELKEL RUDIGER

IPC: C08G18/10 ,  C08G18/40 ,  C08G18/72 ,  C08G18/76 ,  C08J9/14

Abstract: Compact and preferably cellular polyurethane elastomers based on polyisocyanate mixtures containing 3,3'-dimethylbiphenyl 4,4'-diisocyanate are produced by reactinga) relatively high molecular weight polyhydroxyl compounds and, if desired,b) low molecular weight hydroxyl-containing chain extenders and/or crosslinkers withc) 3,3'-dimethylbiphenyl 4,4'-diisocyanate and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or at least one aliphatic diisocyanate having from 4 to 12 carbon atoms and/or at least one cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are advantageously reacted by the prepolymer method,in the presence or absence ofd) catalysts,e) blowing agents andf) additives.Isocyanate prepolymers suitable for this purpose are preferably ones based on diphenylmethane 4,4'-diisocyanate and 3,3'-dimethylbiphenyl 4,4'-diisocyanate.

公开(公告)号：CA2230171A1

公开(公告)日：1997-03-20

申请号：CA2230171

申请日：1996-09-09

Applicant: BASF AG

Inventor： PEUKER HARTMUT ,  SCHOLZ WOLFGANG ,  STRAUSS MICHAEL ,  HELLMANN GERHARD ,  BOLLMANN HEINZ ,  BRUNS UTE ,  VOELKEL RUEDIGER ,  JESCHKE TORSTEN ,  GENZ MANFRED ,  HASELHORST WALTER

IPC: C08G18/40 ,  C08G18/10 ,  C08G18/65 ,  C08G18/72 ,  C08G18/76 ,  C08J9/04

Abstract: The invention concerns a method of preparing compact and preferably cellular polyurethane elastomers by reacting a) high molecular polyhydroxyl compounds and optionally b) low molecular chain-extending and/or crosslinking agents with c) 1,5-naphthylene diisocyanate and at least one additional aromatic diisocyanate, selected from the group comprising toluylene diisocyanate, diphenylmethane diisocyanate, 3,3'-dimethyl diphenyl diisocyante, 1,2diphenylethane diisocyanate and phenylene diisocyanate, and/or aliphatic diisocyanate with between 4 and 12 carbon atoms and/or cycloaliphatic diisocyanate with between 6 and 18 carbon atoms, the structural components (a), (c) and optionally (b) advantageously being reacted by the prepolymer method, in the presence or absence of d) catalysts, e) expanding agents and f) additives. The invention further concerns isocyanate prepolymers suitable for this method.