公开(公告)号：DE59506919D1

公开(公告)日：1999-10-28

申请号：DE59506919

申请日：1995-12-16

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  EBEL KLAUS ,  SCHNURR WERNER ,  MELDER JOHANN-PETER ,  HARDER WOLFGANG

IPC: B01J23/80 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24

Abstract: Aliphatic alpha , omega -aminonitriles are prepared by partial hydrogenation of aliphatic alpha , omega -dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst, by a process in which the catalyst used is obtainable by thermal decomposition of a metal compound selected from the group consisting of metal carbonyl compounds, metal salts of C1-C6-carboxylic acids and C2-C6-dicarboxylic acids and metal complexes with diketones to give the corresponding metal and/or a metal oxide thereof, with the proviso that the metal used is nickel or cobalt.

公开(公告)号：BR9710621A

公开(公告)日：1999-08-17

申请号：BR9710621

申请日：1997-07-29

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24

Abstract: A process for preparing an NH2-containing compound by hydrogenating a compound containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent which process includes the following steps: a) using a catalyst comprising a cobalt- and/or iron-containing catalyst, and b) after the conversion based on the compound to be hydrogenated and/or the selectivity based on the desired product has or have dropped below a defined value or the amount of an unwanted by-product has risen beyond a defined value, interrupting the hydrogenation by stopping the feed of the compound to be hydrogenated and of the solvent, if used, c) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and d) subsequently continuing the hydrogenation of the compound containing at least one unsaturated carbon-nitrogen bond.

公开(公告)号：PL331479A1

公开(公告)日：1999-07-19

申请号：PL33147997

申请日：1997-07-29

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24

Abstract: A process for preparing an NH2-containing compound by hydrogenating a compound containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent which process includes the following steps: a) using a catalyst comprising a cobalt- and/or iron-containing catalyst, and b) after the conversion based on the compound to be hydrogenated and/or the selectivity based on the desired product has or have dropped below a defined value or the amount of an unwanted by-product has risen beyond a defined value, interrupting the hydrogenation by stopping the feed of the compound to be hydrogenated and of the solvent, if used, c) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and d) subsequently continuing the hydrogenation of the compound containing at least one unsaturated carbon-nitrogen bond.

公开(公告)号：CZ9900810A3

公开(公告)日：1999-06-16

申请号：CZ81099

申请日：1997-08-21

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FLICK KLEMENS ,  LUYKEN HERMANN ,  REHFINGER ALWIN ,  BASSLER PETER

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C255/03

CPC classification number: C07C209/48 ,  C07C253/30

公开(公告)号：CZ81099A3

公开(公告)日：1999-06-16

申请号：CZ81099

申请日：1997-08-21

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FLICK KLEMENS ,  LUYKEN HERMANN ,  REHFINGER ALWIN ,  BASSLER PETER

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C255/03

Abstract: PCT No. PCT/EP97/04542 Sec. 371 Date Mar. 10, 1999 Sec. 102(e) Date Mar. 10, 1999 PCT Filed Aug. 21, 1997 PCT Pub. No. WO98/11051 PCT Pub. Date Mar. 19, 1998A process for coproduction of 6-aminocapronitrile and hexamethylenediamine starting from a mixture comprising a phosphorus-containing compound and essentially adiponitrile and obtained by reaction of butadiene with hydrocyanic acid in the presence of a catalyst comprising a phosphorus-containing compound comprises (1) reducing the weight proportion of phosphorus-containing compound, calculated as phosphorus, in the mixture, (2) partially hydrogenating the resulting mixture in the presence of a catalyst to form an alpha , omega -aminonitrile, and (3) removing 6-aminocapronitrile and hexamethylenediamine from the mixture.

公开(公告)号：MX9901061A

公开(公告)日：1999-05-01

申请号：MX9901061

申请日：1999-01-28

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24

公开(公告)号：DE59505332D1

公开(公告)日：1999-04-15

申请号：DE59505332

申请日：1995-12-16

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  WULFF-DOERING JOACHIM

IPC: B01J25/00 ,  B01J25/02 ,  B01J37/00 ,  C07B31/00 ,  C07C253/30

Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.

公开(公告)号：CA2302440A1

公开(公告)日：1999-03-11

申请号：CA2302440

申请日：1998-08-21

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  FLICK KLEMENS

IPC: B01J21/06 ,  B01J37/06 ,  C07D201/08 ,  C07D223/10

Abstract: The invention relates to a process for producing cyclic lactams by reacting aminocarboxylic acid nitriles with water, in liquid phase, in a fixed bed reactor, in the presence of a catalyst containing a catalytically active oxide comprising no soluble constituent under the reaction conditions. This process is characterised in that the catalyst is composed of shaped bodies which can be obtained by shaping the oxide into shaped bodies and by treating the oxide with an acid which is hardly soluble, having 0.1 to 30 % by weight of the oxide, before or after the shaping process.

公开(公告)号：NO990432L

公开(公告)日：1999-01-29

申请号：NO990432

申请日：1999-01-29

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24

Abstract: A process for preparing an NH2-containing compound by hydrogenating a compound containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent which process includes the following steps: a) using a catalyst comprising a cobalt- and/or iron-containing catalyst, and b) after the conversion based on the compound to be hydrogenated and/or the selectivity based on the desired product has or have dropped below a defined value or the amount of an unwanted by-product has risen beyond a defined value, interrupting the hydrogenation by stopping the feed of the compound to be hydrogenated and of the solvent, if used, c) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and d) subsequently continuing the hydrogenation of the compound containing at least one unsaturated carbon-nitrogen bond.

公开(公告)号：NO990432D0

公开(公告)日：1999-01-29

申请号：NO990432

申请日：1999-01-29

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B43/04 ,  C07B61/00 ,  C07C20060101 ,  C07C209/48 ,  C07C209/52 ,  C07C211/12 ,  C07C211/35 ,  C07C253/30 ,  C07C255/24 ,  C07C

Abstract: A process for preparing an NH2-containing compound by hydrogenating a compound containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent which process includes the following steps: a) using a catalyst comprising a cobalt- and/or iron-containing catalyst, and b) after the conversion based on the compound to be hydrogenated and/or the selectivity based on the desired product has or have dropped below a defined value or the amount of an unwanted by-product has risen beyond a defined value, interrupting the hydrogenation by stopping the feed of the compound to be hydrogenated and of the solvent, if used, c) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and d) subsequently continuing the hydrogenation of the compound containing at least one unsaturated carbon-nitrogen bond.