公开(公告)号：JPH11166062A

公开(公告)日：1999-06-22

申请号：JP27011998

申请日：1998-09-24

Applicant: BASF AG

Inventor： ROTERMUND UDO ,  HEINZ MARION ,  BIEDERMANN ANJA ,  HEMPEL RENATE ,  WIEGMANN WERNER

IPC: C08J9/00 ,  B01F17/34 ,  C08G18/00 ,  C08G18/28 ,  C08G18/34 ,  C08G18/36 ,  C08G18/40 ,  C08G18/42 ,  C08G18/65 ,  C08G18/66 ,  C08G101/00 ,  C08J9/08 ,  C08J9/14

Abstract: PROBLEM TO BE SOLVED: To obtain the subject emulsion capable of generating a hard polyurethane foam having closed cells or open cells not containing a halogen, by making the emulsion include a reactive hydrogen atom-containing compound, a foaming agent, an auxiliary agent and an additive and using a specific emulsifying auxiliary agent. SOLUTION: This emulsion includes (A) a compound containing a hydrogen atom reactive with isocyanate, (B) a foaming agent and (C) an auxiliary agent and an additive. The emulsion includes a polyester alcohol of the formula (m) is 0-15; (n) is 0-1; (o) is 0-15; (p) is 0-1; (q) is 0-15; (r) is 0-1; (s) is 0-15; (t) is 0-1; (u) is 0-10; (v) is 0-15; (x) is 1-5; (y) is 1-4 or a mixture of 1 to 3 when (r+n)≠0; (z) is 0-3; (zi is 0.1-3; R1 is a fatty structural substance based on a multifunctional alcoholic structure not having OH group; R2 is a group of polycarboxylic acid not having COOH; R3 is an alcoholic group same as R1 } and the component B exists in an emulsified state in the component A and the component C.

公开(公告)号：JPH10120754A

公开(公告)日：1998-05-12

申请号：JP25901197

申请日：1997-09-24

Applicant: BASF AG

Inventor： ROTERMUND UDO DR ,  HEMPEL RENATE ,  SEIFERT HOLGER DR ,  WIEGMANN WERNER

IPC: C08J9/12 ,  C08G18/06 ,  C08G18/48 ,  C08G18/50

Abstract: PROBLEM TO BE SOLVED: To obtain the subject foamed material having low thermal conductivity and improved thermal strain resistance and useful for a plastic-coated pipe, etc., without using a halogenated hydrocarbon foaming agent by reacting a polyisocyanate with a specific compound under specific condition. SOLUTION: A rigid polyurethane foam is produced by reacting (A) a polyisocyanate with (B) a compound having hydrogen atom reactive with isocyanate and composed of a mixture of (i) a polyol produced by the addition reaction of ethylene oxide, etc., to hexitol (mixture) and (ii) a polyol produced by the addition reaction of ethylene oxide, etc., to an aromatic amine wherein the hexitol content in the mixture is 15-30wt.%, the amine content is 1-10wt.% and the ratio of the polyol mixture is 60-1.00 pts.wt. based on 1.00 pts.wt. of the constituent components in the presence of (C) water and optionally further (D) a physical foaming agent and (E) a catalyst, etc.

公开(公告)号：JPH11171959A

公开(公告)日：1999-06-29

申请号：JP27013798

申请日：1998-09-24

Applicant: BASF AG

Inventor： ROTERMUND UDO ,  HEMPEL RENATE ,  SEIFERT HOLGER DR ,  SCHMIADE WERNER

IPC: C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/66 ,  C08G18/67 ,  C08G101/00 ,  C08J9/14

Abstract: PROBLEM TO BE SOLVED: To provide a rigid foam based on an isocyanate compound, using a foaming agent not causing an environment disruption, capable of being produced by a conventional technology for producing rigid foams, and provided with resistance to high temperature, low heat conductivity at high temperature and low brittleness. SOLUTION: This thermally stable rigid foam comprises (a) a polyisocyanate, (b) a polyol, (c) water in an amount of at most 2 wt.%, and (d) 5-30 wt.% of a hydrocarbon and/or a fluorinated hydrocarbon as a foaming agent. The polyol (b) comprises (bi) at least one polyetheralcohol having a functional value number of at least 1.5 and hydroxyl groups of 10-100 mgKOH/g in an amount of 0.2-80 wt.% based on the component (b) and (bii) at least one polyesterpolyalcohol in an amount of 5-90 wt.% based on the component (b).

公开(公告)号：JPH11158369A

公开(公告)日：1999-06-15

申请号：JP27011298

申请日：1998-09-24

Applicant: BASF AG

Inventor： ROTERMUND UDO ,  BIEDERMANN ANJA ,  HEMPEL RENATE ,  WIEGMANN WERNER ,  HEINZ MARION

IPC: C08J3/02 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/50 ,  C08G18/66 ,  C08G101/00 ,  C08J9/12 ,  C08J9/14 ,  C08L75/04

Abstract: PROBLEM TO BE SOLVED: To provide an emulsion containing a halogen-free foaming agent for producing rigid foam based on isocyanate groups that brings about the properties improved by processing (in other words, improved heat stability and/or good foaming of the reaction mixture). SOLUTION: This emulsion contains (a) a compound bearing hydrogen atoms reactive to isocyanate, (b) water, (c) a halogen-free foaming agent having physical activity, and, when necessary (d) auxiliary agents and/or usually used additives. In this case, the components (a) contains 0.2-80 wt.% of polyether alcohol with the functionality of > 1.5 and the hydroxyl value of 10-100 mg KOH/g and the physically active halogen-free foaming agent (c) is hydrocarbon of 3-10 carbon atoms.

公开(公告)号：WO9961501A8

公开(公告)日：2000-01-27

申请号：PCT/EP9903195

申请日：1999-05-10

Applicant: BASF AG ,  REICHELT MICHAEL ,  ROTERMUND UDO ,  HEMPEL RENATE ,  FALKE PETER ,  VON MALOTKI PETER ,  SEIFERT HOLGER

Inventor： REICHELT MICHAEL ,  ROTERMUND UDO ,  HEMPEL RENATE ,  FALKE PETER ,  VON MALOTKI PETER ,  SEIFERT HOLGER

IPC: C08G18/10 ,  C08G18/50 ,  C08G18/76 ,  C09K3/10 ,  C08G18/48

CPC classification number: C09K3/1021 ,  C08G18/10 ,  C08G18/5006 ,  C08G18/7664 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/0083 ,  C08G18/6674

Abstract: The invention relates to prepolymers which contain isocyanate groups and which can be produced by reacting an isocyanate mixture, said mixture being predominantly comprised of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates, with a maximum proportion of two-core isomers of 74 wt.% with at least 4 functional polyols or with a mixture of polyols having an average functionality of at least 4. The polyols or polyol mixture comprise(s) a hydroxyl value ranging from 200 to 1650 mg KOH/g and an average molar mass of less than 1100 g/mol with an NCO content of at least 30.0 wt.%. In addition, the invention relates to a method for producing these prepolymers which contain isocyanate groups, to their use for producing polyurethanes, and to a method for producing polyurethanes by reacting at least one of the inventive prepolymers which contain isocyanate groups, optionally mixed with additional organic and/or modified organic isocyanates (a), with compounds having at least two reactive hydrogen atoms (b) in the presence of optional expanding agents (c), catalysts (d), optional additional auxiliary agents and/or additives (e).

Abstract translation: 本发明涉及含有可获得异氰酸酯基通过由二苯基甲烷二异氰酸酯和多苯基多亚甲基多异氰酸酯的主要的异氰酸酯混合物反应的预聚物，具有至少4官能的多元醇的不大于74重量％或具有至少4的平均官能度的多元醇的混合物两环异构体的比例 方法，其中所述多元醇或多元混合物具有的羟基数为200至1650毫克KOH /克和低于1100克/ mol的数均分子量，具有至少30.0重量％的NCO含量。 本发明的目的也可用于，任选地与另外的有机和/或改性的有机异氰酸酯的混合物制备含异氰酸酯基团，它们用于制备聚氨酯这些预聚物和含有异氰酸酯基的至少一种本发明的预聚物反应制备的聚氨酯的处理的方法（a）中 与具有化合物中的至少两个反应性氢原子（b）中，如果需要的话的情况下，发泡剂（C），催化剂（D），以及任选的其它助剂和/或添加剂（E）。

公开(公告)号：WO03042286A2

公开(公告)日：2003-05-22

申请号：PCT/EP0212604

申请日：2002-11-12

Applicant: BASF AG ,  ROTERMUND UDO ,  HEMPEL RENATE ,  VOELKEL RUEDIGER ,  SCHLEGEL KARL ,  FALKE PETER

Inventor： ROTERMUND UDO ,  HEMPEL RENATE ,  VOELKEL RUEDIGER ,  SCHLEGEL KARL ,  FALKE PETER

IPC: C04B38/00 ,  C08J9/36 ,  C08J9/00

CPC classification number: C08J9/36 ,  C04B38/0022 ,  C04B2111/00793 ,  C08J2375/04 ,  C04B35/52 ,  C04B38/0051 ,  C04B38/0058 ,  C04B38/0074

Abstract: The invention concerns a foam consisting of at least 70 wt. % of carbon, having an average cell size more than 30 mu m, porosity between 35 % and 99.7 %, a percentage of open cells higher than 90 %, and comprising linking elements between the cells, which, viewed in cross-section, form a triangle with inward-curving sides. Inside the surface of the cross-section, the sum of the surfaces having a cavity constitutes less than 5 % of the total cross-sectional area of the linking elements. The invention also concerns the use of said foams consisting for the major part of carbon in electrical and electrochemical applications, in the form of filtering material, heat insulation material, support material, storage material and as starting material for other transformations. The invention further concerns a method for producing a foam consisting of at least 70 wt. % of carbon, by pyrolizing synthetic foams. Said method is characterized in that the synthetic foams used contain at least 30 wt. % of a polymer material having a nitrogen content higher than 6 wt. %, and having a porosity between 20 and 99 %, as well as a percentage of open cells higher than 1 %.

Abstract translation: 本发明的目的是至少70重量超过30微摩尔的平均泡孔尺寸，35％和99.7％之间的孔隙率，开孔含量在90％以上，并与细胞的肋，其在横截面中具有三角形的碳现有泡沫的％ 有向内弯曲的边，其中，显示表面的腔体的总和的横截面区域的内部是格网网格的总横截面面积，以及使用这种主要由用于电和电化学应用碳泡沫的少于5％，如 过滤和热冲击吸收材料，如载体和储存材料并且作为用于进一步反应的起始材料。 本发明进一步提供了一种用于至少70制造位置包括-的重量碳泡沫的％通过，其特征在于，塑料泡沫中使用的聚合物材料的至少30质量％的聚合物泡沫体的热解 氮含量在6％以上质量和包含具有20％和99％和1％以上的开孔含量之间的Porosi-TY。

公开(公告)号：WO2004079837A3

公开(公告)日：2004-10-28

申请号：PCT/EP2004001675

申请日：2004-02-20

Applicant: BASF AG ,  ROTERMUND UDO ,  HEMPEL RENATE ,  RUDLOFF JAN ,  HENNIG INGOLF ,  MOEHWALD HELMUT ,  RAHNER DIETMAR ,  TROMMER KRISTIN

Inventor： ROTERMUND UDO ,  HEMPEL RENATE ,  RUDLOFF JAN ,  HENNIG INGOLF ,  MOEHWALD HELMUT ,  RAHNER DIETMAR ,  TROMMER KRISTIN

IPC: C01B31/02 ,  C08G18/02 ,  C08G18/06 ,  H01M20060101 ,  H01M4/36 ,  H01M4/86 ,  H01M4/88 ,  H01M4/96

CPC classification number: H01M4/587 ,  H01M4/8605 ,  H01M4/8673 ,  H01M4/96 ,  H01M8/0234

Abstract: The invention relates to carbon materials consisting of at least 70 wt. % carbon with a partial graphite structure. Said materials are characterised by 2 signals in the Raman spectrum excited at 488 nm for numbers of waves of 1595 cm and 1370 cm , the half-width of the signal for numbers of waves of 1595 cm (signal number 1) being less than 180 cm and the half-width of the signal for numbers of waves of 1370 cm (signal number 2) being less than 280 cm . The ratio of the products of the half-width and the intensity of the signals for signal number 1 to signal number 2 is greater than 0.5. The invention also relates to a method for producing said materials and to their use in electrical and electrochemical applications, in particular for electric energy accumulation.

Abstract translation: 本发明的目的是至少70种现有重量％的碳的碳材料具有部分石墨结构，其特征在于在488nm的拉曼光谱激发在波数约1595 2个信号厘米<-1>和1370厘米< - 1>，其中，在波数的信号的半宽度1595厘米<-1>（信号数目1）小于180 CM <-1>和在波数的信号的半宽度1370厘米<-1>（信号数2）较小 并且信号编号1的信号的半高宽与信号编号2的乘积之比大于0.5，以及它们的制备方法及其在电气和电化学应用中的用途， 特别是对于电能储存。

公开(公告)号：AT276298T

公开(公告)日：2004-10-15

申请号：AT98118033

申请日：1998-09-23

Applicant: BASF AG

Inventor： ROTERMUND UDO DR ,  HEMPEL RENATE ,  SEIFERT HOLGER DR ,  SCHMIADE WERNER

IPC: C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/66 ,  C08G18/67 ,  C08G101/00 ,  C08J9/14

Abstract: Emulsions containing polyether alcohols and polyester alcohols are used in the production of hard foams based on isocyanates to improve the temperature stability of the foams. Temperature-stable hard foams based on isocyanates are produced by reacting (a) polyisocyanates with (b) compounds with at least two hydrogen atoms reactive with isocyanate groups and (c) water in the presence of (d) propellants and optionally catalysts and auxiliary aids and additives. (b) comprises (bi) a polyether alcohol present in an amount of 0.2-80 wt.% and having a functionality of at least 1.5 and an OH number of 10-100 mg KOH/g, and (bii) a polyester alcohol present in an amount of 5-90 wt.%. (c) is present in an amount of maximum 2 wt.%. (d) contains hydrocarbons and/or hydrocarbons containing fluorine in an amount of 5-30 wt.%.

公开(公告)号：DE19816526A1

公开(公告)日：1999-10-21

申请号：DE19816526

申请日：1998-04-15

Applicant: BASF AG

Inventor： DINSCH STEFAN ,  ROTERMUND UDO ,  FALKE PETER ,  HEMPEL RENATE ,  SCHROETER HORST

IPC: C07B63/04 ,  C08G18/50 ,  C08G18/66 ,  C09K15/20 ,  C10M133/08 ,  C10M133/14 ,  C10M149/12 ,  C07C217/08 ,  C08K5/16 ,  C10M133/04

Abstract: Alkoxylated amines are used to stabilize fluid or solid compounds against aging.

公开(公告)号：DE59602971D1

公开(公告)日：1999-10-07

申请号：DE59602971

申请日：1996-12-16

Applicant: BASF AG

Inventor： KRECH RUEDIGER ,  ROTERMUND UDO ,  BOLLMANN HEINZ ,  HEMPEL RENATE ,  SCHOLZ WOLFGANG ,  GENZ MANFRED

IPC: C08J9/36 ,  C08G18/08 ,  C08G18/76

Abstract: PCT No. PCT/EP96/05640 Sec. 371 Date Oct. 7, 1998 Sec. 102(e) Date Oct. 7, 1998 PCT Filed Dec. 16, 1996 PCT Pub. No. WO97/23535 PCT Pub. Date Jul. 3, 1997A microcellular PU elastomer having improved dynamic mechanical properties and based on an isocyanate component consisting essentially of 4,4'-MDI and further customary constituents has a physicochemical structure which, in the gel permeation chromatograph (GPC) of a solution of the microcellular polyurethane elastomer prepared at 90 DEG C. in N,N-dimethylformamide containing 1 percent of di-n-butylamine measured against polymethyl methacrylate (PMMA) as standard, displays a signal occurring in addition to low molecular weight main signal and comprising one or more peaks at an (apparent) molar mass of greater than 250,000 g/mol which becomes smaller or disappears on addition of lithium chloride to this solution, and a urea content of from 14 to 18% by weight. A process is also provided for preparing such a microcellular PU elastomer having improved dynamic mechanical properties. The microcellular PU elastomers can be used for producing damping elements.